公开(公告)号：US12104123B2

公开(公告)日：2024-10-01

申请号：US18379230

申请日：2023-10-12

Applicant: BASF CORPORATION

Inventor： David M. Stockwell ,  Junmei Wei ,  Xingtao Gao ,  David H. Harris

IPC: C10G11/05 ,  B01J21/12 ,  B01J21/16 ,  B01J29/08 ,  B01J35/00 ,  B01J35/40 ,  B01J35/51 ,  B01J35/61 ,  B01J35/63 ,  B01J37/00 ,  B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  C10G11/18

CPC classification number: C10G11/05 ,  B01J21/12 ,  B01J21/16 ,  B01J29/088 ,  B01J35/19 ,  B01J35/40 ,  B01J35/51 ,  B01J35/613 ,  B01J35/615 ,  B01J35/633 ,  B01J35/635 ,  B01J37/0045 ,  B01J37/038 ,  B01J37/082 ,  B01J37/10 ,  C10G11/18 ,  B01J2229/18 ,  C10G2300/70

Abstract: A bottoms cracking catalyst composition, comprising: about 30 to about 60 wt % alumina; greater than 0 to about 10 wt % of a dopant, measured as the oxide; about 2 to about 20 wt % reactive silica; about 3 to about 20 wt % of a component comprising peptizable boehmite, colloidal silica, aluminum chlorohydrol, or a combination of any two or more thereof, and about 10 to about 50 wt % of kaolin.

公开(公告)号：US12064751B2

公开(公告)日：2024-08-20

申请号：US17631094

申请日：2020-07-16

Applicant: IFP Energies nouvelles

Inventor： Anne-Claire Dubreuil ,  Vincent Coupard ,  Malika Boualleg

IPC: B01J23/755 ,  B01J21/04 ,  B01J27/02 ,  B01J35/40 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  C07C5/05 ,  C07C5/09 ,  C07C5/11 ,  C10G45/36

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J27/02 ,  B01J35/40 ,  B01J37/0009 ,  B01J37/0207 ,  B01J37/082 ,  B01J37/10 ,  C07C5/05 ,  C07C5/09 ,  C07C5/11 ,  C10G45/36 ,  C07C2521/04 ,  C07C2523/755

Abstract: Catalyst comprising nickel and sulfur on an alumina support, said catalyst being characterized in that:



the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst;
the nickel density ratio between the crust and the core is strictly greater than 3;
said crust comprises more than 25% by weight of nickel element relative to the total weight of nickel contained in the catalyst,
the size of the nickel particles in the catalyst, measured in oxide form, is between 7 and 25 nm.

公开(公告)号：US12060280B2

公开(公告)日：2024-08-13

申请号：US17271233

申请日：2019-08-23

Applicant: Pacific Industrial Development Corporation

Inventor： Yunkui Li ,  David Shepard ,  De Gao ,  Wei Wu ,  Jeffery Lachapelle ,  Geng Zhang

IPC: C01B39/48 ,  B01J29/76 ,  B01J35/02 ,  B01J35/10 ,  B01J35/50 ,  B01J35/61 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30

CPC classification number: C01B39/48 ,  B01J29/76 ,  B01J35/50 ,  B01J35/615 ,  B01J35/617 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/036 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  B01J2229/186 ,  C01P2004/61 ,  C01P2006/12

Abstract: A method of forming an AEI-type zeolite in a hydrothermal synthesis without the use of hydrogen fluoride (HF) and in the absence of any FAU zeolite Y. A gel composition formed upon using this method includes one or more sources of silica; one or more sources of alumina, one or more organic structure directing agents (OSDA); a source of alkali metal ions; and water. This gel composition is defined by the molar ratios of: SiO2/AI2O3 16:1 to 100:1; M2O/SiO2 0.15:1 to 0.30:1; ROH/SiO2 0.05:1 to 0.20:1; and H2O/SiO2 5:1 to 20:1; wherein M is the alkali metal ion and R is an organic moiety derived from the OSDA. This gel composition, after reacting at a temperature between 135° C. to about 180° C. for 15 hours to 168 hours forms the crystalline AEI-type zeolite having a silica to alumina ratio (SiO2:AI2O3) that is greater than 8:1.

