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公开(公告)号:US12091619B2
公开(公告)日:2024-09-17
申请号:US18347923
申请日:2023-07-06
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z Albaher
CPC classification number: C10G47/04 , B01J19/24 , B01J23/002 , B01J23/83 , C10G69/06 , C10G2300/4006 , C10G2300/4012 , C10G2300/706 , C10G2400/30
Abstract: A method for upgrading mixed pyrolysis oil may include contacting the mixed pyrolysis oil with hydrogen in the presence of a mixed metal oxide catalyst at reaction conditions to produce a reaction effluent including light aromatic compounds. The mixed pyrolysis oil includes multi-ring aromatic compounds and is formed from light pyrolysis oil and heavy pyrolysis oil at a ratio of 10:90 to 40:60 with light pyrolysis oil representing a bottom stream of a gas steam cracker and heavy pyrolysis oil representing a bottom stream of a naphtha steam cracker. The mixed metal oxide catalyst includes a plurality of catalyst particles with each catalyst particles including a plurality of metal oxides. An associated system for upgrading mixed pyrolysis oil may include a pyrolysis upgrading unit housing the mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from the reaction effluent.
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公开(公告)号:US20240010505A1
公开(公告)日:2024-01-11
申请号:US18151984
申请日:2023-01-09
Inventor: Rajesh Kumar PARSAPUR , Robert Peter HODGKINS , Omer Refa KOSEOGLU , Kuo-Wei HUANG , Anissa Bendjeriou SEDJERARI
CPC classification number: C01B39/20 , B01J35/1052 , C10G47/04 , B01J29/16 , B01J29/10 , B01J35/0006 , B01J21/04 , C01P2006/16 , C01P2002/74
Abstract: A composition of matter is provided comprising hierarchically ordered crystalline microporous material having well-defined long-range mesoporous ordering of hexagonal symmetry. The composition possesses mesopores having walls of crystalline microporous material and a mass of mesostructure between mesopores of crystalline microporous material. Long-range ordering is defined by presence of secondary peaks in an X-ray diffraction (XRD) pattern and/or hexagonal symmetry observable by microscopy.
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公开(公告)号:US20180334622A1
公开(公告)日:2018-11-22
申请号:US15971590
申请日:2018-05-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Gaurav Agrawal , Stephen T. Cohn , Kapil Kandel , Subramanya V. Nayak , Teng Xu
IPC: C10G47/04
CPC classification number: C10G47/04 , C10G9/36 , C10G45/38 , C10G47/00 , C10G65/04 , C10G65/12 , C10G2300/301 , C10G2400/04
Abstract: A hydrocarbon conversion process comprises providing a hydrocarbon feedstock comprising an effluent fraction from a pyrolysis process, wherein the effluent fraction has an initial boiling point at atmospheric pressure of at least 177° C. and a final boiling point at atmospheric pressure of no more than 343° C. and comprises at least 0.5 wt. % of olefinic hydrogen atoms based on the total weight of hydrogen atoms in the effluent fraction. The hydrocarbon feedstock is hydroprocessed in at least one hydroprocessing zone in the presence of treatment gas comprising molecular hydrogen under catalytic hydroprocessing conditions to produce a hydroprocessed product comprising less than 0.5 wt. % of olefinic hydrogen atoms based on the total weight of hydrogen atoms in the hydroprocessed product. The hydroprocessing conditions comprise a temperature from 150 to 350° C. and a pressure from 500 to 1500 psig (3550 to 10445 kPa-a).
