公开(公告)号：US20230001385A1

公开(公告)日：2023-01-05

申请号：US17776933

申请日：2020-11-16

申请人： The Regents of The University Of California

发明人： Philip Christopher ,  Ji Qi

IPC分类号： B01J23/36 ,  B01J23/00 ,  B01J35/10 ,  B01J23/40 ,  C07C51/12

摘要： Catalysts containing a support and a metal oxide, and reactors and methods of using the catalysts in a carbonylation reaction, such as alcohol carbonylation and ester carbonylation, are described herein. The support is typically chemically inert and has a high surface area. The metal oxide typically contains a transition metal or a mixture of metals, such as rhenium, aluminum, tungsten, molybdenum, or a combination thereof. Typically, the metal oxide is mainly atomically dispersed on the surface of the support, as indicated by STEM. For example, at least 10% of the metal oxide is atomically dispersed on the surface of the support. The method includes (i) exposing a mixture of one or more alcohols or one or more esters and carbon monoxide to the catalyst. Typically, the one or more alcohols or one or more esters and carbon monoxide are in a gas phase.

公开(公告)号：US20220258136A1

公开(公告)日：2022-08-18

申请号：US17478283

申请日：2021-09-17

申请人： HONEYWELL INTERNATIONAL INC.

发明人： HAIYOU WANG ,  HSUEH S. TUNG ,  DANIEL C. MERKEL

IPC分类号： B01J23/44 ,  C07C17/354 ,  B01J23/48 ,  B01J23/40 ,  B01J35/10 ,  B01J21/04 ,  B01J37/18 ,  B01J23/70 ,  B01J23/36

摘要： An alpha-alumina support for a hydrogenation catalyst useful in hydrogenating fluoroolefins is provided.

公开(公告)号：US11369950B2

公开(公告)日：2022-06-28

申请号：US15901442

申请日：2018-02-21

申请人： Saudi Arabian Oil Company

发明人： Michele Ostraat ,  Brian Hanna ,  Maxim Bukhovko ,  Timothy J. Kucharski ,  Ke Zhang ,  Sergio Fernandez

IPC分类号： B01J35/00 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J23/02 ,  B01J23/10 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/36 ,  B01J29/40 ,  B01J29/78 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J29/48 ,  C07C6/04 ,  B01J29/076 ,  B01J29/06

摘要： A multi-functional composite catalyst includes a catalyst support material, a preformed catalyst material at least partially secured in the catalyst support, and at least one catalytically active compound supported by the catalyst support, the preformed catalyst material, or both. The catalyst support material may include fumed silica, alumina, fumed alumina, fumed titania, or combinations of these. A catalytic activity of the catalytically active compound may be different than a catalytic activity of the preformed catalyst material. The composite catalyst may be catalyst for producing propene from 2-butene and may include a zeolite as the preformed catalyst material and a metal oxide, such as tungsten oxide, as the catalytically active material. A method of making the composite catalyst may include aerosolizing a catalyst precursor mixture that includes a preformed catalyst material, catalyst support precursor, and catalytically active compound precursor, and drying the aerosolized catalyst precursor mixture.

公开(公告)号：US11285461B2

公开(公告)日：2022-03-29

申请号：US16468906

申请日：2017-11-16

申请人： SMH Co., Ltd

发明人： Amnart Jantharasuk ,  Kongkiat Suriye

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/10 ,  B01J21/12 ,  B01J23/02 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/36 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J35/00 ,  B01J29/40 ,  B01J29/16 ,  B01J29/70 ,  C10G11/04 ,  C10G65/10 ,  B01J29/076

摘要： This invention relates to a catalyst system comprising (a) at least one layer of a first catalyst comprising a dehydrogenation active metal on a solid support; (b) at least one layer of a second catalyst comprising a metal oxide; and (c) at least one layer of a third catalyst comprising a transition metal on an inorganic support; wherein the at least one layer of a second catalyst is sandwiched between the at least one layer of a first catalyst and the at least one layer of a third catalyst; and a process comprising contacting a hydrocarbon feed with the catalyst system.

公开(公告)号：US11242297B2

公开(公告)日：2022-02-08

申请号：US16712280

申请日：2019-12-12

申请人： Saudi Arabian Oil Company

发明人： Faisal H. Alshafei ,  Munir D. Khokhar ,  Noor A. Sulais ,  Mohammed R. Alalouni ,  Sohel K. Shaikh

IPC分类号： C07C2/10 ,  C07C2/12 ,  C07C11/08 ,  C07C11/06 ,  B01J23/30 ,  C07C4/06 ,  B01J23/36 ,  B01J35/00 ,  C07C5/25 ,  B01J35/10 ,  B01J23/28 ,  B01J29/035 ,  B01J29/40 ,  B01J37/08 ,  C07C6/04 ,  B01J37/02 ,  B01J29/48

摘要： Embodiments of processes and multiple-stage catalyst systems for producing propylene comprising introducing a hydrocarbon stream comprising 2-butene to an isomerization catalyst zone to isomerize the 2-butene to 1-butene, passing the 2-butene and 1-butene to a metathesis catalyst zone to cross-metathesize the 2-butene and 1-butene into a metathesis product stream comprising propylene and C4-C6 olefins, and cracking the metathesis product stream in a catalyst cracking zone to produce propylene. The isomerization catalyst zone comprises a silica-alumina catalyst with a ratio by weight of alumina to silica from 1:99 to 20:80. The metathesis catalyst comprises a mesoporous silica catalyst support impregnated with metal oxide. The catalyst cracking zone comprises a mordenite framework inverted (MFI) structured silica catalyst.