公开(公告)号：US12030042B2

公开(公告)日：2024-07-09

申请号：US17660545

申请日：2022-04-25

Applicant: Johnson Matthey Public Limited Company

Inventor： Hai-Ying Chen ,  Joseph Fedeyko ,  Raul Lobo ,  Nicholas McNamara ,  Trong Pham

IPC: B01J29/78 ,  B01D53/94 ,  B01J20/18 ,  B01J29/70 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J35/00 ,  B01J35/30 ,  B01J35/56 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  C01B39/02 ,  C01B39/04 ,  C01B39/08 ,  C01B39/48 ,  F01N3/022 ,  F01N3/035 ,  F01N3/08 ,  F01N3/10 ,  F01N3/20

CPC classification number: B01J29/78 ,  B01D53/94 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/944 ,  B01J20/18 ,  B01J29/70 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J35/19 ,  B01J35/30 ,  B01J35/56 ,  B01J37/0018 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  C01B39/026 ,  C01B39/04 ,  C01B39/08 ,  C01B39/48 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2047 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/50 ,  B01D2255/91 ,  B01D2255/915 ,  B01D2255/9155 ,  B01D2258/012 ,  B01J2229/183 ,  B01J2229/186 ,  C01P2002/72 ,  C01P2004/03 ,  F01N3/0222 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/103 ,  F01N3/2066 ,  F01N2330/02 ,  F01N2370/04

Abstract: Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.

公开(公告)号：US20240189803A1

公开(公告)日：2024-06-13

申请号：US18553120

申请日：2022-03-30

Applicant: FURUKAWA ELECTRIC CO., LTD. ,  NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY

Inventor： Yuichiro BANBA ,  Masayuki FUKUSHIMA ,  Yuki KAWAMATA ,  Yuki IWANO ,  Tomohiko MORI ,  Takashi FUJIKAWA ,  Takao MASUDA ,  Yuta NAKASAKA ,  Takuya YOSHIKAWA

IPC: B01J29/035 ,  B01J35/45 ,  B01J37/02 ,  B01J37/10 ,  C01B3/40

CPC classification number: B01J29/0356 ,  B01J35/45 ,  B01J37/0201 ,  B01J37/10 ,  C01B3/40 ,  B01J2229/183

Abstract: A catalyst structure for synthesis gas production is used to produce a synthesis gas that includes carbon monoxide and hydrogen. The structure includes a carrier with a porous structure that comprises a zeolite-type compound; first catalyst particles that contain at least one iron-group element selected from the group consisting of nickel, iron, and cobalt; and a second catalyst that contains at least one transition metal element with redox capacity. The carrier includes, inside thereof, mutually communicating passages; the first catalyst particles are present at least in the passages of the carrier; and the second catalyst is present at least in the interior or on an outer surface of the carrier.

公开(公告)号：US20240150263A1

公开(公告)日：2024-05-09

申请号：US18549582

申请日：2022-03-14

Applicant: LINDE GMBH ,  Clariant International Ltd.

Inventor： Mathieu Zellhuber ,  Martin Schubert ,  Andreas Meiswinkel ,  Gerhard Mestl ,  Klaus Wanninger ,  Peter Scheck ,  Anina Wohl

IPC: C07C5/48 ,  B01J8/06 ,  B01J23/22 ,  B01J23/28 ,  B01J27/057 ,  B01J35/50 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/10

CPC classification number: C07C5/48 ,  B01J8/06 ,  B01J23/22 ,  B01J23/28 ,  B01J27/0576 ,  B01J35/50 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/10 ,  B01J2208/021 ,  B01J2208/025 ,  C07C2523/22 ,  C07C2523/28 ,  C07C2527/057

Abstract: A process for producing a target compound includes forming a feed mixture containing at least one reactant compound. The feed mixture is distributed to parallel reaction tubes of one or more shell-and-tube reactors and subjected to oxidative catalytic conversion in the reaction tubes. Steam is added to the feed mixture in an amount such that a steam fraction of the feed mixture is 5 to 95 vol %, oxygen is added to the feed mixture in the form of a fluid containing at least 95 vol % oxygen, and the oxidative catalytic conversion is carried out using one or more catalysts containing the metals molybdenum, vanadium, niobium and optionally tellurium.

公开(公告)号：US20240149255A1

公开(公告)日：2024-05-09

申请号：US18543520

申请日：2023-12-18

Applicant: DALIAN UNIVERSITY OF TECHNOLOGY ,  DALIAN QIYUAN TECHNOLOGY CO., LTD.

