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1.
公开(公告)号:US10550049B2
公开(公告)日:2020-02-04
申请号:US15867403
申请日:2018-01-10
Applicant: UOP LLC
Inventor: Erin M. Broderick , Avram M. Buchbinder , Alakananda Bhattacharyya
Abstract: A hydrocarbon conversion process is described. The process involves contacting a hydrocarbon feed with a non-cyclic amide or thioamide based ionic liquid catalyst in a reaction zone under reaction conditions to form a mixture comprising reaction products, and the non-cyclic amide or thioamide based ionic liquid catalyst. Typical hydrocarbon conversion processes include alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation.
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公开(公告)号:US10252956B2
公开(公告)日:2019-04-09
申请号:US16035851
申请日:2018-07-16
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Erin M. Broderick , Susie C. Martins , Alakananda Bhattacharyya , Stuart Smith
Abstract: A process utilizing an ionic liquid is described. The process includes contacting a hydrocarbon feed with an ionic liquid component, the ionic liquid component comprising a mixture of a first ionic liquid and a viscosity modifier, wherein a viscosity of the ionic liquid component is at least about 10% less than a viscosity of the first ionic liquid.
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公开(公告)号:US20180319718A1
公开(公告)日:2018-11-08
申请号:US16035851
申请日:2018-07-16
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Erin M. Broderick , Susie C. Martins , Alakananda Bhattacharyya , Stuart Smith
CPC classification number: C07C2/60 , B01J31/0277 , C07C2527/125 , C07C2531/02 , C07C9/21
Abstract: A process utilizing an ionic liquid is described. The process includes contacting a hydrocarbon feed with an ionic liquid component, the ionic liquid component comprising a mixture of a first ionic liquid and a viscosity modifier, wherein a viscosity of the ionic liquid component is at least about 10% less than a viscosity of the first ionic liquid.
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4.
公开(公告)号:US20180127334A1
公开(公告)日:2018-05-10
申请号:US15867403
申请日:2018-01-10
Applicant: UOP LLC
Inventor: Erin M. Broderick , Avram M. Buchbinder , Alakananda Bhattacharyya
CPC classification number: C07C2/60 , B01J31/0205 , B01J31/0215 , B01J31/0279 , B01J31/0285 , B01J31/40 , C07C2/58 , C07C2531/02 , C10G50/00 , C10G2400/02
Abstract: A hydrocarbon conversion process is described. The process involves contacting a hydrocarbon feed with a non-cyclic amide or thioamide based ionic liquid catalyst in a reaction zone under reaction conditions to form a mixture comprising reaction products, and the non-cyclic amide or thioamide based ionic liquid catalyst. Typical hydrocarbon conversion processes include alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation.
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公开(公告)号:US09914674B2
公开(公告)日:2018-03-13
申请号:US14675175
申请日:2015-03-31
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Susie C. Martins , Erin M. Broderick , Paul T. Barger , Alakananda Bhattacharyya , Douglas A. Nafis
CPC classification number: C07C2/60 , C07C2527/126 , C07C2531/02 , C10G29/205 , C10G2300/305 , C10L1/06 , C10L10/10 , C10L2270/023 , C07C9/21
Abstract: An alkylation process utilizing less than 10 vol % of a halometallate based ionic liquid catalyst is described. By decreasing the catalyst volume fraction, the level of subsequent undesirable reactions may be minimized. The total residence time is typically in the range of about 1 min to about 30 min. The alkylate typically has a research octane number of at least about 93, and the olefin conversion is typically at least about 96%.
