公开(公告)号：US12115517B1

公开(公告)日：2024-10-15

申请号：US18660098

申请日：2024-05-09

Applicant: QINGDAO AGRICULTURAL UNIVERSITY

Inventor： Yongchao Ma ,  Qingli Yang ,  Ping Liu ,  Fuguo Xing

IPC: B01J35/39 ,  A23D9/04 ,  A23L11/30 ,  B01J21/18 ,  B01J27/24 ,  B01J31/06 ,  B01J35/45 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08 ,  B01J37/34

CPC classification number: B01J21/18 ,  A23D9/04 ,  A23L11/34 ,  A23L11/36 ,  B01J27/24 ,  B01J31/06 ,  B01J35/39 ,  B01J35/45 ,  B01J37/0236 ,  B01J37/036 ,  B01J37/06 ,  B01J37/084 ,  B01J37/343

Abstract: Disclosed are a SA@CDs/g-C3N4 composite material, a method for preparing same, and an application of the same to aflatoxin removal, which belong to the technical field of organic materials. The method for preparing a SA@CDs/g-C3N4 composite material includes: adding a CDs/g-C3N4 compound into water, and uniformly dispersing same through ultrasonic treatment; adding sodium alginate, intensely stirring and fully mixing a mixture, and forming a pregel solution; transferring the fully mixed pregel solution into a mold, and freeze-drying the pregel solution to obtain sponge; and soaking the sponge in a CaCl2) solution for gel, performing washing with deionized water, performing freeze-drying, and obtaining the SA@CDs/g-C3N4 composite material. The SA@CDs/g-C3N4 composite material prepared according to the present disclosure can effectively remove residual aflatoxin in foods, and is wild in effect, environmentally-friendly and safe.

公开(公告)号：US20240228309A1

公开(公告)日：2024-07-11

申请号：US18454824

申请日：2023-08-24

Applicant: ZHEJIANG UNIVERSITY

Inventor： Chuande WU ,  Jijie YE

IPC: C01C1/04 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J23/83 ,  B01J23/86 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08

CPC classification number: C01C1/0411 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J23/83 ,  B01J23/862 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0236 ,  B01J37/036 ,  B01J37/086

Abstract: The present disclosure discloses a porous ammonia synthesis catalyst, its preparation method and use, which are suitable for catalyzing ammonia synthesis reaction by using nitrogen and hydrogen as raw materials. The porous ammonia synthesis catalyst is a novel ammonia synthesis catalyst material prepared by taking metal coordination compound as template, uniformly dispersing the metal coordination compound in silica gel through a sol-gel method, then carrying out hydrothermal aging, and finally controlling calcination conditions. Compared with traditional synthetic ammonia catalysts, the porous ammonia synthesis catalyst has uniform pore distribution, easily regulated pore size, large specific surface area, easily regulated aggregation degree of metal active centers, particle size, distribution, structure and composition, high ammonia synthesis catalytic efficiency, ammonia synthesis catalysis under mild reaction conditions, high stability, low catalyst preparation cost, which can completely replace existing ammonia synthesis industrial catalysts.

公开(公告)号：US11975309B2

公开(公告)日：2024-05-07

申请号：US16960930

申请日：2019-01-11

Applicant: Ketjen Limited Liability Company

Inventor： Amir Sabahi ,  Eswaramoorthi Iyyamperumal ,  Nataly G. Vargas ,  William Knowles ,  Andrew Loebl ,  Julie Francis

IPC: B01J29/08 ,  B01J6/00 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/80 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/06 ,  B01J37/10 ,  B01J37/28 ,  B01J37/30 ,  C10G11/05 ,  C10G11/18 ,  B01J29/40 ,  B01J29/65

CPC classification number: B01J29/088 ,  B01J6/001 ,  B01J29/005 ,  B01J29/06 ,  B01J29/061 ,  B01J29/085 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/80 ,  B01J35/0013 ,  B01J35/1033 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/036 ,  B01J37/038 ,  B01J37/06 ,  B01J37/10 ,  B01J37/28 ,  B01J37/30 ,  C10G11/05 ,  C10G11/18 ,  B01J2029/062 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7007 ,  B01J29/7042 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2527/14 ,  C07C2527/16 ,  C07C2527/167 ,  C07C2527/18 ,  C07C2527/182 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/70

Abstract: Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high SiO2/Al2O3 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.

