公开(公告)号：US12084410B2

公开(公告)日：2024-09-10

申请号：US17433135

申请日：2019-02-22

申请人： BP P.L.C. ,  BP (CHINA) HOLDINGS LTD

发明人： Benjamin James Dennis-Smither ,  John Glenn Sunley ,  Zhiqiang Yang

IPC分类号： C07C41/09 ,  B01J29/06 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70

CPC分类号： C07C41/09 ,  B01J29/06 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7042 ,  B01J29/7046 ,  B01J2229/42

摘要： A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, wherein: —the aluminosilicate zeolite is selected from: (i) a zeolite having a 2-dimensional framework structure comprising at least one channel having a 10-membered ring, and having a maximum free sphere diameter of at least 4.8 Angstroms; (ii) a zeolite having a 3-dimensional framework structure comprising at least one channel having a 10-membered ring; or (iii) a zeolite comprising at least one channel having a 12-membered ring; —the promoter is selected from one or more compounds of Formula I: (I) wherein Y is selected from a C1-C4 hydrocarbyl substituent, and wherein each of X and any or all of the Z's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.

公开(公告)号：US11912809B2

公开(公告)日：2024-02-27

申请号：US18327119

申请日：2023-06-01

申请人： Chevron Phillips Chemical Company LP

发明人： Max P. McDaniel ,  Eric D. Schwerdtfeger ,  Qing Yang ,  Carlos A. Cruz ,  Jinping J. Zhou ,  Anand Ramanathan ,  Kathy S. Clear ,  Zhihui Gu

IPC分类号： B01J23/00 ,  C08F4/02 ,  B01J29/06 ,  B01J35/10 ,  C08F210/16

CPC分类号： C08F4/025 ,  B01J29/06 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  C08F210/16 ,  C08F2420/00

摘要： Fluorided silica-coated alumina activator-supports have a bulk density from 0.15 to g/mL, a total pore volume from 0.85 to 2 mL/g, a BET surface area from 200 to 500 m2/g, an average pore diameter from 10 to 25 nm, and from 80 to 99% of pore volume in pores with diameters of greater than 6 nm. Methods of making the fluorided silica-coated alumina activator-supports and using the fluorided silica-coated aluminas in catalyst compositions and olefin polymerization processes also are described. Representative ethylene-based polymers produced using the compositions and processes have a melt index of 0.1 to 10 g/10 min and a density of 0.91 to 0.96 g/cm3, and contain from 70 to 270 ppm solid oxide and from 2 to 18 ppm fluorine.

公开(公告)号：US20190184375A1

公开(公告)日：2019-06-20

申请号：US16322156

申请日：2017-07-25

申请人： W.R. GRACE & CO.- CONN.

发明人： Udayshankar Singh ,  Sundaram Krishnamoorthy ,  Michael Scott Ziebarth ,  Wu-Cheng Cheng

IPC分类号： B01J21/04 ,  B01J37/04 ,  B01J35/02 ,  B01J35/00 ,  B01J37/00 ,  B01J35/10 ,  B01J29/85 ,  B01J29/70 ,  B01J21/16 ,  B01J37/08 ,  B01J37/06 ,  C10G11/05 ,  C10G11/18 ,  C10G3/00 ,  C07C1/24

CPC分类号： B01J21/04 ,  B01J21/16 ,  B01J29/04 ,  B01J29/06 ,  B01J29/08 ,  B01J29/7049 ,  B01J29/85 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  C07C1/24 ,  C07C2521/04 ,  C07C2529/70 ,  C10G3/49 ,  C10G3/57 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/70

摘要： A process for preparing a peptized alumina having increased solids and acid contents and a decreased water content. The process comprising mixing a boehmite or pseudoboehmite alumina and acid with a high intensity, high energy mixer at a ratio of 0.16 to 0.65 moles acid/moles alumina for a time period sufficient to form a substantially free-flowing solid particulate having a solids content of 45 to 65 wt %. When used in catalyst manufacture, peptized alumina produced by the process provides an increased rate in catalyst production and decreased costs due to high solids concentration and the presence of less water to be evaporated.

公开(公告)号：US20190184374A1

公开(公告)日：2019-06-20

申请号：US16325842

申请日：2017-08-03

申请人： HEESUNG CATALYSTS CORPORATION

发明人： Ho-dong Kim ,  Young-san Yoo ,  Hyun-sik Han

IPC分类号： B01J20/32 ,  B01J29/08 ,  B01J35/04 ,  B01J37/02 ,  B01J37/08 ,  B01J20/18 ,  C07C2/66

CPC分类号： B01J20/3238 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/32 ,  B01J20/3214 ,  B01J29/06 ,  B01J29/084 ,  B01J32/00 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/08 ,  C07C2/66 ,  C07C7/20 ,  Y02P20/582 ,  Y02P20/584

摘要： The present invention relates to a support structure of a solid catalyst for preparing a linear alkyl aromatic compound, particularly linear alkylbenzene (LAB), and to a method of preparing an alkyl aromatic compound by alkylating an aromatic compound with an olefin using a solid alkylation catalyst, and of regenerating the deactivated solid alkylation catalyst. The present invention provides an integrated method of preparing an alkyl aromatic compound by alkylating an aromatic compound with an olefin using a filter structure as a solid catalyst carrier for alkylating an aromatic compound with an olefin, and of regenerating the deactivated solid alkylation catalyst, thereby realizing simpler and less expensive processing than conventional processes.

