公开(公告)号：US20230357107A1

公开(公告)日：2023-11-09

申请号：US18144083

申请日：2023-05-05

申请人： UOP LLC

发明人： Deng-Yang Jan ,  Xi Zhao ,  Jaime G. Moscoso ,  Mathias Paul Koljack ,  Gregory A. Funk

IPC分类号： C07C5/05 ,  C07C4/06 ,  C07C5/32

CPC分类号： C07C5/05 ,  C07C4/06 ,  C07C5/322 ,  C07C2529/40

摘要： A process for converting naphtha to light olefins comprises contacting a naphtha stream with a zeolitic catalyst to produce a light paraffin stream at conditions which dehydrogenate the naphtha to olefins, interconvert the olefins to lighter olefins and hydrogenate the lighter olefins to produce a light paraffin stream comprising ethane and propane. The catalyst may comprise a zeolite and a metal.

公开(公告)号：US20230278017A1

公开(公告)日：2023-09-07

申请号：US18176465

申请日：2023-02-28

申请人： UOP LLC

发明人： Deng-Yang Jan ,  Rajamani Gounder ,  Sopuruchukwu Ezenwa ,  Jaime G. Moscoso ,  Gregory Kuzmanich

IPC分类号： B01J29/70 ,  C07C2/66 ,  B01J29/76

CPC分类号： B01J29/7049 ,  C07C2/66 ,  B01J29/76 ,  C07C2529/76

摘要： A process for contacting a feed stream comprising an oxygenate feedstock and an aromatic feedstock comprising toluene with a catalyst and recovering a product comprising para-xylene. The catalyst comprises an improved MFI zeolite comprising in the calcined and ion-exchanged form a SiO2/Al2O3 ratio of from about 50 to about 600 and having a distribution of framework aluminum sites characterized by an initial xylene selectivity of greater than 70% in the TM diagnostic test.

公开(公告)号：US20230278016A1

公开(公告)日：2023-09-07

申请号：US18176459

申请日：2023-02-28

申请人： UOP LLC

发明人： Deng-Yang Jan ,  Jaime G. Moscoso ,  Lijun Xu ,  Xi Zhao

IPC分类号： B01J29/40 ,  C07C1/24 ,  C07C4/06 ,  B01J35/10 ,  B01J37/10

CPC分类号： B01J29/40 ,  C07C1/24 ,  C07C4/06 ,  B01J35/1038 ,  B01J37/105 ,  B01J35/1019 ,  C07C2529/40

摘要： An improved MFI zeolite having low aluminum occupation at intersection sites characterized by an ortho-xylene to para-xylene uptake ratio of 0.1 to about 0.55. Processes for converting hydrocarbon or oxygenate to a product comprising light olefins and/or aromatics using the improved MFI zeolite as catalyst are also disclosed. Para-xylene in the product may be greater than about 24% of the xylenes.

公开(公告)号：US11426711B2

公开(公告)日：2022-08-30

申请号：US16420066

申请日：2019-05-22

申请人： UOP LLC

发明人： Wei Pan ,  Zara Osman ,  Jaime G. Moscoso

IPC分类号： B01J27/051 ,  B01J37/00 ,  B01J37/04 ,  B01J37/20 ,  C01G53/00 ,  C07B35/02

摘要： A method of making highly an active mixed transition metal oxide material has been developed. The method may include sulfiding the metal oxide material to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

公开(公告)号：US11213803B2

公开(公告)日：2022-01-04

申请号：US16420083

申请日：2019-05-22

申请人： UOP LLC

发明人： Zara Osman ,  Wei Pan ,  Jaime G. Moscoso

IPC分类号： B01J23/00 ,  B01J35/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/20 ,  B01J23/883 ,  B01J37/08

摘要： A highly active mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

公开(公告)号：US20210205795A1

公开(公告)日：2021-07-08

申请号：US16734469

申请日：2020-01-06

申请人： UOP LLC

发明人： Eseoghene Jeroro ,  Deng-Yang Jan ,  Pelin Cox ,  Jaime G. Moscoso ,  Martha Leigh Abrams

IPC分类号： B01J29/80 ,  B01J29/18 ,  B01J29/40 ,  C07C6/12

摘要： A catalyst suitable for the conversion of aromatic hydrocarbons is described. The catalyst comprises UZM-54 zeolite; a mordenite zeolite; a binder comprising alumina, silica, or combinations, thereof; and a metal selected from one or more of: Groups VIB(6) VIIB(7), VIII(8-10) and IVA(14) of the Periodic Table. A process for transalkylation using the catalyst is also described.