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公开(公告)号:US10053637B2
公开(公告)日:2018-08-21
申请号:US15377676
申请日:2016-12-13
Applicant: UOP LLC
Inventor: Stuart Miller , Susan C. Koster
IPC: B01J21/10 , B01J23/16 , B01J23/72 , B01J23/74 , B01J23/76 , B01J37/04 , B01J37/08 , B01J37/20 , C10G45/08 , C10G45/50 , C10G47/04 , B01J21/08 , B01J21/04 , B01J21/12 , B01J37/00 , C10G45/60 , C10G45/04 , C10G45/46 , B01J31/22 , B01J31/02
CPC classification number: C10G47/04 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/888 , B01J31/0202 , B01J31/0207 , B01J31/0208 , B01J31/223 , B01J37/0009 , B01J37/009 , B01J37/04 , B01J37/20 , B01J2231/64 , B01J2531/0272 , B01J2531/16 , B01J2531/22 , B01J2531/26 , B01J2531/66 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C10G45/04 , C10G45/08 , C10G45/46 , C10G45/50 , C10G45/60
Abstract: A hydroprocessing catalyst has been developed. The catalyst is a unique transition metal tungsten oxy-hydroxide material. The hydroprocessing using the transition metal tungsten oxy-hydroxide material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
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公开(公告)号:US10052614B2
公开(公告)日:2018-08-21
申请号:US15377753
申请日:2016-12-13
Applicant: UOP LLC
Inventor: Stuart Miller , Susan C. Koster
IPC: B01J21/10 , B01J23/16 , B01J23/72 , B01J23/74 , B01J23/76 , B01J37/04 , B01J37/08 , B01J37/20 , C10G45/08 , C10G45/50 , C10G47/04 , B01J23/883 , B01J23/00 , B01J21/08 , B01J21/04 , B01J21/12 , B01J37/00 , C10G45/60
CPC classification number: B01J23/883 , B01J23/8892 , B01J35/002 , B01J37/031 , B01J37/088 , B01J37/20 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/04 , C10G2300/202 , C10G2300/205
Abstract: A novel mixed metal molybdate useful as a hydroprocessing catalyst has been created. The hydroprocessing using the novel mixed metal molybdate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
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公开(公告)号:US20180195013A1
公开(公告)日:2018-07-12
申请号:US15558846
申请日:2016-02-16
Applicant: IFP ENERGIES NOUVELLES
Inventor: Matthieu DREILLARD , Frederic FEUGNET , Joao MARQUES , Frederic MOREL
CPC classification number: C10G65/12 , B01J21/04 , B01J23/28 , B01J23/755 , C10G47/04 , C10G47/12 , C10G65/00 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: The invention concerns a process for the conversion of a heavy hydrocarbon feed, said process comprising the following steps: a) a step for hydroconversion of the heavy hydrocarbon feed in the presence of hydrogen in at least one or more three-phase reactors disposed in series or in parallel, containing at least one hydroconversion catalyst, so as to obtain a liquid effluent with a reduced Conradson carbon, metals, sulphur and nitrogen content, b) one or more optional steps for separating the effluent obtained from step a) in order to obtain at least one light liquid fraction boiling at a temperature of less than 350° C. and a heavy liquid fraction boiling at a temperature of more than 350° C., c) a step for hydroconversion of the liquid effluent obtained from the hydroconversion step a) in the case in which the separation step b) is not carried out, or of the heavy liquid fraction obtained from the separation step b) when said step b) is carried out, in the presence of hydrogen in at least one or more three-phase reactors disposed in series or in parallel and containing at least one hydroconversion catalyst, in which process the overall hourly space velocity employed is in the range 0.05 to 0.18 h−1.
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公开(公告)号:US20180179453A1
公开(公告)日:2018-06-28
申请号:US15783777
申请日:2017-10-13
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Stanley J. Frey , Hayim Abrevaya , Falaah Falih
CPC classification number: C10G47/04 , B01D3/14 , B01J29/40 , C07C4/06 , C07C4/18 , C07C15/40 , C07C2529/06 , C07C2529/40 , C10G47/24 , C10G2400/30 , Y02P20/52 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/04
Abstract: A naphtha cracking feed stream is taken, heated and passed to a cracking reactor. Hydrogen is added to the cracking reactor to mitigate catalyst deactivation. The aliphatic compounds are selectively cracked and at least a portion of the alkyl groups on the aromatic compounds are selectively dealkylated in the presence of a cracking catalyst to produce a cracked effluent stream comprising aromatic compounds and cracked olefins.