Inventor： Hongchen GUO ,  Cuilan MIAO ,  Quanren ZHU

IPC: B01J29/89 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10

CPC classification number: B01J29/89 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/082 ,  B01J37/10 ,  B01J2229/18

Abstract: An alkali metal ion modified titanium silicalite zeolite TS-1 for gas phase epoxidation of propylene and hydrogen peroxide and a preparation method thereof. The method includes: 1: preparing an alkali metal hydroxide modification solution containing a small amount of TPA+ ions; 2: conducting a controlled hydrothermal treatment on a TS-1 zeolite matrix by using the alkali metal hydroxide solution containing a small amount of TPA+ ions; and 3: conducting post-treatment on the hydrothermally modified TS-1 zeolite. In the washing process, the modified TS-1 zeolite wet material is washed with a low concentration alkali metal hydroxide solution; and alkali metal ions are reserved on the silicon hydroxyl of the modified titanium silicalite zeolite. The prepared alkali metal ion modified titanium silicalite zeolite has significantly improved catalytic performance in the gas phase epoxidation of propylene and hydrogen peroxide.

公开(公告)号：US20240149254A1

公开(公告)日：2024-05-09

申请号：US18121922

申请日：2023-03-15

Applicant: Hyundai Motor Company ,  Kia Corporation ,  Korea University Research and Business Foundation

Inventor： Chun Yong Kang ,  Eunhee Jang ,  Jungkyu Choi ,  Jaehee Shim ,  Jin Seong Kim

IPC: B01J29/72 ,  B01J6/00 ,  B01J20/16 ,  B01J20/30 ,  B01J20/32 ,  B01J37/02 ,  B01J37/10

CPC classification number: B01J29/7215 ,  B01J6/001 ,  B01J20/165 ,  B01J20/3078 ,  B01J20/3204 ,  B01J37/0209 ,  B01J37/0236 ,  B01J37/10

Abstract: Provided herein are a method for producing a hydrocarbon adsorption catalyst includes dealuminated zeolite by heat-treating a zeolite in moisture-containing air at a first temperature to remove a portion of aluminum included in the zeolite, and supporting a metal on a carrier including the zeolite after the heat-treating and a hydrocarbon adsorption catalyst prepared using the same method. The metal-supported support may be additionally heat-treated in moisture-containing air at a second temperature that is higher than the first temperature.

公开(公告)号：US11944959B2

公开(公告)日：2024-04-02

申请号：US17296182

申请日：2020-04-14

Applicant: DALIAN UNIVERSITY OF TECHNOLOGY ,  DALIAN QIYUAN TECHNOLOGY CO., LTD.

Inventor： Hongchen Guo ,  Cuilan Miao ,  Quanren Zhu ,  Ning He ,  Yanhui Yi ,  Jiaxu Liu

IPC: B01J29/89 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10

CPC classification number: B01J29/89 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/082 ,  B01J37/10 ,  B01J2229/18

Abstract: An alkali metal ion modified titanium silicalite zeolite for gas phase epoxidation of propylene and hydrogen peroxide and a preparation method thereof. The method includes, at first step: preparing an alkali metal hydroxide modification solution; at second step: conducting controlled hydrothermal treatment on a TS-1 zeolite matrix by using an alkali metal hydroxide solution; and at third step: conducting post-treatment on the hydrothermally modified TS-1 zeolite, including solid-liquid separation, washing, drying and calcining. In the washing process, the modified TS-1 zeolite wet material is washed with a low concentration alkali metal hydroxide solution; alkali metal ions are reserved on the silicon hydroxyl of the modified titanium silicalite zeolite; and an infrared characteristic absorption band of a framework titanium active center modified by the alkali metal ions is in a range above 960 cm−1 and below 980 cm−1.

公开(公告)号：US11904306B2

公开(公告)日：2024-02-20

申请号：US17167280

申请日：2021-02-04

Applicant: Furukawa Electric Co., Ltd.

Inventor： Sadahiro Kato ,  Masayuki Fukushima ,  Hiroko Takahashi ,  Yuichiro Banba ,  Kaori Sekine ,  Takao Masuda ,  Yuta Nakasaka ,  Takuya Yoshikawa

IPC: B01J29/89 ,  B01J23/46 ,  B01J23/44 ,  B01J23/42 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/10 ,  B01J37/00 ,  B01J29/12 ,  B01J29/14 ,  C01B3/40

CPC classification number: B01J29/89 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J29/12 ,  B01J29/14 ,  B01J35/0013 ,  B01J35/0066 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/10 ,  B01J2229/186 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/066 ,  C01B2203/107 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241

Abstract: A catalyst structure includes a carrier having a porous structure composed of a zeolite type compound and at least one catalytic material existing in the carrier. The carrier has channels communicating with each other, and the catalytic material is a metal fine particle and exists at least in the channel of the carrier.