公开(公告)号：US20240299924A1

公开(公告)日：2024-09-12

申请号：US18273108

申请日：2022-08-01

申请人： LG CHEM, LTD.

发明人： Jun Yeon Cho ,  Sojin Kim ,  Suji Kim ,  Jun Seon Choi ,  Sangjin Kim ,  Jae Soon Choi

IPC分类号： B01J37/02 ,  B01J23/00 ,  B01J23/86 ,  B01J37/04 ,  B01J37/08 ,  C01B3/40

CPC分类号： B01J37/0244 ,  B01J23/002 ,  B01J23/866 ,  B01J37/0228 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  C01B3/40 ,  B01J2523/24 ,  B01J2523/31 ,  B01J2523/36 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/821 ,  B01J2523/847 ,  C01B2203/0238 ,  C01B2203/1029 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241

摘要： The catalyst for methane reformation according to an exemplary embodiment of the present application comprises: a porous metal support; a first coating layer provided on the porous metal support and comprising an inorganic oxide; and a second coating layer provided on the first coating layer and comprising the perovskite-based compound represented by Chemical Formula 2:


Sr1-xAxTiαByO3-δ  [Chemical Formula 2]



wherein all the variables are described herein.

公开(公告)号：US12030989B2

公开(公告)日：2024-07-09

申请号：US18071656

申请日：2022-11-30

申请人： Zhejiang Huangma Technology Co., Ltd. ,  Zhejiang Lukean Chemical Co., Ltd. ,  Zhejiang Huangma Shangyi New Material Co., Ltd. ,  Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.

发明人： Weisong Wang ,  Xinrong Wang ,  Yifeng Jin ,  Shengli Wang ,  Jiang Yu ,  Shicong Zhao ,  Baocheng Qiu

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/10 ,  B01J23/10 ,  B01J23/28 ,  B01J23/72 ,  B01J23/755 ,  B01J23/83 ,  B01J23/883 ,  B01J23/885 ,  C08G65/26

CPC分类号： C08G65/269 ,  B01J21/04 ,  B01J21/06 ,  B01J21/10 ,  B01J23/10 ,  B01J23/885 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

摘要： Disclosed are to a supported catalyst used for synthesizing polyether amine, and a preparation method and use thereof. The supported catalyst introduces Mo and CeO2 into Ni and Cu active components. By means of the cooperation of Ni, Cu and Mo, CeO2 and Ni form more active sites, such that the supported catalyst can have high reaction activity and selectivity. By using the supported catalyst to synthesize polyether amine, the amination efficiency and selectivity of polyether polyol can be greatly enhanced, thereby preparing the polyether amine with light color and narrow molecular weight distribution. In addition, the cost of the catalyst can be reduced, a process condition is relatively mild, and the disadvantage of low reaction activity of a nickel-based catalyst in synthesizing small molecule polyether amine can be overcome, such that the supported catalyst has a desirable industrial application prospect.

公开(公告)号：US11918987B2

公开(公告)日：2024-03-05

申请号：US17291250

申请日：2020-01-14

申请人： Wanhua Chemical Group Co., Ltd.

发明人： Lei Wang ,  Tongji Wang ,  Fei Ye ,  Kang Sun ,  Naibo Chu ,  Qiankun Jiao ,  Yuan Li

IPC分类号： B01J37/00 ,  B01J21/06 ,  B01J21/08 ,  B01J23/28 ,  B01J35/10 ,  B01J37/08 ,  C07D301/14

CPC分类号： B01J37/0018 ,  B01J21/063 ,  B01J21/08 ,  B01J23/28 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/08 ,  C07D301/14 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

摘要： Provided are a preparation method for a propylene epoxidation catalyst, and a use thereof. During the preparation, an alkoxide solution of a prepared active component and a silica gel support are mixed, then a rotary evaporation treatment is performed on the mixture to remove a low-carbon alcohol to obtain a catalyst precursor, and then the obtained catalyst precursor is subjected to calcination and silylation treatments to obtain the propylene epoxidation catalyst. The catalyst is prepared in a simple process, can be applied to the chemical process of preparing propylene oxide by propylene epoxidation, has high average selectivity to propylene oxide, and has industrial application prospect.

公开(公告)号：US20190210006A1

公开(公告)日：2019-07-11

申请号：US16303278

申请日：2017-05-16

申请人： SABIC Global Technologies B.V.