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公开(公告)号:US09994779B2
公开(公告)日:2018-06-12
申请号:US15182319
申请日:2016-06-14
Applicant: INSTITUTO MEXICANO DEL PETROLEO
Inventor: Jorge Ancheyta Juarez , Sergio Ramirez Amador , Zenaida Carolina Leyva Inzunza , Alexander Quitian Arciniegas
IPC: C10G47/02 , C10G47/04 , C10G47/24 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/14 , C10G49/10 , C10G65/14
CPC classification number: C10G47/04 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/14 , C10G47/02 , C10G47/24 , C10G49/10 , C10G65/14 , C10G2300/302 , C10G2300/308
Abstract: The present invention relates to a catalytic hydroconversion process in dispersed phase of extra-heavy and heavy crude oils for upgrading their transport properties, that operates at low severity conditions, in such a way that the obtained product can be transported by conventional pumping to the distribution and refining centers.The main technical contributions of the hydroconversion process in dispersed phase of this invention to upgrade the transport properties of heavy and extra-heavy crudes are: Compact size and can be localized next to the production facilities on ground or offshore Use of operating conditions at low severity Reduction of the viscosity and increase of the API gravity at values that allow the transportation by pipeline of heavy or extra-heavy crude Upgrading of the crude oil properties in a permanent way Hydrocarbon and gases from production centers are used as supplies Operation in dispersed phase avoiding plugging problems Use of low-cost disposable catalysts at low concentrations.
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公开(公告)号:US20170306252A1
公开(公告)日:2017-10-26
申请号:US15496921
申请日:2017-04-25
Applicant: Sherritt International Corporation
CPC classification number: C10G65/10 , C10G45/00 , C10G45/58 , C10G47/00 , C10G47/04 , C10G47/06 , C10G47/26 , C10G49/12 , C10G65/00
Abstract: A process is provided to partially upgrade heavy oil using two or more reaction zones connected in series, each reaction zone being a continuous stirred tank maintained at hydrocracking conditions. The heavy oil feedstock and a solid particulate catalyst are stirred to form pumpable slurry which is heated to a target hydrocracking temperature and then continuously fed to the first reaction zone. Hydrogen is continuously introduced to the reaction zone to achieve hydrocracking and to produce a volatile vapour stream carried upwardly by the hydrogen to produce an overhead vapour stream. The hydrocracked heavy oil slurry from one reaction zone is fed to a next reaction zone also maintained under hydrocracking conditions with a continuous hydrogen feed to produce a volatile vapour stream. The overhead vapour stream from each reactor zone is continuously removed, and the hydrocracked heavy oil slurry from the last of the reaction zones is removed.
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公开(公告)号:US20160333272A1
公开(公告)日:2016-11-17
申请号:US15218258
申请日:2016-07-25
Applicant: Epic Oil Extractors, LLC
Inventor: Richard H. Schlosberg , Edward L. Diefenthal , Richard D. Jordan
CPC classification number: C10G1/002 , C10G1/04 , C10G1/042 , C10G1/045 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/00 , C10G47/02 , C10G47/04 , C10G2300/1033 , C10G2300/202 , C10G2400/02 , C10G2400/04 , C10G2400/08
Abstract: Disclosed are processes for producing deasphalted bitumen and heavy bitumen compositions from oil sands and processes for upgrading the bitumen compositions. The processes for producing the deasphalted bitumen and heavy bitumen compositions involve a Phase I and/or Phase II extraction solvent. According to the Phase I process, a high quality oil sands-derived, deasphalted bitumen can be produced using a Phase I type solvent. According to the Phase II process, a substantial amount of the heavy bitumen on the oil sand can be extracted using a Phase II type solvent, while producing a relatively a tailings by-product that is non-harmful to the environment. The heavy bitumen from the Phase II type extraction process can be hydroprocessed for ready conversion into relatively high volumes of high quality transportation fuels.
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