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公开(公告)号:US12053765B2
公开(公告)日:2024-08-06
申请号:US16891442
申请日:2020-06-03
Applicant: University of New Hampshire
Inventor: Gonghu Li , Anatoly Frenkel , Peipei Huang , Jiahao Huang
IPC: B01J31/18 , B01J35/39 , B01J37/04 , C01B32/40 , C07D487/16
CPC classification number: B01J31/1815 , B01J35/39 , B01J37/04 , C01B32/40 , C07D487/16 , B01J2231/005 , B01J2231/625 , B01J2531/845
Abstract: A composition of a photocatalyst, a method of manufacturing the photocatalyst, and a method of chemically reducing carbon dioxide to carbon monoxide using the photocatalyst under visible-light irradiation is provided. The photocatalyst comprises a transition metal ion and graphitic carbon nitride and includes single metal sites on carbon nitride. Under visible light, the metal sites that are coordinated to nitrogen atoms get activated, without the use of additional ligands, to catalyze the reduction of carbon dioxide to selectively produce carbon monoxide. The photocatalytic reduction of carbon dioxide to carbon monoxide is highly efficient, resulting a turnover number of more than 800 for carbon monoxide production in 2 hours. The composition is useful in converting carbon dioxide into useful chemicals and carbon-based fuels. A functional model of molecular catalysts for efficient carbon dioxide reduction is also present.
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公开(公告)号:US11926710B2
公开(公告)日:2024-03-12
申请号:US16234062
申请日:2018-12-27
Applicant: UNIVERSITY OF SOUTHERN CALIFORNIA
Inventor: Travis J. Williams , Steven Nutt , Yijia Ma , Carlos Navarro
IPC: C08J11/28 , B01J31/22 , B29B17/02 , C01B32/05 , C01B32/354 , C08K3/012 , C08K5/00 , C08K7/06 , D01F9/12 , C08K3/16 , C08K3/22 , D01F9/00
CPC classification number: C08J11/28 , B01J31/2217 , B29B17/0206 , C01B32/05 , C01B32/382 , C08K3/012 , C08K5/0033 , C08K7/06 , D01F9/12 , B01J2231/70 , B01J2531/0252 , B01J2531/16 , B01J2531/72 , B01J2531/74 , B01J2531/845 , C08J2363/00 , C08K3/16 , C08K3/22 , C08K5/0091 , D01F9/00 , C08K5/0033 , C08L63/00 , C08K7/06 , C08L63/00 , C08K3/012 , C08L63/00
Abstract: A method of aerobic depolymerization of fiber-reinforced polymer (FRP) composites using sustainable reagents and conditions. A cured matrix is digested into soluble monomers and oligomers by catalytic aerobic oxidation. Carbon fibers are removed for re-use, then the remaining material is treated and valuable monomers are isolated. The isolated monomers can be converted back into resin precursors for re-use. The method solves the problem created because the typically irreversible cure reaction impedes recycling and re-use of FRP composites.
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公开(公告)号:US20240052250A1
公开(公告)日:2024-02-15
申请号:US18257944
申请日:2021-10-26
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Ravichander NARAYANASWAMY , Alexander STANISLAUS , Girish KORIPELLY , Sivakumar PERIYASAMY , Sadasivam GOPALAKRISHNAN , Ranjith PUTHANVEEDU , Anilkumar METTU
CPC classification number: C10G51/04 , B01J31/04 , B01J29/40 , C10G2300/1003 , C10G2300/1088 , C10G2300/1096 , C10G2300/4006 , B01J2531/845
Abstract: Systems and methods for processing a plastic are disclosed. The system includes a feeding device in fluid communication with a cracking unit. A feed stream comprising a plastic is depolymerized in the feeding device at a depolymerization temperature to produce a hydrocarbonaceous wax stream. The hydrocarbonaceous wax stream is then cracked in the cracking unit. The cracking is conducted at a cracking temperature that is lower than, or the same as the depolymerization temperature.
