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公开(公告)号:US20240335824A1
公开(公告)日:2024-10-10
申请号:US18293533
申请日:2022-06-16
CPC分类号: B01J29/763 , B01D53/9418 , B01J37/0018 , B01J37/031 , B01J37/036 , B01J37/30 , C01B39/48 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9202 , B01D2255/9205 , B01D2255/9207 , B01D2257/404 , B01D2258/01 , B01J2229/186 , C01P2002/60 , C01P2002/72 , C01P2004/03 , C01P2006/12 , C01P2006/14
摘要: A low SAR chabazite zeolite, its synthesis, and its use for the treatment of an exhaust gas, are disclosed. The chabazite (CHA) zeolite having an SAR of from 7 to 15, and at least one following features: (a) a mesoporous surface area of less than 35 m2 (b) a BET surface area of 500-800 m2/g; and/or (c) a micropore volume of 0.2-0.3 cm2/g.
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2.
公开(公告)号:US12042787B2
公开(公告)日:2024-07-23
申请号:US17297522
申请日:2019-11-29
发明人: Jae Suk Choi , Ka Young Kim , Hee Soo Kim , Ju Hwan Im , Dae Hyun Choo , Ho Won Lee , Je Mi Lim
IPC分类号: B01J29/04 , B01J29/035 , B01J35/61 , B01J35/63 , B01J35/64 , B01J37/08 , B01J37/30 , C07C2/12
CPC分类号: B01J29/044 , B01J29/0356 , B01J35/615 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/647 , B01J37/08 , B01J37/30 , C07C2/12
摘要: In the present disclosure, a heterogeneous nickel-based oligomerization catalyst in which nickel in the form of single atom is loaded on an Al-mesoporous silicate support by ion exchange and a method for producing the same, and a method for oligomerizing light olefins, specifically C4 olefins using the catalyst are described.
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公开(公告)号:US20240226860A1
公开(公告)日:2024-07-11
申请号:US18439356
申请日:2024-02-12
申请人: UOP LLC
发明人: Deng-Yang Jan , Jaime G. Moscoso , Lijun Xu , Xi Zhao
IPC分类号: B01J29/40 , B01J35/61 , B01J35/63 , B01J37/03 , B01J37/30 , C01B39/40 , C07C1/22 , C07C4/06 , C10G11/05
CPC分类号: B01J29/40 , B01J35/615 , B01J35/633 , B01J37/03 , B01J37/30 , C01B39/40 , C07C1/22 , C07C4/06 , C10G11/05 , B01J2229/36 , C07C2529/40 , C10G2400/20
摘要: An improved MFI zeolite having low aluminum occupation at intersection sites characterized by an ortho-xylene to para-xylene uptake ratio of 0.1 to about 0.55. Processes for converting hydrocarbon or oxygenate to a product comprising light olefins and/or aromatics using the improved MFI zeolite as catalyst are also disclosed. Para-xylene in the product may be greater than about 24% of the xylenes.
