公开(公告)号：US20240253023A1

公开(公告)日：2024-08-01

申请号：US11867898

申请日：2007-10-05

Applicant: Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Yves Choquette

Inventor： Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Yves Choquette

IPC: B01J31/02 ,  B01J31/04 ,  B01J31/06 ,  B01J31/12 ,  B01J31/18 ,  B01J31/22 ,  C07B37/02 ,  C07B37/12 ,  C07C45/46 ,  C07C45/69 ,  C07C67/00 ,  C07C255/10 ,  C07C255/17 ,  C07C255/27 ,  C07C255/46 ,  C07C255/65 ,  C07C257/14 ,  C07C311/03 ,  C07C311/04 ,  C07C311/09 ,  C07C311/48 ,  C07C317/04 ,  C07C317/08 ,  C07C317/14 ,  C07C317/22 ,  C07C317/24 ,  C07C317/34 ,  C07C317/44 ,  C07D207/452 ,  C07D213/76 ,  C07D219/10 ,  C07D231/18 ,  C07D233/90 ,  C07D239/60 ,  C07D241/42 ,  C07D249/04 ,  C07D249/10 ,  C07D249/12 ,  C07D251/70 ,  C07D277/64 ,  C07D277/82 ,  C07D285/125 ,  C07D285/135 ,  C07D285/15 ,  C07D285/16 ,  C07D303/34 ,  C07D307/54 ,  C07D307/64 ,  C07D311/52 ,  C07D311/58 ,  C07D311/82 ,  C07D319/06 ,  C07D333/16 ,  C07D333/24 ,  C07D405/06 ,  C07D409/12 ,  C07D417/10 ,  C07D417/14 ,  C07F17/02 ,  C08F4/04 ,  C08G65/334 ,  C09B69/00 ,  C09B69/02 ,  C09B69/10 ,  H01B1/12 ,  H01G9/022 ,  H01G11/02 ,  H01G11/62 ,  H01M4/00 ,  H01M4/38 ,  H01M4/58 ,  H01M4/62 ,  H01M6/00 ,  H01M6/16 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  G02F1/1516 ,  G02F1/1523 ,  H01M4/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/40 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/60 ,  H01M4/66 ,  H01M6/04

CPC classification number: B01J31/0224 ,  B01J31/0215 ,  B01J31/0222 ,  B01J31/0225 ,  B01J31/0227 ,  B01J31/0235 ,  B01J31/0239 ,  B01J31/0247 ,  B01J31/0251 ,  B01J31/0252 ,  B01J31/0267 ,  B01J31/0271 ,  B01J31/0281 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/04 ,  B01J31/06 ,  B01J31/068 ,  B01J31/124 ,  B01J31/1815 ,  B01J31/2208 ,  C07B37/02 ,  C07B37/12 ,  C07C45/46 ,  C07C45/69 ,  C07C67/00 ,  C07C255/10 ,  C07C255/17 ,  C07C255/27 ,  C07C255/46 ,  C07C255/65 ,  C07C257/14 ,  C07C311/03 ,  C07C311/04 ,  C07C311/09 ,  C07C311/48 ,  C07C317/04 ,  C07C317/08 ,  C07C317/14 ,  C07C317/22 ,  C07C317/24 ,  C07C317/34 ,  C07C317/44 ,  C07D207/452 ,  C07D213/76 ,  C07D219/10 ,  C07D231/18 ,  C07D233/90 ,  C07D239/60 ,  C07D241/42 ,  C07D249/04 ,  C07D249/10 ,  C07D249/12 ,  C07D251/70 ,  C07D277/64 ,  C07D277/82 ,  C07D285/125 ,  C07D285/135 ,  C07D285/15 ,  C07D285/16 ,  C07D303/34 ,  C07D307/54 ,  C07D307/64 ,  C07D311/52 ,  C07D311/58 ,  C07D311/82 ,  C07D319/06 ,  C07D333/16 ,  C07D333/24 ,  C07D405/06 ,  C07D409/12 ,  C07D417/10 ,  C07D417/14 ,  C07F17/02 ,  C08F4/04 ,  C08G65/3344 ,  C09B69/00 ,  C09B69/02 ,  C09B69/10 ,  H01B1/122 ,  H01B1/128 ,  H01G9/022 ,  H01G11/02 ,  H01G11/62 ,  H01M4/00 ,  H01M4/382 ,  H01M4/5815 ,  H01M4/625 ,  H01M6/00 ,  H01M6/166 ,  H01M6/181 ,  H01M6/183 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  B01J2231/122 ,  B01J2231/14 ,  B01J2231/326 ,  B01J2231/341 ,  B01J2231/348 ,  B01J2231/4205 ,  B01J2231/543 ,  B01J2531/35 ,  B01J2531/824 ,  C07C2601/10 ,  C07C2602/42 ,  G02F2001/1518 ,  G02F1/1525 ,  H01M4/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/405 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/60 ,  H01M4/661 ,  H01M6/04 ,  H01M6/164 ,  H01M6/168 ,  Y02E60/13 ,  Y10S430/127 ,  Y10T29/49108 ,  Y10T428/2918