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公开(公告)号:US11896947B2
公开(公告)日:2024-02-13
申请号:US16916110
申请日:2020-06-30
Applicant: Battelle Memorial Institute
Inventor: Radha Kishan Motkuri , Jagannadha R. Bontha , B. Peter McGrail
IPC: B01J19/10 , B01J19/06 , B01J19/00 , B01J20/22 , B01J20/30 , B01J31/16 , B01J35/02 , B01J37/00 , C07F15/06 , C07F3/00 , C07C63/307 , C07F15/04 , C07C65/05 , C07C51/43 , C07C51/41 , B01J20/32 , C07F7/00
CPC classification number: B01J19/10 , B01J19/0013 , B01J19/06 , B01J20/226 , B01J20/3085 , B01J20/3204 , B01J20/3236 , B01J20/3293 , B01J31/1691 , B01J35/026 , B01J37/0072 , C07C51/418 , C07C51/43 , C07C63/307 , C07C65/05 , C07F3/003 , C07F7/003 , C07F15/045 , C07F15/065 , B01J2219/00051 , B01J2219/0877 , B01J2231/005 , B01J2531/16 , B01J2531/845 , B01J2531/847 , C07C51/418 , C07C65/05 , C07C51/43 , C07C65/05 , C07C51/418 , C07C63/307 , C07C51/43 , C07C63/307
Abstract: A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.
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公开(公告)号:US11826736B2
公开(公告)日:2023-11-28
申请号:US17536850
申请日:2021-11-29
Applicant: Merichem Company
Inventor: Zhouyang Liu , Nachiketa Anand
CPC classification number: B01J27/20 , B01J31/0232 , B01J31/183 , B01J37/04 , B01J37/24 , B01J37/36 , C12P17/182 , B01J2231/005 , B01J2531/845
Abstract: A method of producing a catalytic carbon fiber may include: providing a carbon fiber and an aminated macrocycle, mixing the carbon fiber and the aminated macrocycle with a solvent; and reacting the carbon fiber and the aminated macrocycle to form an amide bond between the carbon fiber and the aminated macrocycle thereby forming the catalytic carbon fiber.
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公开(公告)号:US20230202954A1
公开(公告)日:2023-06-29
申请号:US17813213
申请日:2020-12-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Hans Goris , Dries Timmermans , Stephen Beadle , Thomas Wesselmann , Alex Carpenter , Travis Reine , Edwin Kooke , Byron Sevin , Zsigmond Varga , Bradley Kontra
CPC classification number: C07C45/505 , B01J31/20 , B01J2531/845 , B01J2231/321
Abstract: Catalyst preforming rates during hydroformylation may decrease in the presence of carbonates. Carbonate mitigation methods may comprise treating a hydroformylation reaction product with an aqueous carboxylic acid under oxidizing conditions to form a deactivated catalyst aqueous solution having a pH of about 4 or less, reducing the hydroformylation reaction product to form a reduced reaction product, conveying a gas stream through the reduced reaction product to strip carbon dioxide therefrom, contacting caustic aqueous solution with the stripped reduced reaction product to form partially spent caustic aqueous solution, combining at least a portion of the partially spent caustic aqueous solution with the deactivated catalyst aqueous solution to form a combined aqueous mixture sufficiently acidic to decompose carbonate, and extracting a Group 9 transition metal carboxylate from the combined aqueous mixture into an organic phase.
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公开(公告)号:US20230166243A1
公开(公告)日:2023-06-01
申请号:US17536850
申请日:2021-11-29
Applicant: Merichem Company
Inventor: Zhouyang Liu , Nachiketa Anand
CPC classification number: B01J27/20 , B01J37/24 , B01J37/36 , B01J37/04 , B01J31/183 , B01J31/0232 , C12P17/182 , B01J2531/845 , B01J2231/005
Abstract: A method of producing a catalytic carbon fiber may include: providing a carbon fiber and an aminated macrocycle, mixing the carbon fiber and the aminated macrocycle with a solvent; and reacting the carbon fiber and the aminated macrocycle to form an amide bond between the carbon fiber and the aminated macrocycle thereby forming the catalytic carbon fiber.
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公开(公告)号:US20180154343A1
公开(公告)日:2018-06-07
申请号:US15883862
申请日:2018-01-30
Applicant: SK INNOVATION CO., LTD.