公开(公告)号：US11014862B2

公开(公告)日：2021-05-25

申请号：US16563609

申请日：2019-09-06

申请人： Mitsubishi Chemical Corporation

发明人： Takeshi Matsuo ,  Yumiko Yoshikawa ,  Takayuki Aoshima

IPC分类号： C07C29/149 ,  B01J23/36 ,  B01J21/06 ,  B01J23/656 ,  B01J27/053 ,  B01J37/18 ,  C07C29/141 ,  C07C29/132 ,  C07C29/136 ,  B01J37/08

摘要： Provided is a catalyst including a metal component including a first component that is rhenium and one or more second components selected from the group consisting of silicon, gallium, germanium, and indium and a carrier on which the metal component is supported, the carrier including an oxide of a metal belonging to Group 4 of the periodic table. Also provided is an alcohol production method in which a carbonyl compound is treated using the above catalyst. It is possible to produce an alcohol by a hydrogenation reaction of a carbonyl compound with high selectivity and high efficiency while reducing side reactions.

公开(公告)号：US20210139398A1

公开(公告)日：2021-05-13

申请号：US17154118

申请日：2021-01-21

申请人： Mitsubishi Chemical Corporation

发明人： Takeshi MATSUO ,  Yumiko YOSHIKAWA ,  Naoyuki SAKAMOTO ,  Takayuki AOSHIMA

IPC分类号： C07C29/136 ,  C01G25/02 ,  B01J23/36 ,  B01J23/14

摘要： An alcohol production method in which an alcohol is produced from a carbonyl compound, the method including producing an alcohol by using a catalyst, the catalyst including a metal component including rhenium having an average valence of 4 or less and a carrier supporting the metal component, the carrier including zirconium oxide. A catalyst for producing an alcohol by hydrogenation of a carbonyl compound, the catalyst including a carrier including zirconium oxide and a metal component supported on the carrier, the metal component including rhenium having an average valence of 4 or less.

公开(公告)号：US10919023B2

公开(公告)日：2021-02-16

申请号：US16284756

申请日：2019-02-25

申请人： Lyondell Chemical Technology, L.P.

发明人： Xueyong Yang ,  Daniel F. White ,  Beaven S. Mandimutsira

IPC分类号： C07C45/50 ,  C07C29/60 ,  B01J23/00 ,  B01J31/00 ,  B01J23/36 ,  B01J31/22 ,  C07C29/141 ,  C07C31/20 ,  B01J31/40 ,  C07C29/143 ,  C07C33/03 ,  C07C47/19

摘要： A method including hydroformylating, with syngas, allyl alcohol in an allyl alcohol feed, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a 1,4-butanediol (BDO) product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, bio-allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product; and removing a byproduct of the production of the bio-allyl alcohol prior to hydroformylating the bio-allyl alcohol and/or from the BDO-product.

公开(公告)号：US10780422B2

公开(公告)日：2020-09-22

申请号：US15561737

申请日：2016-03-23

申请人： BASF SE

发明人： Andrian Milanov ,  Ekkehard Schwab ,  Mike Hoffmann ,  Stefan Kotrel ,  Stefan Altwasser

IPC分类号： B01J23/46 ,  B01J23/656 ,  B01J23/75 ,  B01J23/755 ,  B01J23/889 ,  C07C1/04 ,  B01J23/10 ,  B01J21/06 ,  B01J37/02 ,  B01J35/00 ,  C10K3/04 ,  B01J35/10 ,  C10L3/08 ,  C01B3/58 ,  B01J23/36 ,  B01J37/00

摘要： The present invention relates to a catalytically active composition for the selective methanation of carbon monoxide in reformate streams comprising hydrogen and carbon dioxide, comprising at least one element selected from the group consisting of ruthenium, rhodium, nickel and cobalt as active component and rhenium as dopant on a support material. The catalyst according to the invention is preferably used for carrying out methanation reactions in a temperature range from 100 to 300° C. for use in the production of hydrogen for fuel cell applications.

公开(公告)号：US20200216372A1

公开(公告)日：2020-07-09

申请号：US16729147

申请日：2019-12-27

申请人： Saudi Arabian Oil Company

发明人： Sohel Shaikh ,  Raed Abudawoud ,  Zhonglin Zhang ,  Munir Khokhar ,  Miao Sun

IPC分类号： C07C6/04 ,  C07C41/06 ,  B01J37/02 ,  C07C2/10 ,  B01J21/12 ,  B01J23/36

摘要： Provided here are methods and systems to enhance the production of ethylene and MTBE from propylene using integrated metathesis and cracking processes. Also disclosed is a method for producing ethylene by at least partially metathesizing propylene in the presence of a metathesis catalyst in a reactor to produce ethylene and butenes, and at least partially cracking the butenes to further produce ethylene using a cracking catalyst positioned downstream of the metathesis catalyst in the same reactor, and further producing MTBE.