发明人： Wugeng LIANG ,  Sagar SARSANI ,  David WEST

IPC分类号： B01J23/34 ,  B01J23/00 ,  B01J23/04 ,  B01J21/08 ,  B01J37/04 ,  B01J37/08 ,  C07C2/84 ,  C07C11/04 ,  C07C27/14 ,  C07C29/48 ,  C07C31/08

CPC分类号： B01J23/34 ,  B01J21/08 ,  B01J23/002 ,  B01J23/04 ,  B01J35/0013 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  B01J2523/12 ,  B01J2523/69 ,  B01J2523/72 ,  C07C2/84 ,  C07C11/04 ,  C07C27/14 ,  C07C29/48 ,  C07C31/08 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/52 ,  B01J2523/41

摘要： Disclosed is a supported catalyst and methods to prepare and use the supported catalyst in an oxidative coupling of methane (OCM) reaction. The supported catalyst can contain MnWO4 or MnWO4 nanostructures that are in contact with the surface of a sodium containing silicon dioxide support material. The supported MnWO4 catalyst can have an active MnWO4 crystal phase.

公开(公告)号：US20180305473A1

公开(公告)日：2018-10-25

申请号：US15495116

申请日：2017-04-24

申请人： Chevron Phillips Chemical Company LP

发明人： Eric D. SCHWERDTFEGER ,  Max P. MCDANIEL ,  Ted H. CYMBALUK ,  Jeremy M. PRAETORIUS ,  Kathy S. CLEAR ,  Alan L. SOLENBERGER

IPC分类号： C08F10/02

CPC分类号： C08F10/02 ,  B01J23/26 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/086 ,  B01J37/14 ,  B01J2523/00 ,  C08F2/34 ,  C08F4/025 ,  C08F4/24 ,  C08F4/76 ,  C08F4/78 ,  C08F110/02 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/67

摘要： A method comprising calcining a catalyst precursor comprising chromium and a silica support material at a temperature in the range of from about 95° C. to about 400° C. in a bed fluidized by a gas flowing at a volumetric flow rate of from about 2.5 to about 30 times the settled volume of the bed per minute to form a calcined catalyst precursor. A method comprising calcining a catalyst precursor comprising chromium and silica at a temperature in the range of from about 95° C. to about 400° C. with a gas flowing through the bed at a gas hourly space velocity of from about 15 to about 200 per hour. A method comprising calcining a catalyst precursor comprising chromium and silica at a temperature in the range of from about 95° C. to about 400° C. with a gas flowing through the bed at a weight hourly space velocity of from about 1.9 to about 240 per hour.

公开(公告)号：US20180243729A1

公开(公告)日：2018-08-30

申请号：US15756432

申请日：2016-09-21

申请人： BASF Corporation

发明人： Gerard D. Lapadula ,  Tiep M. Pham ,  Michael Durilla ,  Pascaline Harrison Tran

IPC分类号： B01J23/63 ,  B01J21/08 ,  B01J21/06 ,  B01J23/42 ,  B01J23/44 ,  B01J21/04 ,  B01J37/02 ,  B01J37/08 ,  B01D53/94 ,  F01N3/28

CPC分类号： B01J23/63 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/30 ,  B01J21/04 ,  B01J21/066 ,  B01J21/08 ,  B01J23/002 ,  B01J23/42 ,  B01J23/44 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0228 ,  B01J37/0236 ,  B01J37/0242 ,  B01J37/0248 ,  B01J37/08 ,  B01J2523/00 ,  C10K3/04 ,  F01N3/2803 ,  F01N3/2825 ,  F01N2370/02 ,  F01N2510/067 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/3712 ,  B01J2523/31

摘要： Disclosed in certain embodiments is a sulfur tolerant catalytic system that includes a catalytic material coated onto a substrate.

公开(公告)号：US20180169623A1

公开(公告)日：2018-06-21

申请号：US15831594

申请日：2017-12-05

申请人： ExxonMobil Research and Engineering Company

发明人： Brian M. Weiss ,  Gerardo J. Majano ,  Tilman W. Beutel ,  Karl G. Strohmaier ,  John F. Brody ,  Samia Ilias ,  Scott J. Weigel ,  Shamel Merchant ,  Eugine Choi ,  Robert J. Colby ,  Walter Weissman

IPC分类号： B01J23/46 ,  F02M26/35 ,  C10L3/08 ,  C01B3/40 ,  B01J23/08 ,  B01J23/06 ,  B01J23/60 ,  B01J29/70 ,  B01J29/85 ,  B01J23/10

CPC分类号： B01J23/464 ,  B01D53/92 ,  B01D2256/24 ,  B01J23/002 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/70 ,  B01J29/7015 ,  B01J29/74 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/78 ,  B01J29/783 ,  B01J29/80 ,  B01J29/85 ,  B01J35/0006 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/04 ,  B01J37/088 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/24 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0277 ,  C01B2203/062 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/84 ,  C10G2/333 ,  C10G2/334 ,  C10G35/09 ,  C10G35/095 ,  C10G47/04 ,  C10G47/14 ,  C10G47/18 ,  C10G47/20 ,  C10G63/08 ,  C10G2300/104 ,  C10G2300/305 ,  C10G2400/02 ,  C10L3/08 ,  F02M26/35 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/51 ,  B01J2523/32 ,  C07C1/04 ,  C07C9/04

摘要： Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.