Inventor: Sang Il LEE , Do Woan KIM , Jae Hyun KOH , Seung Hoon OH , Hee Jung JEON , Sang Heup MOON , A Ra CHO , Young Moo PARK
IPC: B01J31/02 , C10G45/08 , B01J37/06 , B01J31/34 , B01J31/38 , B01J37/08 , B01J37/02 , B01J23/888 , B01J23/88 , B01J35/02 , B01J31/22 , B01J31/12 , B01J37/20 , B01J37/18 , B01J23/882
CPC classification number: B01J31/0209 , B01J23/88 , B01J23/882 , B01J23/888 , B01J31/0201 , B01J31/0207 , B01J31/0208 , B01J31/12 , B01J31/2208 , B01J31/2213 , B01J31/2234 , B01J31/34 , B01J31/38 , B01J35/023 , B01J37/0201 , B01J37/0205 , B01J37/0219 , B01J37/024 , B01J37/06 , B01J37/088 , B01J37/18 , B01J37/20 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08
Abstract: Embodiments of the invention relate to a method for preparing a hydroprocessing catalyst including supporting a carrier with one or more hydrogenation metal components selected from the group consisting of VIB, VIIB, and VIII group metals of the periodic table; drying and calcining the supported carrier having the hydrogenation metal components; supporting the supported carrier having the hydrogenation metal components with an organic compound, and drying and calcining the supported carrier having the hydrogenation metal components and the organic compound. The hydrogenation metal components and the organic compound are supported in the carrier. The organic compound is selected from the group consisting of methyl acetoacetate, ethyl acetoacetate and a mixture thereof. The hydrogenation metal components supported in the carrier is sulfide. An amount of the organic compound is 15 wt % to 90 wt % based on the total amount of the hydroprocessing catalyst.
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公开(公告)号:US09835117B2
公开(公告)日:2017-12-05
申请号:US15035390
申请日:2014-11-19
Applicant: HONDA MOTOR CO., LTD.
Inventor: Kohtaro Hashimoto
CPC classification number: F02M27/02 , B01J8/001 , B01J8/02 , B01J8/0221 , B01J8/0278 , B01J8/0285 , B01J31/0247 , B01J31/2239 , B01J2208/00212 , B01J2208/00548 , B01J2208/00628 , B01J2208/02 , B01J2231/70 , B01J2531/72 , B01J2531/845 , C10G2300/104 , C10G2300/1044 , C10G2300/305 , C10G2300/4037 , C10G2400/02 , C10L1/06 , C10L1/182 , C10L10/10 , C10L2200/0423 , C10L2270/023 , C10L2290/06 , C10L2290/24 , C10L2290/58
Abstract: Provided is a fuel reforming system that can convert gasoline into alcohol in a vehicle. Provided is a fuel reforming system (1) equipped with a reformer (15) having a reforming catalyst (152) that uses air to reform gasoline to produce alcohol, a mixer (14) which mixes gasoline and air and supplies the mixture to the reformer (15), and a condenser (16) which separates the gas produced in the reformer (15) into a gas phase and a condensed phase of which reformed fuel is the primary constituent; wherein the fuel reforming system (1) is characterized in that the reforming catalyst (152) is configured including a main catalyst for extracting hydrogen atoms from the hydrocarbons in the gasoline to produce alkyl radicals, and a catalytic promoter for reducing alkyl hydroperoxides produced from the alkyl radicals to produce alcohol.
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公开(公告)号:US09782763B2
公开(公告)日:2017-10-10
申请号:US13325250
申请日:2011-12-14
Applicant: Keith James Weller , Crisita Carmen H. Atienza , Julie Boyer , Paul Chirik , Johannes G. P. Delis , Kenrick Lewis , Susan A. Nye
Inventor: Keith James Weller , Crisita Carmen H. Atienza , Julie Boyer , Paul Chirik , Johannes G. P. Delis , Kenrick Lewis , Susan A. Nye
CPC classification number: B01J31/1805 , B01J2231/323 , B01J2531/0244 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847
Abstract: Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.
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