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公开(公告)号：US20240182802A1
公开(公告)日：2024-06-06
申请号：US18442628
申请日：2024-02-15
Applicant: Saudi Arabian Oil Company
Inventor： Qi Xu , Aaron Chi Akah , Musaed Salem Al-Ghrami , Zhonglin Zhang
IPC: C10G69/14 , C01B3/24 , C07C6/12 , C10G7/08 , C10G9/36 , C10G11/20 , C10G21/00 , C10G35/04 , C10G49/22
CPC classification number: C10G69/14 , C01B3/24 , C07C6/123 , C10G7/08 , C10G9/36 , C10G11/20 , C10G21/003 , C10G35/04 , C10G49/22 , C01B2203/065 , C01B2203/1241 , C10G2300/1033 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/42 , C10G2400/20 , C10G2400/30
Abstract: In accordance with one or more embodiments herein, an integrated process for upgrading a hydrocarbon oil feed stream utilizing a delayed coker, steam enhanced catalytic cracker, and an aromatics complex includes solvent deasphalting the hydrocarbon oil stream; delayed coking the heavy residual hydrocarbons; hydrotreating the delayed coker product stream and the deasphalted oil stream to form a light C5+ hydrocarbon stream and a heavy C5+ hydrocarbon stream; steam enhanced catalytically cracking the light C5+ hydrocarbon stream; steam enhanced catalytically cracking the heavy C5+ hydrocarbon stream; passing at least a portion of the light steam enhanced catalytically cracked stream, the heavy steam enhanced catalytically cracked stream, or both to a product separator to produce a olefin product stream, a naphtha product stream, and a BTX product stream; and processing the naphtha product stream in the aromatics complex to produce benzene and xylenes.
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公开(公告)号：US11866661B1
公开(公告)日：2024-01-09
申请号：US18163340
申请日：2023-02-02
Applicant: Saudi Arabian Oil Company
Inventor： Mansour Ali Al-Herz , Ali Al Jawad , Qi Xu , Aaron Akah , Musaed Salem Al-Ghrami , Zhonglin Zhang , Luis A. Rojas Cordova
IPC: C10G69/04
CPC classification number: C10G69/04 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/205 , C10G2300/301 , C10G2300/302 , C10G2300/308 , C10G2300/4006
Abstract: According to one embodiment of the present disclosure, a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream and the hydrotreated heavy stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream which includes light olefins. The light stream may be exposed to more severe FCC cracking conditions than the heavy stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions. The light stream may include hydrocarbons boiling at less than 371° C. and the heavy stream may include hydrocarbons boiling at greater than 371° C.
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公开(公告)号：US11613717B2
公开(公告)日：2023-03-28
申请号：US16633311
申请日：2018-07-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V. , SAUDI ARABIAN OIL COMPANY
Inventor： Guillermo Leal , Kareemuddin Mahaboob Shaik , Mohammed Bismillah Ansari , Hiren Shethna , Zhonglin Zhang
Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a methyl tertiary butyl ether unit producing a first process stream; passing the first process stream through a selective hydrogenation unit producing a second process stream; passing the second process stream through an isomerization unit producing a third process stream; and passing the third process stream through a hydration unit producing the fuel additive and a recycle stream.
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公开(公告)号：US20230093607A1
公开(公告)日：2023-03-23
申请号：US17404379
申请日：2021-08-17
Applicant: Saudi Arabian Oil Company
Inventor： Furqan Aljumah , Sohel Shaikh , Zhonglin Zhang
Abstract: Processes for producing olefins include passing a hydrocarbon feed to a hydrocarbon cracking unit that cracks the hydrocarbon feed to produce a cracker effluent, passing the cracker effluent to a cracker effluent separation system that separates the cracker effluent to produce at least a cracking C4 effluent including 1-butene, 1,3-butadiene, and isobutene, passing the cracking C4 effluent to an SHIU that contacts the cracking C4 effluent with hydrogen in the presence of a selective hydrogenation catalyst to produce a hydrogenation effluent having a 2-butenes concentration greater than or equal to the sum of the concentrations of 1-butene and isobutene. The processes include passing the hydrogenation effluent to a metathesis unit that contacts the hydrogenation effluent with a metathesis catalyst and a cracking catalyst downstream of the metathesis catalyst to produce a metathesis reaction effluent comprising at least propene.
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公开(公告)号：US11555156B2
公开(公告)日：2023-01-17
申请号：US17683513
申请日：2022-03-01
Applicant: Saudi Arabian Oil Company
Inventor： Miao Sun , Zhonglin Zhang , Sohel K. Shaikh , Omer Koseoglu
IPC: C10G69/06
Abstract: A catalytic upgrading process includes introducing a feed comprising crude oil to a first catalytic deasphalting reactor to deasphalt the feed, thereby producing polymerized asphaltenes and deasphalted oil (DAO). The DAO is introduced to a steam cracking unit, thereby producing pyrolysis gas (PG), which is introduced into a selective hydrogenation unit, thereby producing an olefin-free product, which can then be introduced to a separation unit. The resulting benzene-toluene-xylenes (BTX)-containing stream and liquid petroleum gas (LPG) are separated, and the BTX-containing stream is introduced to a BTX complex to produce refined BTX. After deasphalting, a wash solvent may be introduced into the first catalytic deasphalting reactor to remove the polymerized asphaltenes, regenerate the catalyst, and produce a mixture comprising the wash solvent and the polymerized asphaltenes. The wash solvent is separated from the polymerized asphaltenes.