公开(公告)号：US09975112B2

公开(公告)日：2018-05-22

申请号：US14969747

申请日：2015-12-15

申请人： ENI S.p.A.

发明人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC分类号： B01J31/00 ,  B01J23/00 ,  B01J27/051 ,  B01J27/049 ,  B01J35/10 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  B01J23/883 ,  B01J23/888 ,  B01J21/00 ,  B01J25/00

CPC分类号： B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC  (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH  (I) wherein the groups RIRIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N  (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US09944587B2

公开(公告)日：2018-04-17

申请号：US15110072

申请日：2014-06-12

申请人： FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER, CHINESE ACADEMY OF SCIENCES

发明人： Zhongning Xu ,  Guocong Guo ,  Siyan Peng ,  Zhiqiao Wang ,  Qingsong Chen ,  Mingsheng Wang ,  Yuangen Yao

IPC分类号： C07C67/36 ,  B01J23/89 ,  B01J37/08 ,  B01J37/16 ,  B01J37/34 ,  B01J21/04 ,  B01J21/10 ,  B01J21/06 ,  B01J21/08 ,  B01J21/18 ,  B01J23/02 ,  B01J23/06 ,  B01J23/44 ,  B01J23/48 ,  B01J23/40 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J23/46

CPC分类号： C07C67/36 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/10 ,  B01J21/18 ,  B01J23/02 ,  B01J23/06 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/466 ,  B01J23/468 ,  B01J23/89 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8946 ,  B01J23/8953 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/088 ,  B01J37/16 ,  B01J37/343 ,  B01J2523/00 ,  C07C69/06 ,  B01J2523/22 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/847 ,  B01J2523/822 ,  B01J2523/48 ,  B01J2523/821 ,  B01J2523/47 ,  B01J2523/827 ,  B01J2523/41 ,  B01J2523/825 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/17

摘要： A process for vapor-phase carbonylation of methanol to methyl formate, whereby a feed gas containing methanol, carbon monoxide, hydrogen and oxygen is passed through a reactor loaded with a supported nano-scaled platinum group metal heterogeneous catalyst to produce methyl formate by a vapor-phase carbonylation reaction, under reaction conditions with a space velocity of 500-5000 h−1, a temperature of 50-150° C. and a pressure of 0.01-2 MPa. Supported nano-scaled platinum group metal heterogeneous catalysts are prepared via ultrasonic dispersion and calcination. Methyl formate is produced and isolated under relatively mild conditions.

公开(公告)号：US09920008B2

公开(公告)日：2018-03-20

申请号：US15105499

申请日：2014-09-05

申请人： XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

发明人： Jianming Yang ,  Jian Lu ,  Suning Mei ,  Qinwei Yu ,  Feng Hui ,  Yani Li ,  Fengwei Zhao ,  Weiqiang Wang ,  Wei Wang

IPC分类号： C07D203/08 ,  B01J27/182 ,  B01J37/04 ,  B01J37/08 ,  B01J37/26 ,  B01J37/28 ,  B01J21/06 ,  B01J21/08 ,  B01J23/78 ,  B01J37/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC分类号： C07D203/08 ,  B01J21/063 ,  B01J21/08 ,  B01J23/78 ,  B01J27/182 ,  B01J27/1853 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0217 ,  B01J37/04 ,  B01J37/082 ,  B01J37/088 ,  B01J37/26 ,  B01J37/28 ,  B01J2523/00 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/842

摘要： The present invention relates to a catalyst for synthesizing ethylenimine as well as a preparation method and application thereof. The related catalyst comprises a carrier and metal ions loaded on the carrier; the carrier is a composite oxide comprising titanium, silicon and phosphorus elements; the metal ions are magnesium ions, iron ions and cesium ions; the molar ratio of the magnesium ions to the iron ions to the cesium ions is (1-10):1:0.1; the mass of all metal ions is 0.5-10 percent of that of the carrier. In the related preparation method, a catalyst precursor is roasted at the temperature of 350-650° C., so that the catalyst is obtained; the catalyst precursor is the mixture of the carrier, soluble salt of magnesium, soluble salt of iron and soluble salt of cesium. The present invention also provides the application of the catalyst to synthesis of the ethylenimine by using amino alcohol as the raw material. Compared with a common catalyst which has the requirement on the temperature of over 400° C., the catalyst of the present invention obviously reduces the reaction temperature. The prepared catalyst can catalyze the intramolecular dehydration reaction of the amino alcohol and has relatively excellent selectivity.