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公开(公告)号：US12129174B2
公开(公告)日：2024-10-29
申请号：US17285576
申请日：2019-10-15
申请人： RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGY , IUCF-HYU (INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY)
发明人： Joon-Woo Kim , Young-Woong Suh , Dong-Jun Koh , Cheon-Woo Jeong
IPC分类号： C01B3/16 , B01J21/02 , B01J23/80 , B01J35/00 , B01J37/02 , B01J37/03 , B01J37/06 , B01J37/08 , B01J37/18
CPC分类号： C01B3/16 , B01J21/02 , B01J23/80 , B01J35/19 , B01J37/0236 , B01J37/031 , B01J37/06 , B01J37/08 , B01J37/18 , C01B2203/0283 , C01B2203/1076 , C01B2203/1088
摘要： The present disclosure provides a catalyst for a water gas shift reaction at middle temperature, the catalyst comprising a catalytically active component containing 40 to 80 mol % of copper (Cu), 15 to 50 mol % of zinc (Zn), and 1 to 13 mol % of aluminum (Al), relative to all metals of the catalyst, wherein an aluminum-rich layer is present in a surface layer of a particle of the catalyst. Furthermore, the present disclosure provides a preparation method of the catalyst, and a hydrogen preparation method using the same.
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2.发明授权公开(公告)号：US12036543B2
公开(公告)日：2024-07-16
申请号：US17977514
申请日：2022-10-31
发明人： Wei Huang , Fang Li , Qian Zhang , Penglong Jia , Yongjun Liu
CPC分类号： B01J37/033 , B01J23/06
摘要： The present disclosure provides a preparation method of a doped ZnO catalyst. The preparation method includes the following steps: mixing a precipitant and a first solvent to form a first solution having 1 mol/L to 5 mol/L of the precipitant by concentration; mixing one of a Cu salt or a Ga salt, a Zn salt, and a second solvent to form a second solution having Cu and Zn at a molar ratio of less than 0.05:1 and Ga and Zn at a molar ratio of less than 0.1:1; subjecting the first solution and the second solution to precipitation or hydrolysis at 50° C. to 90° C. to obtain a precipitate, and washing and drying the precipitate to obtain a precursor sample; and conducting calcination on the precursor sample at 300° C. to 500° C. for 3 h to 5 h to obtain a Cu-doped ZnO catalyst or a Ga-doped ZnO catalyst.
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3.发明公开公开(公告)号：US20240189800A1
公开(公告)日：2024-06-13
申请号：US18537124
申请日：2023-12-12
IPC分类号： B01J23/80 , B01J21/04 , B01J21/06 , B01J35/30 , B01J37/02 , B01J37/04 , B01J37/08 , B01J37/18 , C07C29/156
CPC分类号： B01J23/80 , B01J21/04 , B01J21/063 , B01J35/394 , B01J37/0215 , B01J37/0236 , B01J37/04 , B01J37/088 , B01J37/18 , C07C29/156
摘要： The present disclosure is directed to a catalyst for carbon dioxide to methanol conversion comprising: 1-10 wt % of Nickel; 5-15 wt % of Zinc; and 80-95 wt % of metal oxide, wherein the wt % is based on the total weight of the catalyst. The present disclosure also provides a method for preparation of a catalyst for carbon dioxide to methanol conversion comprising: i) dissolving 1-10 wt % nickel precursor and 5-15 wt % zinc precursor in a solvent to obtain a first mixture; ii) adding 80-95 wt % metal oxide in the first mixture as obtained in step (a) to obtain a second mixture; iii) evaporating the solvent from the second mixture as obtained in step (b), drying and calcining in air at a temperature in the range of 350° C. to 500° C. for a period in the range of 2 hr to 4 hrs to obtain calcined mixture; and iv) reducing the calcined mixture as obtained in step (c) under hydrogen atmosphere at a temperature in the range of 500° C. to 700° ° C. for a period in the range of 1 hr to 3 hrs to obtain the catalyst. The disclosure also provides a low pressure process for conversion of carbon dioxide to methanol.
