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公开(公告)号：US20180318811A1
公开(公告)日：2018-11-08
申请号：US15963303
申请日：2018-04-26
Applicant: ExxonMobil Research and Engineering Company
Inventor： Chuansheng BAI , Paul PODSIADLO , Stephen J. McCARTHY
CPC classification number: B01J29/48 , B01J29/076 , B01J29/7861 , B01J35/1019 , B01J37/0203 , B01J37/0236 , B01J37/024 , B01J37/18 , B01J37/20 , B01J2229/186 , B01J2229/20 , B01J2229/34 , B01J2229/42 , C10G45/64 , C10G65/043
Abstract: Methods, catalysts, and corresponding catalyst precursors are provided for performing dewaxing of diesel or distillate boiling range fractions. The dewaxing methods, catalysts, and/or catalyst precursors can allow for production of diesel boiling range fuels with improved cold flow properties at desirable yields. The catalysts and/or catalyst precursors can correspond to supported metal catalysts and/or catalyst precursors that include at least one noble metal, such as Pt, at least one Group 8-10 base metal, preferably a non-noble Group 8-10 base metal, such as Ni and/or Co along with a Group 6 metal, such as Mo and/or W as supported metals along. The support can include a zeolitic framework structure. The catalyst precursors can be formed, for example, by impregnating a support including a zeolitic framework structure with impregnation solution(s) that also includes a dispersion agent.
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公开(公告)号：US20170080410A1
公开(公告)日：2017-03-23
申请号：US15243007
申请日：2016-08-22
Applicant: ExxonMobil Research and Engineering Company
Inventor： Majosefina CUNNINGHAM , Jason M. GOLIAS , Chuansheng BAI
CPC classification number: B01J31/34 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/049 , B01J27/0515 , B01J31/04 , B01J31/069 , B01J31/124 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J37/0018 , B01J37/084 , B01J37/086 , B01J37/20 , C10G45/08
Abstract: Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m2/g or less.
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公开(公告)号：US20190338203A1
公开(公告)日：2019-11-07
申请号：US16512601
申请日：2019-07-16
Applicant: ExxonMobil Research and Engineering Company
Inventor： Benjamin S. UMANSKY , Himanshu GUPTA , John D. NELSON , Cindy J. HUGHART , Jane C. CHENG , Steven W. LEVINE , Stephen H. BROWN , Todd P. MARUT , David C. DANKWORTH , Stuart L. SOLED , Thomas F. DEGNAN, JR. , Robert J. FALKINER , Mohsen N. HARANDI , Juan D. HENAO , Lei ZHANG , Chuansheng BAI , Richard C. DOUGHERTY
IPC: C10G65/12 , B01J23/882 , C10G67/14 , C10G45/16 , C10G31/09 , C10G45/08 , B01J27/19 , B01J35/10 , C10G47/04 , B01J23/885
Abstract: Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
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Patent Agency Ranking
公开(公告)号：US20180162789A1
公开(公告)日：2018-06-14
申请号：US15839974
申请日：2017-12-13
Applicant: ExxonMobil Research and Engineering Company
Inventor： Sophie LIU , Jihad M. DAKKA , Partha NANDI , Sara YACOB , Quddus A. NIZAMI , Chuansheng BAI
Abstract: Methods and systems for converting hydrocarbons including exposing a portion of a hydroperoxide-containing feed including tert-butyl hydroperoxide to a solid deperoxidation catalyst under decomposition conditions to form an oxidation effluent comprising tert-butyl alcohol, wherein the solid deperoxidation catalyst comprises a manganese oxide octahedral molecular sieve, are provided herein. Further methods and systems for converting the oxidation effluent to an alkylation product are also provided herein.