公开(公告)号：US20190144291A1

公开(公告)日：2019-05-16

申请号：US16183862

申请日：2018-11-08

申请人： University of Houston System

发明人： Jeffrey D. Rimer ,  Manjesh Kumar

IPC分类号： C01B39/54 ,  B01J29/70 ,  B01J47/00 ,  C30B7/14 ,  C30B29/14 ,  C01B39/04 ,  C30B29/34

CPC分类号： C01B39/54 ,  B01J29/035 ,  B01J29/06 ,  B01J29/7015 ,  B01J29/85 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/023 ,  B01J47/00 ,  B01J2229/62 ,  C01B39/04 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/38 ,  C01P2004/60 ,  C30B7/14 ,  C30B29/14 ,  C30B29/34 ,  C30B29/60

摘要： Embodiments of the invention generally provide compositions of crystalline zeolite materials with tailored crystal habits and the methods for forming such crystalline zeolite materials. The methods for forming the crystalline zeolite materials include binding one or more zeolite growth modifiers (ZGMs) to the surface of a zeolite crystal, which results in the modification of crystal growth rates along different crystallographic directions, leading to the formation of zeolites having a tailored crystal habit. The improved properties enabled by the tailored crystal habit include a minimized crystal thickness, a shortened internal diffusion pathlength, and a greater step density as compared to a zeolite having the native crystal habit prepared by traditional processes. The tailored crystal habit provides the crystalline zeolite materials with an aspect ratio of about 4 or greater and crystal surfaces having a step density of about 25 steps/μm2 or greater.

公开(公告)号：US20190062672A1

公开(公告)日：2019-02-28

申请号：US16117266

申请日：2018-08-30

申请人： The United States of America, as Represented by the Secretary of Agriculture

发明人： Helen N. Lew ,  Renee J. Latona ,  Majher I Sarker ,  Robert A. Moreau

IPC分类号： C11C3/00

CPC分类号： C11C3/10 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  C07C51/353 ,  C07C67/333 ,  C11C3/00

摘要： A method for preparing triglyceride oils containing at least 2% branching on the hydrocarbon chain, said method involving subjecting in a pressurized container (a) a feedstock containing unsaturated fatty acids attached to a glycerol backbone having 6 to 25 carbon atoms or mixtures thereof, (b) modified zeolite, and (c) water or alcohol in the presence of an inert atmosphere (e.g., at a temperature of about 150° C. to about 350° C. and a pressure of about 10 to about 300 psi for about 24 to about 72 hours) to produce triglycerides containing at least 2% branching (and optionally isolating said triglycerides containing at least 2% branching and optionally purifying the isolated triglycerides containing at least 2% branching); wherein said modified zeolite has been calcined at about 760° C. to about 840° C. for about 20 to about 28 hours, then placed in about 1N HCl at about 50° C. to about 60° C. for about 20 to about 28 hours and washed with water until the pH is neutral.

公开(公告)号：US20180214853A1

公开(公告)日：2018-08-02

申请号：US15803434

申请日：2017-11-03

申请人： Archer-Daniels-Midland Company

发明人： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC分类号： B01J23/52 ,  B01J23/42 ,  B01J37/02 ,  B01J29/06 ,  B01J21/06 ,  B01J21/08 ,  B01J37/18 ,  B01J35/00 ,  C07C51/235 ,  C07C51/377 ,  C07C51/41 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/36 ,  C08G69/26 ,  C08G69/14 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

CPC分类号： B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

摘要： Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

公开(公告)号：US09993811B2

公开(公告)日：2018-06-12

申请号：US14438566

申请日：2013-10-25

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC

发明人： Lingping Zhou ,  Ziyang Liu ,  Jiexiao Zhang ,  Mingde Xu ,  Weilin Zhang ,  Huiping Tian ,  Yuxia Zhu

IPC分类号： C01B39/00 ,  B01J29/08 ,  B01J29/06 ,  C01B39/06 ,  B01J19/24 ,  C01B39/02 ,  C01B39/24 ,  B01J19/00 ,  B01J19/22 ,  B01J6/00 ,  B01J8/00

CPC分类号： B01J29/088 ,  B01J6/002 ,  B01J8/002 ,  B01J8/0055 ,  B01J19/006 ,  B01J19/22 ,  B01J19/2415 ,  B01J29/06 ,  B01J2029/081 ,  B01J2219/0077 ,  B01J2219/18 ,  B01J2219/187 ,  B01J2219/1943 ,  B01J2219/24 ,  B01J2229/16 ,  B01J2229/32 ,  C01B39/00 ,  C01B39/026 ,  C01B39/06 ,  C01B39/24

摘要： A process for preparing a catalytic cracking catalyst, which process comprises: a molecular sieve is introduced into a gas-phase ultra-stabilization reactor, the molecular sieve is moved without the conveying of carrier gas from a molecular sieve inlet of the gas-phase ultra-stabilization reactor to a molecular sieve outlet of the gas-phase ultra-stabilization reactor, and the molecular sieve is contacted and reacted with a gaseous SiCl4 in the gas-phase ultra-stabilization reactor, the molecular sieve resulting from the contacting and the reacting is optionally washed, then mixed with a matrix and water into slurry, and shaped into particles.