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公开(公告)号：US20240149258A1
公开(公告)日：2024-05-09
申请号：US18255535
申请日：2021-12-02
IPC分类号： B01J35/00 , B01J21/06 , B01J23/26 , B01J23/30 , B01J23/34 , B01J23/36 , B01J23/652 , B01J23/656 , B01J23/68 , B01J23/72 , B01J23/755 , B01J23/80 , B01J23/86 , B01J23/888 , B01J23/889 , B01J23/89 , B01J37/02 , B01J37/34
CPC分类号： B01J35/004 , B01J21/063 , B01J23/26 , B01J23/30 , B01J23/34 , B01J23/36 , B01J23/6522 , B01J23/6527 , B01J23/6562 , B01J23/685 , B01J23/687 , B01J23/688 , B01J23/72 , B01J23/755 , B01J23/80 , B01J23/866 , B01J23/868 , B01J23/888 , B01J23/8892 , B01J23/8896 , B01J23/8906 , B01J35/0013 , B01J37/0215 , B01J37/345
摘要： Photocatalysts and methods of making and using the same are disclosed. The photocatalyst includes a TIO2 ultra-nanoparticle having a single Fe, Co, Mn, Cr, or W atom positioned as an engineered defect within the particle and a single metal catalyst atom bound proximal to the single Fe, Co, Mn, Cr, or W atom. The method of making the photocatalyst includes generating a plurality of ultra-nano TIO2 particles, each having a single Fe, Co, Mn, Cr, or W atom positioned as an engineered defect within the particle. The method further includes photodepositing a single metal catalyst atom proximal to the single Fe, Co, Mn, Cr, or W atom for at least a portion of the ultra-nano TIO2 particles, thereby creating the disclosed photocatalyst. The single metal catalyst atom is in a positive oxidation state and can be Pt, Pd, Ir, Ru, Rh, Os, Re, Au, Ni, Zn, or Cu.
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5.发明公开公开(公告)号：US20240131496A1
公开(公告)日：2024-04-25
申请号：US18371739
申请日：2023-09-21
申请人： UT-Battelle, LLC
发明人： Haiying Chen , Josh A. Pihl , Todd J. Toops
CPC分类号： B01J23/80 , B01J29/65 , B01J35/0006 , B01J35/023 , B01J35/04 , B01J35/10 , C07C41/30 , C07C2523/80 , C07C2529/65
摘要： A layered-structure, multifunctional monolith catalyst is provided. The multifunctional monolith catalyst includes a monolithic substrate. A first layer is coated on a surface of the substrate. The first layer includes a first catalyst. A second layer is formed on top of the first layer. The second layer includes a second catalyst, and the second layer is porous. Layering of the first and second catalysts reduces degradation of one or both of the first and second catalysts, and increases a yield of the reaction catalyzed by the second catalyst. A method of converting carbon dioxide to dimethyl ether using the multifunctional monolith catalyst is also provided.
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公开(公告)号：US20240043358A1
公开(公告)日：2024-02-08
申请号：US17915158
申请日：2021-04-21
发明人： Carla Moreira Santos Queiroz , Valeria Perfeito Vicentini , Michael Severance , Darren Adams , Palanichamy Manikandan , Uwe Duerr , Andreas Bachmeier
CPC分类号： C07C7/13 , B01D53/864 , B01D53/8668 , B01D53/8671 , B01J23/80 , B01J21/04 , B01J21/16 , B01J37/03 , B01J37/18 , B01D2257/502 , B01D2257/104 , B01D2257/108 , B01D2257/7022 , B01D2255/20761 , B01D2255/20792 , B01D2255/40 , B01D2256/24
摘要： Disclosed herein are a bed of materials and use of it for removing contaminants not limiting to carbon monoxide, oxygen, carbon dioxide, acetylene, hydrogen, water, carbonyl sulfide and hydrogen sulfide from lower olefins without limiting ethylene.