Abstract: The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula RF—SOx—N−Z, where RF is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.

公开(公告)号：US20230391945A1

公开(公告)日：2023-12-07

申请号：US18202015

申请日：2023-05-25

Applicant: POLYSPECTRA, INC.

Inventor： Aditya BALASUBRAMANIAN ,  Raymond A. WEITEKAMP

IPC: C08G61/08 ,  B01J31/22 ,  C08K5/07 ,  C08K5/45 ,  C08K5/5313 ,  C08K5/5397 ,  G03F7/00 ,  G03F7/028 ,  G03F7/20

CPC classification number: C08G61/08 ,  B01J31/2278 ,  C08K5/07 ,  C08K5/45 ,  C08K5/5313 ,  C08K5/5397 ,  G03F7/0037 ,  G03F7/028 ,  G03F7/2004 ,  B01J2231/543 ,  B01J2531/821 ,  C08G2261/3321 ,  C08G2261/374 ,  C08G2261/418

Abstract: Described herein are compositions and methods for processing photopolymers based on olefin metathesis. The compositions and methods comprise latent ruthenium complexes and photoacids and/or photoacid generators.

公开(公告)号：US11794178B2

公开(公告)日：2023-10-24

申请号：US17577510

申请日：2022-01-18

Applicant: University of Florida Research Foundation, Inc.

Inventor： Adam S. Veige ,  Stella Almeida Gonsales

IPC: C07F11/00 ,  C08F4/78 ,  B01J31/22 ,  C08F32/04 ,  C08G61/08 ,  C08F4/69

CPC classification number: B01J31/223 ,  B01J31/2243 ,  B01J31/2265 ,  B01J31/2286 ,  C07F11/00 ,  C08F4/69 ,  C08F32/04 ,  C08G61/08 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/0244 ,  B01J2531/66 ,  B01J2540/10 ,  B01J2540/225 ,  C08F4/69206 ,  C08F4/78 ,  C08G2261/13 ,  C08G2261/3324 ,  C08G2261/418

Abstract: A tetraanionic OCO pincer ligand metal-oxo-alkylidene complex is prepared from a trianionic pincer ligand supported metal-alkylidyne. The metal can be tungsten or other group 5-7 transition metal. The tetraanionic pincer ligand metal-oxo-alkylidene complex, a trianionic OCO pincer ligand metal complex, or a trianionic ONO pincer ligand metal complex can be used to polymerize cycloalkenes. The poly(cycloalkene)s are predominantly cis-alkene macrocyclics.

公开(公告)号：US20180099268A1

公开(公告)日：2018-04-12

申请号：US15721018

申请日：2017-09-29

Applicant: Provivi, Inc.

Inventor： Keith M. Wampler ,  Peter Meinhold ,  Pedro Coelho ,  Vu Bui ,  Levente Ondi ,  Hasan Mehdi

IPC: B01J31/22 ,  C07C6/04 ,  C07C29/147 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C45/41

CPC classification number: B01J31/2278 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07B2200/09 ,  C07C6/04 ,  C07C29/147 ,  C07C45/41 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C2531/22 ,  C07C69/533 ,  C07C33/025 ,  C07C69/145 ,  C07C47/21 ,  C07C11/21

Abstract: In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US20180050332A1

公开(公告)日：2018-02-22

申请号：US15683033

申请日：2017-08-22

Applicant: Florida State University Research Foundation, Inc.