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公开(公告)号:US20160289138A1
公开(公告)日:2016-10-06
申请号:US14675203
申请日:2015-03-31
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Douglas A. Nafis , Alakananda Bhattacharyya , Susie C. Martins
CPC classification number: C07C2/60 , C07C2527/125 , C07C2531/02 , C07C2531/22 , C10G29/205 , C10G2300/305 , C10L1/04 , C10L1/06 , C10L10/10 , C10L2270/00 , C07C9/21
Abstract: Alkylation processes are described. The processes utilize ionic liquid catalysts having a kinematic viscosity range of about 50 cSt to about 100 cSt at 25° C. Catalysts within this range produce alkylate having higher octane than catalysts outside this range, especially at higher process temperatures which are preferable from an operating cost standpoint. The alkylate can have one or more of a research octane number of at least about 93, a selectivity of C8 of at least about 65%, and a mole ratio of trimethylpentane to dimethylhexane of greater than about 7:1.
Abstract translation: 描述了烷基化方法。 该方法利用在25℃下运动粘度范围为约50cSt至约100cSt的离子液体催化剂。在该范围内的催化剂产生具有比该范围以外的催化剂具有更高辛烷值的烷基化物,特别是在较高的工艺温度下, 成本立场。 烷基化物可以具有至少约93的研究辛烷值,至少约65%的C8的选择性和大于约7:1的三甲基戊烷与二甲基己烷的摩尔比的一种或多种。
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7.
公开(公告)号:US20140171680A1
公开(公告)日:2014-06-19
申请号:US13715571
申请日:2012-12-14
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Alakananda Bhattacharyya , Joel T. Walenga
IPC: C07C51/487
CPC classification number: C07C51/367 , C07C51/16 , Y02P20/542 , C07C65/03 , C07C63/26
Abstract: A method of decreasing an amount of an aromatic aldehyde in a product is described. The method includes reacting the aromatic aldehyde in the presence of a reaction medium comprising a nucleophilic solvent, or an ionic liquid and a carboxylic acid, the reaction taking place in the absence of a hydrogenating agent and an oxidizing agent, to form aromatic carboxylic acid, an aromatic alcohol, or both.
Abstract translation: 描述了减少产物中芳族醛的量的方法。 该方法包括在包含亲核溶剂或离子液体和羧酸的反应介质的存在下使芳醛反应,该反应发生在不存在氢化剂和氧化剂的情况下,形成芳族羧酸, 芳香醇,或两者。
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公开(公告)号:US20240217899A1
公开(公告)日:2024-07-04
申请号:US18394840
申请日:2023-12-22
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , Stanley Joseph Frey , Zhanyong LI , Krishna Mani , Richa Sharma , Krishan Pratap Jadaun , Eseoghene Jeroro
CPC classification number: C07C4/06 , C07C7/12 , C07C2523/28 , C07C2523/42 , C07C2523/755
Abstract: A biorenewable feed that is concentrated in free fatty acids is produced by hydrodeoxygenating a biorenewable feedstock is produced by use of a Group VIII catalyst producing a 10-13 carbon atom product having a high level of linearity. Normal paraffins in the range desired by the detergents industry can be produced. Either isomerization or an iso-normal separation can be performed to provide green fuel streams.
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公开(公告)号:US20220126281A1
公开(公告)日:2022-04-28
申请号:US17570178
申请日:2022-01-06
Applicant: UOP LLC
Inventor: Avram M. Buchbinder , John J. Senetar , Richard A. Johnson, II , Sathit Kulprathipanja , Wei Pan
Abstract: A process for regenerating spent catalyst by combusting coke and fuel gas together in the presence of enriched oxygen restores activity to the catalyst to bring back to adequate activity level while reducing or obviating the need for the oxygen treatment step. The oxygen concentration in the oxygen supply gas should be greater than 21 vol %.
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公开(公告)号:US20180127352A1
公开(公告)日:2018-05-10
申请号:US15866393
申请日:2018-01-09
Applicant: UOP LLC
Inventor: Erin M. Broderick , Avram M. Buchbinder , Alakananda Bhattacharyya
IPC: C07C233/89 , C07C231/12
CPC classification number: C07C233/89 , C07C2/58 , C07C231/12 , C07C2527/125 , C07C9/16
Abstract: Non-cyclic amide or thioamide based ionic liquids and methods of making them are disclosed. The non-cyclic amide or thioamide based ionic liquid comprises a cation and an anion and has the formula:
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