公开(公告)号：US09976462B2

公开(公告)日：2018-05-22

申请号：US15281969

申请日：2016-09-30

申请人： MAN Truck & Bus AG

发明人： Florian Lutz ,  Dieter Rothe

IPC分类号： F01N3/035 ,  F01N3/10 ,  F01N3/20 ,  F01N3/24 ,  B01D53/94 ,  F01N9/00 ,  F01N13/00 ,  B01D46/00 ,  B01J23/22 ,  B01J23/72 ,  B01J29/06 ,  F01N3/023 ,  F01N11/00 ,  F01N3/08 ,  B01J35/04

CPC分类号： F01N3/035 ,  B01D46/0027 ,  B01D46/006 ,  B01D53/9431 ,  B01D53/9495 ,  B01D2255/20723 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2279/30 ,  B01J23/22 ,  B01J23/72 ,  B01J29/06 ,  B01J35/04 ,  F01N3/0231 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/103 ,  F01N3/208 ,  F01N9/00 ,  F01N11/002 ,  F01N13/002 ,  F01N13/009 ,  F01N13/0093 ,  F01N2550/05 ,  F01N2570/14 ,  F01N2610/02 ,  F01N2900/1602 ,  Y02A50/2325 ,  Y02T10/24 ,  Y02T10/47

摘要： The invention relates to a method for the operation of an exhaust gas aftertreatment system in an exhaust tract of an internal combustion engine. The exhaust gas aftertreatment system includes an SCR particle filter, a first reducing agent feed device for introducing the reducing agent into the exhaust tract upstream of the SCR particle filter, continuous regeneration of the SCR particle filter being possible using nitrogen dioxide as oxidizing agent, an SCR catalytic converter element arranged downstream of the SCR particle filter, and a second reducing agent feed device for introducing the reducing agent into the exhaust tract downstream of the SCR particle filter and upstream of the SCR catalytic converter element. A control unit regulates a quantity of reducing agent introduced into the exhaust tract by the first reducing agent feed device and/or by the second reducing agent feed device as a function of the temperature (TSCR-PF) of the SCR particle filter.

公开(公告)号：US20180127668A1

公开(公告)日：2018-05-10

申请号：US15684548

申请日：2017-08-23

申请人： Dioxide Materials, Inc.

发明人： Richard I. Masel

IPC分类号： C10L1/06 ,  C25B9/18 ,  C25B1/04 ,  C25B1/00 ,  C25B11/04 ,  C25B13/08 ,  C10L1/08 ,  C07C1/22 ,  C07C29/154 ,  C07C41/09 ,  B01J19/24 ,  B01J29/06 ,  B01J35/10

CPC分类号： C10L1/06 ,  B01J19/245 ,  B01J21/04 ,  B01J23/755 ,  B01J23/80 ,  B01J23/882 ,  B01J29/06 ,  B01J29/40 ,  B01J29/85 ,  B01J35/0006 ,  B01J35/1019 ,  C07C1/22 ,  C07C29/1518 ,  C07C29/154 ,  C07C41/09 ,  C10L1/08 ,  C10L2200/0423 ,  C10L2200/0446 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2290/38 ,  C25B1/00 ,  C25B1/04 ,  C25B9/18 ,  C25B11/0478 ,  C25B13/08 ,  Y02E60/366 ,  Y02E70/10 ,  Y02P20/52 ,  C07C11/06 ,  C07C43/043 ,  C07C31/04

摘要： A renewable fuel production system includes a carbon dioxide capture unit for extracting carbon dioxide from atmospheric air, a carbon dioxide electrolyzer for converting carbon dioxide to carbon monoxide, a water electrolyzer for converting water to hydrogen, a synfuels generator for converting carbon monoxide produced by the carbon dioxide electrolyzer and hydrogen produced by the water electrolyzer to a fuel. The fuel produced can be synthetic gasoline and/or synthetic diesel. A renewable fuel production process includes the steps of extracting carbon dioxide from atmospheric air via a carbon dioxide capture unit, converting carbon dioxide to carbon monoxide via a carbon dioxide electrolyzer, converting water to hydrogen via a water electrolyzer, and converting carbon monoxide produced via the carbon dioxide electrolyzer and H2 produced via the water electrolyzer to a fuel. The system is also capable of simultaneously or alternatively producing a separate industrial chemical.