PROCESS TO PREPARE PARAFFINS AND WAXES
    6.
    发明申请

    公开(公告)号:US20180258354A1

    公开(公告)日:2018-09-13

    申请号:US15756247

    申请日:2016-09-01

    申请人: SHELL OIL COMPANY

    摘要: A process for preparing paraffins and waxes includes providing a gas mixture comprising hydrogen and carbon monoxide to at least two conversion reactors for catalytically converting the gas mixture to obtain an initial Fischer-Tropsch product comprising paraffins having from 5 to 300 carbon atoms. The initial Fischer-Tropsch product streams from each of the reactors are combined before being subjected to a hydrogenation step. The hydrogenated product stream is separated into C5-C9, C10-C17 and C18-300 fractions. The C18-C300 fraction is separated to obtain one or more light waxes having a congealing point in the range of 30 to 75° C. and a heavy wax having a congealing point in the range of 75 to 120° C. The relative concentrations of the C5-C9 and the C10-C17 fractions, and the concentrations of the light and heavy waxes is changed by raising, lowering or maintaining the reaction temperature of at least one of the reactors.

    PROCESS FOR THE PRODUCTION OF BIODEGRADABLE HYDROCARBON FLUIDS

    公开(公告)号:US20180148656A1

    公开(公告)日:2018-05-31

    申请号:US15574569

    申请日:2016-05-20

    IPC分类号: C10G45/60

    摘要: The invention provides for a process for preparing a fluid having a boiling point in the range of from 100 to 400° C. and comprising more than 95% isoparaffins and containing less than 100 ppm aromatic, comprising the step of catalytically hydrogenating a feed comprising more than 95% by weight of a hydrodeoxygenated isomerized hydrocarbon biomass feedstock, at a temperature from 80 to 180° C. and at a pressure from 50 to 60 bars. The invention also provides for a fluid having a boiling point in the range of from 100 to 400° C. and a boiling range below 80° C., said fluid comprising more than 95% isoparaffins and less than 3% of naphthens by weight and having a ratio of iso-paraffins to n-paraffins of at least 12:1, a biodegradability at 28 days of at least 60%, as measured according to the OECD 306 standard, a biocarbon content of at least 95% by weight, containing less than 100 ppm aromatics by weight, and comprising carbon expressed as CH3 sat less than 30%.