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公开(公告)号：US20240002224A1
公开(公告)日：2024-01-04
申请号：US18250322
申请日：2021-11-24
申请人： TOPSOE A/S
发明人： Jeremy Neil BURN , Raul MONTESANO LOPEZ , Jens SEHESTED , Susanne Lægsgaard JØRGENSEN , Niels Christian SCHJØDT
CPC分类号： C01B3/16 , C01B3/48 , B01J23/005 , B01J23/80 , B01J21/04 , B01J35/1038 , B01J35/0026 , B01J35/026 , B01J35/0066 , C01B2203/0244 , C01B2203/025 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , C01B2203/0283
摘要： The disclosure relates to a process for enriching a synthesis gas in hydrogen by contacting said synthesis gas with a water gas shift catalyst, the synthesis gas being a CO-rich synthesis gas including at least 15 vol % CO and at least 1 ppmv sulfur, and the water gas shift catalyst including Zn, Al, optionally Cu, and an alkali metal or alkali metal compound; the water gas shift catalyst is free of chromium (Cr) and iron (Fe), and has a pore volume, as determined by mercury intrusion, of 240 ml/kg or higher.
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公开(公告)号：US11851786B2
公开(公告)日：2023-12-26
申请号：US17606562
申请日：2019-05-13
发明人： Hironobu Minowa , Masaya Nohara , Mikayo Iwata , Shuhei Sakamoto , Hiroaki Taguchi , Takeshi Komatsu
摘要： A method includes a freezing process in which a solution or gel containing cellulose nanofibers is frozen to obtain a frozen component, a drying process in which the frozen component is dried in a vacuum to obtain a dry component, and a carbonizing process in which the dry component is heated and carbonized in a non-combustible atmosphere, and in the carbonizing process, the dry component is heated together with a reducing catalyst and also a material that generates a reducing gas by thermal decomposition.
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公开(公告)号：US20230391698A1
公开(公告)日：2023-12-07
申请号：US18037312
申请日：2021-11-12
IPC分类号： C07C29/153 , C07C29/154 , C07C29/152 , B01J23/62 , B01J23/80 , B01J21/06 , B01J37/02 , B01J37/03
CPC分类号： C07C29/153 , C07C29/154 , C07C29/152 , B01J23/62 , B01J23/80 , B01J21/066 , B01J37/0201 , B01J37/035 , B01J37/038
摘要： The disclosure describes a process for methanol synthesis remarkable in that it comprises the steps of (a) providing syngas (3), (b) providing at least one first catalytic composition (9) comprising at least one first methanol synthesis catalyst; (c) putting into contact said syngas (3) with said first catalytic composition (9) under first temperature conditions, to provide a first gaseous effluent (15); (d) providing at least one second catalytic composition (17) comprising at least one second methanol synthesis catalyst; (e) putting into contact at least a part of said first gaseous effluent (15) with said second catalytic composition (17), to provide a second gaseous effluent (23) and a second liquid effluent (21); (f) recovering methanol from first (15) and/or second (23) gaseous effluent. The use of a first catalytic composition (9) that comprises at least one first methanol synthesis catalyst in such a process for methanol synthesis is also described.
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公开(公告)号：US20230390744A1
公开(公告)日：2023-12-07
申请号：US18366901
申请日：2023-08-08
发明人： Stafford W. Sheehan , Chi Chen , Mahlet Garedew-Ballard , Neva Luthria , Mihir R. Shah , Qiyuan Wu
IPC分类号： B01J23/80 , B01J23/72 , B01J23/75 , B01J21/04 , B01J23/745 , B01J37/08 , B01J37/03 , B01J37/02 , B01J37/00 , C10G2/00
CPC分类号： B01J23/80 , B01J23/72 , B01J23/75 , B01J21/04 , B01J23/745 , B01J37/08 , B01J37/031 , B01J37/0213 , B01J37/0036 , C10G2/50 , C10G2300/70 , C10G2300/4081
摘要： The present disclosure provides catalysts, reactor systems, and methods for the conversion of carbon dioxide and hydrogen gas into paraffins, olefins, and other hydrocarbon products. Methods for utilization of mixtures of carbon dioxide, carbon monoxide, and hydrogen gas in a manner distinct from legacy Fischer-Tropsch reactors to produce hydrocarbons is also included.
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