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公开(公告)号:US20240226859A1
公开(公告)日:2024-07-11
申请号:US18616525
申请日:2024-03-26
发明人: Amir Sabahi , Eswaramoorthi Iyyamperumal , Nataly G. Vargas , William Knowles , Andrew Loebl , Julie Francis
IPC分类号: B01J29/08 , B01J6/00 , B01J29/00 , B01J29/06 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/80 , B01J35/23 , B01J35/63 , B01J35/64 , B01J35/66 , B01J35/69 , B01J37/00 , B01J37/03 , B01J37/06 , B01J37/10 , B01J37/28 , B01J37/30 , C10G11/05 , C10G11/18
CPC分类号: B01J29/088 , B01J6/001 , B01J29/005 , B01J29/06 , B01J29/061 , B01J29/085 , B01J29/70 , B01J29/7038 , B01J29/7049 , B01J29/7057 , B01J29/80 , B01J35/23 , B01J35/63 , B01J35/647 , B01J35/66 , B01J35/69 , B01J37/0009 , B01J37/0045 , B01J37/036 , B01J37/038 , B01J37/06 , B01J37/10 , B01J37/28 , B01J37/30 , C10G11/05 , C10G11/18 , B01J2029/062 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J29/7042 , B01J2229/186 , B01J2229/36 , B01J2229/42 , C07C2527/14 , C07C2527/16 , C07C2527/167 , C07C2527/18 , C07C2527/182 , C07C2529/06 , C07C2529/08 , C07C2529/40 , C07C2529/70
摘要: Process for the preparation of a catalyst by adding, clay, boehmite, a first silica to form a slurry, digesting the slurry with a monoprotic acid to a pH of less than 4, adding one or more zeolites, adding a rare earth component to the slurry and mixing, adjusting the slurry pH to below 4 with monoprotic acid, adding a second silica anywhere in the preceding steps, destabilizing the slurry by raising the pH, shaping and collecting the resulting catalyst, wherein the resulting catalyst has enhanced mesoporosity.
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5.
公开(公告)号:US20240198324A1
公开(公告)日:2024-06-20
申请号:US18286672
申请日:2022-01-21
申请人: ORGANO CORPORATION
发明人: Shinji NAKAMURA , Hitoshi TAKADA
摘要: In a platinum group metal supported catalyst column, a platinum group metal supported catalyst is a catalyst in which at least one of platinum group metal nanoparticles, platinum group metal ions, and platinum group metal complex ions is supported on an ion exchanger, wherein the exchanger is composed of a continuous skeleton phase and a continuous pore phase, the thickness of the continuous skeleton is 1-100 μm, the average diameter of the continuous pore is 1-1000 μm, the total pore volume is 0.5-50 mL/g, the ion exchange capacity per weight in a dry state is 1-9 mg equivalent/g, and the ion exchanger is non-particulate organic porous ion exchanger in which the ion exchange groups are distributed in the ion exchanger, the amount of platinum group metal nanoparticles, etc., supported is 0.004-20 wt % in a dry state, and a platinum group metal scavenger is provided at the backward stage catalyst.
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公开(公告)号:US20240173702A1
公开(公告)日:2024-05-30
申请号:US18059733
申请日:2022-11-29
发明人: Faisal Alotaibi , Lianhui Ding
IPC分类号: B01J29/08 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/04 , B01J37/08 , B01J37/30 , C01B39/08 , C01B39/24
CPC分类号: B01J29/084 , B01J35/0013 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J37/009 , B01J37/04 , B01J37/08 , B01J37/30 , C01B39/08 , C01B39/24 , B01J2029/081 , B01J2229/16 , B01J2229/32 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要: Methods for synthesizing a mesoporous nano-sized ultra-stable Y zeolite include combining a microporous Y zeolite having a SiO2/Al2O3 molar ratio of less than 5.2 with water to form a microporous Y zeolite slurry and heating the microporous Y zeolite slurry to 30° C. to 100° C. to form a heated microporous Y zeolite slurry. Further the method includes adding a 0.1M to 2.0M ammonium hexafluorosilicate solution and a 0.1M to 2.0M ammonium hydroxide solution in a drop-wise manner, either sequentially or simultaneously, to the heated microporous Y zeolite slurry to form a treated zeolite solution and holding the treated zeolite solution at 50° C. to 100° C. Finally the method includes filtering and washing the dealuminated solution with water to form an ultra-stable Y zeolite precursor, drying the ultra-stable Y zeolite precursor, and calcining the dried zeolite precursor to form the nano-sized ultra-stable Y zeolite.
