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    Osmium oxide carried by hydrophilic polymer
    8.
    发明授权
    Osmium oxide carried by hydrophilic polymer 失效
    由亲水聚合物携带的氧化镉

    公开(公告)号：US07122499B2

    公开(公告)日：2006-10-17

    申请号：US10469238

    申请日：2002-03-08

    申请人： Shu Kobayashi

    发明人： Shu Kobayashi

    IPC分类号： B01J31/00 ,  B01J23/40 ,  B01J23/42 ,  C07C45/00 ,  C07C29/04

    CPC分类号： B01J23/466 ,  B01J31/06 ,  B01J31/1616 ,  B01J2231/70 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/48 ,  C07C45/30 ,  C07C47/54 ,  C07C33/26

    摘要： A carrier for carrying an osmium oxide comprising an aromatic polyolefin polymer having a group shown by the general formula [1] as a substituent on the aromatic ring of said polyolefin polymer: —A′—O(—A—O)n—R[1] (wherein A is an alkylene group; A′ is a direct link or an alkylene group; R is an aryl group; and n is an integer of 1 to 10), an osmium oxide carried by the carrier for carrying an osmium oxide and a method for producing the osmium oxide carried by said carrier are disclosed. Since the osmium oxide carried by the carrier of the present invention has a hydrophilic group, in an oxidation reaction and an asymmetric oxidation reaction, particularly in a heterogeneous solvent system, the osmium oxide carried by the carrier of the present invention enables to produce a diol compound easily and in a high optical yield.

    摘要翻译： 用于承载氧化钕的载体，其包含具有通式[1]所示基团的芳族聚烯烃聚合物作为所述聚烯烃聚合物的芳族环上的取代基：<？在线配方描述=“在线配方” end =“lead”？> - A'-O（-AO）n -R [1] <？in-line-formula description =“In-line Formulas”end =“tail”？ >（其中A是亚烷基; A'是直链或亚烷基; R是芳基; n是1至10的整数），由载体氧化锇承载的氧化锇和 公开了一种用于制造由所述载体承载的氧化锇的方法。 由于本发明的载体携带的氧化锇具有亲水基团，在氧化反应和不对称氧化反应中，特别是在非均相溶剂体系中，本发明的载体携带的氧化锇能够制备二醇 化合物容易和高光学收率。

    Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
    9.
    发明授权
    Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts 有权
    六配位钌或锇金属卡宾复分解催化剂

    公开(公告)号：US06818586B2

    公开(公告)日：2004-11-16

    申请号：US10172765

    申请日：2002-06-14

    申请人： Robert H. Grubbs ,  Melanie S. Sanford ,  Jason L. Moore ,  Jennifer A. Love ,  Tina M. Trnka

    发明人： Robert H. Grubbs ,  Melanie S. Sanford ,  Jason L. Moore ,  Jennifer A. Love ,  Tina M. Trnka

    IPC分类号： B01J3100

    CPC分类号： C07C6/04 ,  B01J23/462 ,  B01J23/466 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/182 ,  B01J31/1825 ,  B01J31/183 ,  B01J31/2273 ,  B01J31/28 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/06 ,  C07C2531/22 ,  C07F15/002 ,  C07F15/0046 ,  C08G61/06

    摘要： The present invention relates to novel hexacoordinated metathesis catalysts and to methods for making and using the same. The inventive catalysts are of the formula wherein: M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; L, L1′ and L2 are the same or different and are each independently a neutral electron donor ligand; and, R and R1 are each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl and silyl. Optionally, each of the R or R1 substituent group may be substituted with one or more moieties selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, and aryl which in turn may each be further substituted with one or more groups selected from a halogen, a C1-C5 alkyl, C1-C5 alkoxy, and phenyl. Moreover, any of the catalyst ligands may further include one or more functional groups. Examples of suitable functional groups include but are not limited to: hydroxyl, thiol, thioether, ketone, aldehyde, ester, ether, amine, imine, amide, nitro, carboxylic acid, disulfide, carbonate, isocyanate, carbodiimide, carboalkoxy, carbamate, halogen, alcohol, sulfonic acid, phosphine, imide, acetal, ketal, boronate, cyano, cyanohydrin, hydrazine, enamine, sulfone, sulfide, and sulfenyl. In certain embodiments, at least one of L, L1′ and L2 is an N-heterocyclic carbene ligand.

    摘要翻译： 本发明涉及新型六配位复分解催化剂及其制备和使用方法。 本发明的催化剂为糠醛：M是钌或锇; X和X 1相同或不同，各自独立地为阴离子配位体; L，L 1和L 2相同或不同 并且各自独立地为中性电子给体配体; 和R 1和R 2各自独立地为氢或选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基， C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基和甲硅烷基。 任选地，R或R ​​1取代基中的每一个可以被一个或多个选自以下的部分取代：C 1 -C 10烷基，C 1 -C 10烷氧基和芳基，其又可以进一步被一个或多个 更多选自卤素，C 1 -C 5烷基，C 1 -C 5烷氧基和苯基的基团。 此外，任何催化剂配体还可以包括一个或多个官能团。 合适的官能团的实例包括但不限于：羟基，硫醇，硫醚，酮，醛，酯，醚，胺，亚胺，酰胺，硝基，羧酸，二硫化物，碳酸酯，异氰酸酯，碳二亚胺，碳烷氧基，氨基甲酸酯，卤素 醇，磺酸，膦，酰亚胺，缩醛，缩酮，硼酸酯，氰基，氰醇，肼，烯胺，砜，硫化物和亚磺酰基。 在某些实施方案中，L，L'和L 2中的至少一个是N-杂环卡宾配体。