公开(公告)号：US20240010504A1

公开(公告)日：2024-01-11

申请号：US17857572

申请日：2022-07-05

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Rajesh Kumar PARSAPUR ,  Robert P. HODGKINS ,  Omer Refa KOSEOGLU ,  Kuo-Wei HUANG ,  Anissa Bendjeriou SEDJERARI

IPC: C01B37/00 ,  B01J21/04 ,  B01J29/03 ,  B01J29/89 ,  B01J37/03 ,  C01B37/02

CPC classification number: C01B37/005 ,  B01J21/04 ,  B01J29/0308 ,  B01J29/89 ,  B01J37/036 ,  C01B37/02

Abstract: A composition of matter is provided comprising hierarchically ordered crystalline microporous material having well-defined long-range mesoporous ordering of lamellar symmetry. The composition possesses mesopores having walls of crystalline microporous material and a mass of mesostructure between mesopores of crystalline microporous material. Long-range ordering is defined by presence of secondary peaks in an X-ray diffraction (XRD) pattern and/or lamellar symmetry observable by microscopy.

公开(公告)号：US20180305294A1

公开(公告)日：2018-10-25

申请号：US15491490

申请日：2017-04-19

Applicant: King Abdulaziz University

Inventor： Mohammad W. KADI ,  Reda Mohamedy Mohamed OUF

IPC: C07C209/36 ,  B01J27/185 ,  B01J35/00 ,  B01J35/10 ,  B01J35/02 ,  B01J37/04 ,  B01J37/08

CPC classification number: B01J37/08 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J37/0045 ,  B01J37/036

Abstract: A photocatalytic nanocomposite hollow sphere comprising a shell surrounding a hollow core, and the shell comprising zirconium dioxide, hydroxyapatite, and platinum, as well as a method for producing the nanocomposite hollow sphere and a method employing the nanocomposite hollow sphere in reducing an aromatic nitro compound to an aromatic amine compound under visible light are disclosed.

公开(公告)号：US20180272318A1

公开(公告)日：2018-09-27

申请号：US15764038

申请日：2016-09-12

Applicant: The Chugoku Electric Power Co., Inc. ,  Tokyo Metropolitan University

Inventor： Eiji KIYONAGA ,  Kenji HIKINO ,  Keiichiro MORITA ,  Masatake HARUTA ,  Toru MURAYAMA ,  Makoto MINO

IPC: B01J23/22 ,  B01J35/10 ,  B01J37/08 ,  B01D53/94 ,  F01N3/20

CPC classification number: F01N3/2842 ,  B01D53/8628 ,  B01D53/90 ,  B01D53/9418 ,  B01D53/9436 ,  B01D53/96 ,  B01D2251/206 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/9207 ,  B01D2258/012 ,  B01D2259/4566 ,  B01J23/22 ,  B01J23/92 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0219 ,  B01J37/036 ,  B01J37/08 ,  B01J37/082 ,  B01J37/088 ,  B01J38/02 ,  B01J38/485 ,  B01J38/64 ,  B01J38/66 ,  F01N3/0205 ,  F01N3/021 ,  F01N3/2066 ,  F01N3/208 ,  F01N3/28 ,  F01N3/2803 ,  F01N5/02 ,  F01N13/009 ,  F01N2330/00 ,  F01N2330/06 ,  F01N2330/08 ,  F01N2330/42 ,  F01N2370/02 ,  F01N2510/068 ,  F01N2570/14 ,  F01N2590/02 ,  F01N2610/02 ,  Y02T10/16

Abstract: There is provided a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A denitration catalyst contains 3.3 wt % or more of vanadium oxide in terms of vanadium pentoxide and has a BET specific surface area of 10 m2/g or more.

公开(公告)号：US20180200694A1

公开(公告)日：2018-07-19

申请号：US15744106

申请日：2016-07-05

Applicant: IFP Energies Nouvelles ,  Compagnie Generale Des Etablissements Michelin

Inventor： Nicolas CADRAN ,  Alexandra CHAUMONNOT ,  Arnold LAMBERT

IPC: B01J21/08 ,  B01J23/20 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  B01J37/10 ,  C07C1/20

CPC classification number: B01J21/08 ,  B01J23/06 ,  B01J23/20 ,  B01J23/682 ,  B01J23/847 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/036 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  B01J2523/27 ,  B01J2523/41 ,  B01J2523/57 ,  C07C1/20 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/20 ,  C07C11/167

Abstract: A mesoporous mixed oxide catalyst that comprises silicon and at least one metal M that is selected from the group that consists of the elements of groups 4 and 5 of the periodic table and mixtures thereof, with the mass of metal M being between 0.1 and 20% of the mixed oxide mass.