Inventor： Hoyong Chung

IPC: B01J31/40 ,  B01J31/22 ,  B01J35/12 ,  B01J38/52 ,  C07F15/00 ,  C07C209/70 ,  C07D211/02 ,  C07D211/70 ,  C07D207/20 ,  C07C29/56 ,  C07C29/46 ,  C07D209/48 ,  C07C67/333 ,  C07D223/10 ,  C07D307/28 ,  C08F132/08

CPC classification number: B01J31/2278 ,  B01J31/123 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/4023 ,  B01J35/12 ,  B01J38/52 ,  B01J2231/543 ,  B01J2531/821 ,  C07C29/46 ,  C07C29/56 ,  C07C41/28 ,  C07C41/30 ,  C07C67/333 ,  C07C209/68 ,  C07C209/70 ,  C07C2601/10 ,  C07C2603/74 ,  C07D207/20 ,  C07D209/48 ,  C07D211/02 ,  C07D211/70 ,  C07D223/10 ,  C07D307/28 ,  C07F15/0046 ,  C07H3/06 ,  C08B37/0012 ,  C08B37/0015 ,  C08F132/08 ,  Y02P20/584 ,  C07C43/196 ,  C07C43/235 ,  C07C211/63

Abstract: This describes homogeneous catalysts that are recoverable from solution by being phase selective and through host-guest interactions. An example of a method includes separating a water soluble N-heterocyclic carbene homogeneous catalyst from a solution by: (a) forming a host-guest compound between the catalyst and an inclusion compound in the solution; and (b) isolating the host-guest compound from the solution.

公开(公告)号：US09850268B2

公开(公告)日：2017-12-26

申请号：US14933741

申请日：2015-11-05

Applicant: Massachusetts Institute of Technology ,  Trustees of Boston College

Inventor： Amir H. Hoveyda ,  Hanmo Zhang ,  Ming Joo Koh ,  Richard Royce Schrock

IPC: C07C17/275 ,  C07C45/63 ,  C07C37/62 ,  B01J31/22 ,  C07F11/00 ,  C07D333/54 ,  C07D209/10 ,  C07D209/48 ,  C07F5/02 ,  C07F7/18 ,  C07C17/266 ,  C07C17/269 ,  C07C17/278 ,  C07C17/10 ,  C07C17/14 ,  C07C17/361 ,  C07B37/04 ,  C07C17/02 ,  C07J9/00 ,  C07J51/00 ,  C07C67/307 ,  C07C67/333 ,  C07C41/30

CPC classification number: C07F11/00 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07B37/04 ,  C07C17/02 ,  C07C17/10 ,  C07C17/14 ,  C07C17/266 ,  C07C17/269 ,  C07C17/275 ,  C07C17/278 ,  C07C17/361 ,  C07C21/14 ,  C07C21/18 ,  C07C22/08 ,  C07C37/62 ,  C07C41/30 ,  C07C45/63 ,  C07C67/307 ,  C07C67/333 ,  C07C69/753 ,  C07C2601/14 ,  C07C2603/26 ,  C07D209/10 ,  C07D209/48 ,  C07D333/54 ,  C07F5/025 ,  C07F7/1804 ,  C07J9/00 ,  C07J51/00 ,  C07C21/19 ,  C07C21/04 ,  C07C25/24 ,  C07C22/04 ,  C07C22/00 ,  C07C22/02 ,  C07C25/28 ,  C07C43/225 ,  C07C43/192 ,  C07C43/17 ,  C07C69/65 ,  C07C69/63

Abstract: The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and/or stereoselectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and Z-selectivity. In some embodiments, the present disclosure provides methods for preparing alkenyl halide with regioselectivity and E-selectivity. In some embodiments, provided technologies are particularly useful for preparing alkenyl fluorides. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-a. In some embodiments, a provided compound useful for metathesis reactions has the structure of formula II-b.

公开(公告)号：US20170291863A1

公开(公告)日：2017-10-12

申请号：US15633435

申请日：2017-06-26

Applicant: ASAHI GLASS COMPANY, LIMITED

Inventor： Yusuke TAKAHIRA ,  Daisuke JOMUTA

IPC: C07C6/04 ,  B01J23/24 ,  C07C21/04 ,  C07C21/18

CPC classification number: C07C6/04 ,  B01J23/24 ,  B01J23/28 ,  B01J31/1805 ,  B01J31/2226 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2531/64 ,  C07B61/00 ,  C07C17/361 ,  C07C21/04 ,  C07C21/18 ,  C07C41/22 ,  C07C67/287 ,  C07C67/307 ,  C07D207/27 ,  C07D209/86 ,  C07C43/17 ,  C07C69/63