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公开(公告)号:US20240132437A1
公开(公告)日:2024-04-25
申请号:US18383156
申请日:2023-10-23
发明人: Jong Wook BAE , Xu WANG , So Yun JEONG , Eun Jeong KIM , Zafar FAISAL , Ali MANSOOR
IPC分类号: C07C67/00 , B01J21/08 , B01J23/80 , B01J29/65 , B01J29/68 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/08 , B01J37/10 , B01J37/18 , B01J37/30 , C01B39/44
CPC分类号: C07C67/00 , B01J21/08 , B01J23/80 , B01J29/65 , B01J29/68 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J37/0018 , B01J37/082 , B01J37/10 , B01J37/18 , B01J37/30 , C01B39/445
摘要: Disclosed are a tandem catalyst for synthesizing methyl acetate from carbon dioxide, a method for preparing the same, and a method for preparing methyl acetate using the same. The tandem catalyst of the present invention includes a first catalyst having a core-shell structure including a composite metal oxide core and a silica shell surrounding a surface of the composite metal oxide core, and a second catalyst including nano-ferrierite (N-FER) zeolite.
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公开(公告)号:US11951464B2
公开(公告)日:2024-04-09
申请号:US17270662
申请日:2019-08-21
申请人: Kunlun Ding
发明人: Kunlun Ding
IPC分类号: B01J35/00 , B01J21/08 , B01J23/44 , B01J23/46 , B01J23/52 , B01J23/89 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/18 , B01J37/30
CPC分类号: B01J35/0006 , B01J21/08 , B01J23/44 , B01J23/462 , B01J23/468 , B01J23/52 , B01J23/8906 , B01J23/8913 , B01J23/892 , B01J23/8926 , B01J35/023 , B01J37/0063 , B01J37/009 , B01J37/04 , B01J37/06 , B01J37/082 , B01J37/18 , B01J37/30
摘要: The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals Ma and Mb; wherein the ratio of Ma to Mb is between about 2:1 and about 1:2.
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9.
公开(公告)号:US20240109058A1
公开(公告)日:2024-04-04
申请号:US17766578
申请日:2020-11-24
申请人: BASF SE
CPC分类号: B01J29/76 , B01D53/56 , B01D53/9418 , B01J35/19 , B01J37/08 , B01J37/30 , C01B39/02 , B01D2255/2061 , B01D2255/20761 , B01D2255/50
摘要: A rare earth element containing zeolitic material having an AEI-type framework structure, the framework structure of the zeolitic material comprising SiO2 and X2O3, X being a trivalent element, wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure, and wherein the zeolitic material is obtainable and/or obtained according to a process involving the hydrothermal treatment of the rare earth element containing zeolitic material at a temperature in the range of from 400 to 1,000° C. A coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure, wherein the zeolitic material is supported on the monolith substrate. A process for the production of a coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure.
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公开(公告)号:US11926796B2
公开(公告)日:2024-03-12
申请号:US17865555
申请日:2022-07-15
IPC分类号: B01J29/06 , B01J29/00 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/83 , B01J29/85 , B01J35/00 , B01J37/00 , B01J37/03 , B01J37/10 , B01J37/28 , B01J37/30 , C10G11/05 , C10G11/18
CPC分类号: C10G11/05 , B01J29/005 , B01J29/06 , B01J29/061 , B01J29/084 , B01J29/085 , B01J29/088 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7038 , B01J29/7057 , B01J29/80 , B01J29/83 , B01J29/85 , B01J35/0013 , B01J37/0009 , B01J37/0045 , B01J37/036 , B01J37/038 , B01J37/10 , B01J37/28 , B01J37/30 , C10G11/18 , B01J2029/062 , B01J2029/081 , B01J2229/36 , B01J2229/42 , C07C2527/14 , C07C2527/16 , C07C2527/167 , C07C2527/18 , C07C2527/182 , C07C2529/06 , C07C2529/08 , C07C2529/40 , C07C2529/70 , C07C2529/83 , C07C2529/85
摘要: Process for the preparation of a catalyst and a catalyst comprising the use of more than one silica source is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 15 to about 35 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized basic colloidal silica, greater than about 0 to about 30 wt % silica from acidic colloidal silica or polysilicic acid, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with a good accessibility.
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