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Patent Agency Ranking
公开(公告)号：US20230002689A1
公开(公告)日：2023-01-05
申请号：US17365008
申请日：2021-07-01
Applicant: Saudi Arabian Oil Company
Inventor： Miao Sun , Sohel K Shaikh , Ibrahim A. Abba , Noor Al-Mana , Zhonglin Zhang
Abstract: A method for upgrading pyrolysis oil includes contacting a pyrolysis oil feed with hydrogen in the presence of a mixed metal oxide catalyst in a first slurry reactor, where: the pyrolysis oil feed comprises multi-ring aromatic compounds comprising greater than or equal to sixteen carbon atoms, and contacting the pyrolysis oil feed with hydrogen in the presence of the mixed metal oxide catalyst in the first slurry reactor to convert at least a portion of the multi-ring aromatic compounds in the pyrolysis oil feed to light aromatic compounds comprising di-aromatic compounds, tri-aromatic compounds, or both, passing an intermediate stream comprising the light aromatic compounds to a second slurry reactor downstream of the first slurry reactor; and contacting the intermediate stream with hydrogen in the presence of a mesoporous zeolite supported metal catalyst in a second slurry reactor.
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公开(公告)号：US11453624B2
公开(公告)日：2022-09-27
申请号：US16992616
申请日：2020-08-13
Applicant: Saudi Arabian Oil Company
Inventor： Zhonglin Zhang , Sohel K Shaikh , Veera Venkata R Tammana , Raed H. Abudawoud , Bruce Richard Beadle , Hisham Tawfiq Bassam , Rakan Sulaiman Bilaus
IPC: C07C5/27 , C07C7/144 , C07C4/12 , C07C15/08 , B01J8/00 , B01J16/00 , B01J19/24 , C07C5/22 , C07C7/00 , C07C7/12 , C07C7/14
Abstract: A method for producing para-xylene (PX) includes introducing a C8 aromatic-containing composition to a xylene rerun column to separate the C8 aromatic-containing composition into a xylene-containing effluent and a heavy effluent and passing the xylene-containing effluent to a PX processing loop that includes a PX recovery unit operable to separate a PX product from the xylene-containing effluent, a membrane isomerization unit operable to convert a portion of the MX, OX, or both from the xylene-containing effluent to PX, an EB dealkylation unit operable to dealkylate EB from the xylene-containing effluent to produce benzene, toluene, and other C7− compounds, and a membrane separation unit operable to produce a permeate that is PX-rich and a retentate that is PX-lean. The permeate is passed to the PX recovery unit for recovery of PX, which the retentate is bypassed around the PX recovery unit circulated through the xylene processing loop.
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8.发明申请公开(公告)号：US20220243135A1
公开(公告)日：2022-08-04
申请号：US17167489
申请日：2021-02-04
Applicant: Saudi Arabian Oil Company
Inventor： Miao Sun , Noor Al-Mana , Sohel K Shaikh , Zhonglin Zhang , Fahad A. Almalki
Abstract: A system for upgrading pyrolysis oil may include a pyrolysis upgrading unit having a mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from a reaction effluent. A method for upgrading pyrolysis oil may include contacting the pyrolysis oil with hydrogen in the presence of the mixed metal oxide catalyst at reaction conditions to produce a reaction effluent. The pyrolysis oil may include multi-ring aromatic compounds. The mixed metal oxide catalyst may include a plurality of catalyst particles and each of the plurality of catalyst particles having a plurality of metal oxides. Contacting the pyrolysis oil with hydrogen in the presence of the mixed metal oxide catalyst at the reaction conditions may convert at least a portion of the multi-ring aromatic compounds in the pyrolysis oil to the light aromatic compounds.
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公开(公告)号：US11326108B1
公开(公告)日：2022-05-10
申请号：US17198705
申请日：2021-03-11
Applicant: Saudi Arabian Oil Company
Inventor： Omer Refa Koseoglu , Sohel Shaikh , Zhonglin Zhang
Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing alcohol gasoline blending components includes cracking, in a steam cracker, a hydrocarbon feed to form a first ethylene stream, a first propylene stream, and a C4 stream comprising isobutene and butadiene; reacting, in a methyl tertiary butyl ether (MTBE) unit, the C4 stream with a methanol stream to form MTBE and a butadiene-rich C4 stream; selectively hydrogenating, in a butadiene unit, the butadiene-rich C4 stream to form a butene-rich C4 stream including butene-1, cis-butene-2, and trans-butene-2; producing, in an isononanol unit, isononanol and an olefin-rich stream from the butene-rich C4 stream; and hydrating the olefin-rich stream in a hydration unit by combining the olefin-rich stream with a water stream and a catalyst composition to produce the alcohol gasoline blending components.
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公开(公告)号：US11306257B1
公开(公告)日：2022-04-19
申请号：US17198735
申请日：2021-03-11
Applicant: Saudi Arabian Oil Company
Inventor： Omer Refa Koseoglu , Sohel Shaikh , Zhonglin Zhang
IPC: C10G9/36 , C10G67/12 , C10G45/38 , C10G27/04 , C07C2/06 , C07C5/02 , C07C29/141 , C07C41/06 , C07C45/50
Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing epoxide gasoline blending components includes cracking, in a steam cracker, a hydrocarbon feed to form a first ethylene stream, a first propylene stream, and a C4 stream comprising isobutene and butadiene; reacting, in a methyl tertiary butyl ether (MTBE) unit, the C4 stream with a methanol stream to form MTBE and a butadiene-rich C4 stream; selectively hydrogenating, in a butadiene unit, the butadiene-rich C4 stream to form a butene-rich C4 stream including butene-1, cis-butene-2, and trans-butene-2; producing, in an isononanol unit, isononanol and an olefin-rich stream from the butene-rich C4 stream; and hydrogenating the olefin-rich stream by combining the olefin-rich stream with a hydrogen stream and a catalyst composition to produce the paraffins.
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