Abstract: A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51) and a compound of formula (52), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

公开(公告)号：US09713808B2

公开(公告)日：2017-07-25

申请号：US14797834

申请日：2015-07-13

Applicant: Massachusetts Institute of Technology ,  Trustees of Boston College

Inventor： Richard R. Schrock ,  Annie J. King ,  Yu Zhao ,  Margaret M. Flook ,  Amir H. Hoveyda

IPC: C07F11/00 ,  B01J31/18 ,  B01J31/22 ,  C07C6/04 ,  C07C41/30 ,  C07C67/475 ,  C07C209/68 ,  C07C303/40 ,  C07F7/08 ,  C07C209/64 ,  C07F5/02

CPC classification number: B01J31/2295 ,  B01J31/1805 ,  B01J31/181 ,  B01J31/1825 ,  B01J31/2226 ,  B01J31/2265 ,  B01J31/2278 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/0266 ,  B01J2531/0288 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/225 ,  B01J2540/40 ,  C07B2200/09 ,  C07C6/04 ,  C07C41/30 ,  C07C67/475 ,  C07C209/64 ,  C07C209/68 ,  C07C303/40 ,  C07C2531/18 ,  C07C2531/22 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2602/10 ,  C07F5/025 ,  C07F7/083 ,  C07F11/00 ,  C07F11/005 ,  C07C13/28 ,  C07C11/02 ,  C07C15/50 ,  C07C43/166 ,  C07C69/593 ,  C07C311/18 ,  C07C211/53

Abstract: The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

公开(公告)号：US20170037069A1

公开(公告)日：2017-02-09

申请号：US15303089

申请日：2015-04-09

Applicant: XiMo AG

Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

IPC: C07F11/00 ,  C07C6/04 ,  B01J31/22 ,  C07C67/475

CPC classification number: C07F11/00 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2601/10 ,  C07D321/00 ,  C07C69/74 ,  C07C69/593 ,  C07C11/02 ,  C07C15/12

Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

Abstract translation: 本公开提供了第6组配合物，其在一些实施方案中可用于催化烯烃复分解反应。 在一些实施方案中，化合物是下式（I）的化合物，其中：M是第6族金属原子; X是氧原子，= N-R5，= N-N（R5）（R5'）或= N-0-R5，R5和R5独立地是各种取代基，例如芳基或杂芳基，各自任选被取代; n为0或1; Rz是中性配体; R1是氢或有机取代基; R2是芳基或杂芳基，各自任选被取代; R3是阴离子配体; 并且R 4是阴离子配体，例如吡咯烷，吡唑啉，咪唑啉，吲哚啉，氮杂吲哚，或吲唑啉，各自任选被取代。

公开(公告)号：US20170001925A1

公开(公告)日：2017-01-05

申请号：US15190950

申请日：2016-06-23

Applicant: Saudi Arabian Oil Company ,  King Fahd University of Petroleum & Minerals

Inventor： Raed Abudawoud ,  Sulaiman Saleh Al-Khattaf ,  Arudra Palani ,  Abdullah M. Aitani ,  Mohammad Naseem Akhtar ,  Tazul Islam Bhuiyan ,  Mohammed A. Al-Yami

IPC: C07C6/04 ,  B01J35/10 ,  B01J23/30

CPC classification number: C07C6/04 ,  B01J21/08 ,  B01J23/30 ,  B01J29/0341 ,  B01J32/00 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J2231/543 ,  B01J2523/41 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/74 ,  C07C2521/08 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2529/78 ,  Y02P20/52 ,  C07C11/06

Abstract: Embodiments of a metathesis process for producing propylene comprise providing a metathesis catalyst comprising an amorphous mesoporous silica foam impregnated with metal oxides, where the metathesis catalyst has a pore size distribution of at least 3 nm to 40 nm and a total pore volume of at least 0.700 cm3/g. The process further involves producing a product stream comprising propylene by contacting a feed stream comprising butene with the metathesis catalyst.

Abstract translation: 用于生产丙烯的复分解方法的实施方案包括提供包含浸渍有金属氧化物的无定形介孔二氧化硅泡沫的复分解催化剂，其中复分解催化剂具有至少3nm至40nm的孔径分布和至少0.700的总孔体积 cm3 / g。 该方法还涉及通过使包含丁烯的进料流与复分解催化剂接触来生产包含丙烯的产物流。