公开(公告)号：US11040885B2

公开(公告)日：2021-06-22

申请号：US15996330

申请日：2018-06-01

申请人： UOP LLC

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C01B39/36 ,  C01B39/40 ,  B01J29/40 ,  B01J29/46 ,  C01B39/04 ,  B01J29/072 ,  B01J35/00 ,  B01J35/10 ,  B01J29/06

摘要： A family of crystalline aluminosilicate zeolites has been synthesized that is a layered pentasil zeolite. These zeolites are represented by the empirical formula: Mmn+Rrp+Al1-xExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as sodium or strontium, R can be a mixture of organoammonium cations and E is a framework element such as gallium, iron, boron, or indium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes. The diffraction patterns can be characterized by the following table: 2Θ
d(Å)
I/Io 7.92-7.99
11.04-11.31
m 8.79-8.88
 9.94-11.09
m 20.28-20.56
4.31-4.35
w 23.10-23.18
3.83-3.84
vs 23.86-24.05
3.69-3.72
m 29.90-30.05
2.97-2.98
w 45.02-45.17
2.00-2.01
w

公开(公告)号：US20200368733A1

公开(公告)日：2020-11-26

申请号：US16419271

申请日：2019-05-22

申请人： UOP LLC

发明人： Martha Leigh Abrams ,  Eseoghene Jeroro ,  Jaime G. Moscoso ,  Deng-Yang Jan ,  Pelin Cox

IPC分类号： B01J29/18 ,  B01J29/80 ,  B01J35/10 ,  C07C6/12 ,  C07C15/08

摘要： A modified UZM-14 zeolite is described. The modified UZM-14 zeolite has a Modification Factor of 6 or more. The modified UZM-14 zeolite may have one or more of: a Si/Al2 ratio of 14 to 30; a total pore volume in a range of 0.5 to 1.0 cc/g; at least 5% of a total pore volume being mesopores having a diameter of 10 nm of less; a cumulative pore volume of micropores and mesopores having a diameter of 100 Å or less of 0.25 cc/g or more; or a Collidine IR Bronsted acid site distribution greater than or equal to an area of 3/mg for a peak in a range of 1575 to 1700 cm−1 after desorption at 150° C. Processes of making the modified UZM-14 zeolite and transalkylation processes using the modified UZM-14 zeolite are also described.

公开(公告)号：US10822247B2

公开(公告)日：2020-11-03

申请号：US16206804

申请日：2018-11-30

申请人： UOP LLC

发明人： Zara Osman ,  Wei Pan ,  Jaime G. Moscoso

IPC分类号： C01G53/00 ,  C01G49/00 ,  C01G1/02 ,  B01J23/00 ,  B01J37/20 ,  B01J37/00 ,  B01J37/04 ,  C01G51/00 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/04

摘要： A highly active trimetallic mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

公开(公告)号：US10384986B1

公开(公告)日：2019-08-20

申请号：US16434772

申请日：2019-06-07

申请人： UOP LLC

发明人： Thulasidas Chellppannair ,  Nicholas J. Schoenfeldt ,  Andrea G. Bozzano ,  Wolfgang A. Spieker ,  Christopher D. DiGiulio ,  Gregory A. Funk ,  Jaime G. Moscoso

IPC分类号： C07C1/20 ,  C07C6/04 ,  C07C4/06 ,  B01J29/85 ,  B01J38/12 ,  B01J29/90

摘要： A process is presented for the production of light olefins. The process utilizes a SAPO-18 catalyst and is operated at an elevated pressure. The process generates higher concentrations of heavier olefins which can then be processed to generate light olefins. The processing of the heavier olefins can include metathesis reactions and olefin cracking processes.