公开(公告)号：US10017397B2

公开(公告)日：2018-07-10

申请号：US15399052

申请日：2017-01-05

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Salvador Castillo Cervantes ,  Isidro Mejia Centeno ,  Roberto Camposeco Solis ,  Florencia Marina Moran Pineda ,  Juan Navarrete Bolanos ,  J. Ascension Montoya De La Fuente ,  Alfredo Vargas Escudero

IPC: C01G23/053 ,  B01J21/06 ,  B01J35/02 ,  B01J37/03 ,  B01J37/08 ,  C01G23/08

CPC classification number: C01G23/053 ,  B01J21/063 ,  B01J35/02 ,  B01J37/036 ,  B01J37/08 ,  C01G23/08 ,  C01P2002/02 ,  C01P2002/60 ,  C01P2006/12 ,  C01P2006/16 ,  C01P2006/40

Abstract: A semiconductor material basically consists of titanium oxide, with the special feature of being like nanostructures, which gives special physicochemical properties, with ability to disperse and stabilize metal particles with high activity and selectivity in catalytic processes mainly. The process of producing the semiconductor material includes adding a titanium alkoxide to an alcoholic solution, adding an acid to the alcoholic solution, controlling the pH from 1 to 5; subjecting the acidic solution to agitation and reflux conditions at 70 to 80° C.; stabilizing the medium and adding bidistilled water in a water/alkoxide molar ratio of 1-2/0.100-0.150, continuing with reflux until gelation; aging the gel for 1 to 24 hours for complete formation of the titania; drying the titania nanostructured at of 50 to 80° C. for about 1 to 24 hours, and subjecting the dried titania to a calcination step at 200 to 600° C. for 1 to 12 hours.

公开(公告)号：US09999874B2

公开(公告)日：2018-06-19

申请号：US15474795

申请日：2017-03-30

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Federico Jesus Jimenez Cruz ,  Celia Marin Rosas ,  Luis Carlos Castaneda Lopez ,  Rogelio Hernandez Suarez ,  Javier Esteban Rodriguez Rodriguez ,  Maria del Carmen Martinez Guerrero ,  Florentino Rafael Murrieta Guevara ,  Alicia del Rayo Jaramillo Jacob

IPC: B01J27/182 ,  B01J27/18 ,  B01J27/055 ,  B01J21/18 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/03 ,  B01J37/04 ,  B01J37/00 ,  B01J37/08 ,  C11C3/04

CPC classification number: B01J27/1806 ,  B01J21/18 ,  B01J23/007 ,  B01J27/055 ,  B01J27/1808 ,  B01J27/1811 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J37/086 ,  B01J2523/00 ,  C01B25/45 ,  C01F7/043 ,  C01F7/76 ,  C01P2004/60 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C11C3/04 ,  C11C3/10 ,  Y02E50/13 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/51 ,  B01J2523/47 ,  B01J2523/62

Abstract: The present invention relates to heterogeneous acid catalysts comprising or consisting of mixed metal salts, of lithium and aluminum phosphates and sulfates, and combinations with metallic cations, such as magnesium, titanium, zinc, zirconium and gallium, to provide adequate Lewis acidity; organic or inorganic porosity promoters, such as polysaccharides; and agglomerates, such as clays, kaolin and metal oxides of the type MxOy, where; M=Al, Mg, Sr, Zr or Ti, and other metals of groups IA, IIA and IVB, x=1 or 2 and y=2 or 3, for the formation of particles. A process is disclosed for obtaining from the catalyst by the hydrolysis of aluminum lithium hydride with water and oxygenated solvent, such as an ether. The catalysts are used in batch reactor and continuous flow systems in reactions that require moderate Lewis acidity, such as refining, petrochemical and general chemistry, including the transesterification of glycerides to produce alkyl esters.

公开(公告)号：US20180141028A1

公开(公告)日：2018-05-24

申请号：US15359986

申请日：2016-11-23

Applicant: Jiefeng Lin ,  Gervase Maxwell Christie

Inventor： Jiefeng Lin ,  Gervase Maxwell Christie

IPC: B01J23/89 ,  B01J23/83 ,  B01J35/10

CPC classification number: B01J23/894 ,  B01J23/002 ,  B01J23/005 ,  B01J23/83 ,  B01J23/89 ,  B01J23/892 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/031 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J2523/00 ,  C01B3/40 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/847

Abstract: This invention relates to highly active and stable catalyst composite used in high temperature synthesis gas production. More specifically, nickel alumina catalysts doped with noble metals and lanthanide groups or transition metal groups containing a lattice spinel structure with a general formula [NixA1-x] [(ByAl1-y)2]O4 Stabilizers such as yttria-stabilized zirconia are also integrated in this composite to enhance high temperature catalytic performance. The catalyst composite of present invention exhibits high redox tolerance, coking resistance, high temperature stability, and high catalytic activity.