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公开(公告)号：US20180250662A1
公开(公告)日：2018-09-06
申请号：US15902211
申请日：2018-02-22
Applicant: ExxonMobil Research and Engineering Company
Inventor： Chuansheng BAI , Paul PODSIADLO , Stephen J. McCARTHY
IPC: B01J27/051 , B01J29/40 , B01J21/04 , B01J35/00 , B01J37/02 , B01J37/20 , B01J37/00 , C10G45/64 , C10G65/04
CPC classification number: B01J27/0515 , B01J21/04 , B01J27/049 , B01J29/40 , B01J29/48 , B01J29/7861 , B01J35/0006 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0203 , B01J37/0213 , B01J37/0236 , B01J37/20 , B01J2229/42 , C10G45/50 , C10G45/54 , C10G45/62 , C10G45/64 , C10G49/04 , C10G49/08 , C10G65/04 , C10G65/043 , C10G2300/1048 , C10G2300/202
Abstract: Methods, catalysts, and corresponding catalyst precursors are provided for performing dewaxing of diesel or distillate boiling range fractions. The dewaxing methods, catalysts, and/or catalyst precursors can allow for production of diesel boiling range fuels with improved cold flow properties at desirable yields. The catalysts and/or catalyst precursors can correspond to supported base metal catalysts and/or catalyst precursors that include at least two Group 8-10 base metals supported on the catalyst, such as a catalyst/catalyst precursor including both Ni and Co as supported metals along with a Group 6 metal (i.e., Mo and/or W). The support can correspond to a support including a zeolitic framework structure. The catalyst precursors can be formed, for example, by impregnating a support including a zeolitic framework structure with an impregnation solution that also includes a dispersion agent.
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公开(公告)号：US20180002617A1
公开(公告)日：2018-01-04
申请号：US15626288
申请日：2017-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Benjamin S. UMANSKY , Himanshu GUPTA , John D. NELSON , Cindy J. HUGHART , Jane C. CHENG , Steven W. LEVINE , Stephen H. BROWN , Todd P. MARUT , David C. DANKWORTH , Stuart L. SOLED , Thomas F. DEGNAN, JR. , Robert J. FALKINER , Mohsen N. HARANDI , Juan D. HENAO , Lei ZHANG , Chuansheng BAI , Richard C. DOUGHERTY
CPC classification number: C10G65/12 , B01J23/882 , B01J23/885 , B01J27/19 , B01J35/1028 , B01J35/1038 , B01J35/1047 , B01J35/1061 , C10G31/09 , C10G45/08 , C10G45/16 , C10G47/04 , C10G67/14 , C10G2300/202 , C10G2300/205
Abstract: Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
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公开(公告)号：US20170297986A1
公开(公告)日：2017-10-19
申请号：US15455181
申请日：2017-03-10
Applicant: ExxonMobil Research and Engineering Company
Inventor： Anita S. LEE , Jihad M. DAKKA , Arun K. SHARMA , Michel DAAGE , Preeti KAMAKOTI , Ronald SURYO , Chuansheng BAI , J. Timothy CULLINANE
IPC: C07C41/09 , C01B3/34 , C07C29/151
CPC classification number: C07C41/09 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/06 , C01B2203/061 , C07C29/151 , C07C41/01 , C07C43/043
Abstract: Integrated methods and systems are disclosed for the production of dimethyl ether. The method may include reforming natural gas to syngas in a first reactor; contacting the syngas produced in the first reactor with a catalyst system in a second reactor to produce dimethyl ether and carbon dioxide; and supplying steam as a cofeed to at least one of the first reactor and the second reactor in an amount sufficient to achieve a Mm value of 1.4 to 1.8 or to improve the hydrocarbon or oxygenate selectivity.
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公开(公告)号：US20170175011A1
公开(公告)日：2017-06-22
申请号：US15364869
申请日：2016-11-30
Applicant: ExxonMobil Research and Engineering Company
Inventor： Stephen J. McCARTHY , Chuansheng BAI , Wenyih Frank LAI , Paul PODSIADLO , William W. LONERGAN
Abstract: Methods are provided for making base metal catalysts with improved activity. After forming catalyst particles based on a support comprising a zeolitic molecular sieve, the catalyst particles can be impregnated with a solution comprising a) metal salts (or other precursors) for a plurality of base metals and b) an organic dispersion agent comprising 2 to 10 carbons. The impregnated support particles can be dried to form a base metal catalyst, and then optionally sulfided to form a sulfided base metal catalyst. The resulting (sulfided) base metal catalyst can have improved activity for cloud point reduction and/or for improved activity for heteroatom removal, relative to a base metal dewaxing catalyst prepared without the use of a dispersion agent.
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