-
公开(公告)号:US20230093607A1
公开(公告)日:2023-03-23
申请号:US17404379
申请日:2021-08-17
Applicant: Saudi Arabian Oil Company
Inventor: Furqan Aljumah , Sohel Shaikh , Zhonglin Zhang
Abstract: Processes for producing olefins include passing a hydrocarbon feed to a hydrocarbon cracking unit that cracks the hydrocarbon feed to produce a cracker effluent, passing the cracker effluent to a cracker effluent separation system that separates the cracker effluent to produce at least a cracking C4 effluent including 1-butene, 1,3-butadiene, and isobutene, passing the cracking C4 effluent to an SHIU that contacts the cracking C4 effluent with hydrogen in the presence of a selective hydrogenation catalyst to produce a hydrogenation effluent having a 2-butenes concentration greater than or equal to the sum of the concentrations of 1-butene and isobutene. The processes include passing the hydrogenation effluent to a metathesis unit that contacts the hydrogenation effluent with a metathesis catalyst and a cracking catalyst downstream of the metathesis catalyst to produce a metathesis reaction effluent comprising at least propene.
-
2.
公开(公告)号:US11939540B2
公开(公告)日:2024-03-26
申请号:US18092655
申请日:2023-01-03
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K Shaikh , Raed H Abudawoud , Zhonglin Zhang , Munir D Khokhar , Furqan Aljumah
IPC: C10G69/06 , B01J19/18 , C07C1/22 , C07C4/04 , C07C4/06 , C07C5/05 , C07C6/04 , C07C41/06 , C10G51/02 , C10G51/06 , C10G65/10 , C10G65/12
CPC classification number: C10G69/06 , B01J19/1862 , C07C1/22 , C07C4/04 , C07C4/06 , C07C5/05 , C07C6/04 , C07C41/06 , C10G51/023 , C10G51/026 , C10G51/06 , C10G65/10 , C10G65/12 , B01J2219/0004 , C10G2300/1044 , C10G2400/20
Abstract: Processes for producing olefins include integration of steam cracking with a dual catalyst metathesis process. The processes include steam cracking a hydrocarbon feed to form a cracking reaction effluent containing butenes, separating the cracking reaction effluent to produce a cracking C4 effluent including normal butenes, isobutene, and 1,3-butadiene, subjecting the cracking C4 effluent to selective hydrogenation to convert 1,3-butadiene in the cracking C4 effluent to normal butenes, removing isobutene from a hydrogenation effluent to produce a metathesis feed containing normal butenes, and contacting the metathesis feed with a metathesis catalyst and a cracking catalyst directly downstream of the metathesis catalyst to produce a metathesis reaction effluent. Contacting with the metathesis catalyst causes metathesis of normal butenes to produce ethylene, propene, and C5+ olefins, and contacting with the cracking catalyst causes C5+ olefins produced through metathesis to undergo cracking reactions to produce additional propene, ethylene, or both.
-
3.
公开(公告)号:US20230151284A1
公开(公告)日:2023-05-18
申请号:US18092655
申请日:2023-01-03
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K. Shaikh , Raed H. Abudawoud , Zhonglin Zhang , Munir D. Khokhar , Furqan Aljumah
IPC: C10G69/06 , C07C1/22 , C07C4/04 , C07C4/06 , C07C5/05 , C07C6/04 , C07C41/06 , C10G51/02 , C10G51/06 , C10G65/10 , C10G65/12 , B01J19/18
CPC classification number: C10G69/06 , C07C1/22 , C07C4/04 , C07C4/06 , C07C5/05 , C07C6/04 , C07C41/06 , C10G51/023 , C10G51/026 , C10G51/06 , C10G65/10 , C10G65/12 , B01J19/1862 , C10G2400/20 , B01J2219/0004 , C10G2300/1044
Abstract: Processes for producing olefins include integration of steam cracking with a dual catalyst metathesis process. The processes include steam cracking a hydrocarbon feed to form a cracking reaction effluent containing butenes, separating the cracking reaction effluent to produce a cracking C4 effluent including normal butenes, isobutene, and 1,3-butadiene, subjecting the cracking C4 effluent to selective hydrogenation to convert 1,3-butadiene in the cracking C4 effluent to normal butenes, removing isobutene from a hydrogenation effluent to produce a metathesis feed containing normal butenes, and contacting the metathesis feed with a metathesis catalyst and a cracking catalyst directly downstream of the metathesis catalyst to produce a metathesis reaction effluent. Contacting with the metathesis catalyst causes metathesis of normal butenes to produce ethylene, propene, and C5+ olefins, and contacting with the cracking catalyst causes C5+ olefins produced through metathesis to undergo cracking reactions to produce additional propene, ethylene, or both.
-
4.
公开(公告)号:US11339332B2
公开(公告)日:2022-05-24
申请号:US16775677
申请日:2020-01-29
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K. Shaikh , Raed H. Abudawoud , Zhonglin Zhang , Munir D. Khokhar , Furqan Aljumah
Abstract: Processes for producing olefins include introducing a hydrocarbon feed to a high-severity fluidized catalytic cracking system, contacting the hydrocarbon feed with a cracking catalyst under high-severity conditions in the high-severity fluidized catalytic cracking system to produce a cracking reaction effluent comprising butene, and passing at least a portion of the cracking reaction effluent, which includes at least butene, to a metathesis system. The processes further include contacting the portion of the cracking reaction effluent with a metathesis catalyst in the metathesis system, which causes at least a portion of the butene in the cracking C4 effluent to undergo a metathesis reaction to produce a metathesis reaction effluent comprising at least one of ethylene, propene, or both. The processes may further include separating a metathesis C5+ effluent from the metathesis reaction effluent and passing the metathesis C5+ effluent back to the high-severity fluidized catalytic cracking unit.
-
5.
公开(公告)号:US11572516B2
公开(公告)日:2023-02-07
申请号:US16830759
申请日:2020-03-26
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K Shaikh , Raed H Abudawoud , Zhonglin Zhang , Munir D Khokhar , Furqan Aljumah
IPC: C10G69/06 , C07C6/04 , C07C11/06 , B01J19/18 , C07C1/22 , C07C4/04 , C07C4/06 , C07C5/05 , C07C41/06 , C10G51/02 , C10G51/06 , C10G65/10 , C10G65/12
Abstract: Processes for producing olefins include integration of steam cracking with a dual catalyst metathesis process. The processes include steam cracking a hydrocarbon feed to form a cracking reaction effluent containing butenes, separating the cracking reaction effluent to produce a cracking C4 effluent including normal butenes, isobutene, and 1,3-butadiene, subjecting the cracking C4 effluent to selective hydrogenation to convert 1,3-butadiene in the cracking C4 effluent to normal butenes, removing isobutene from a hydrogenation effluent to produce a metathesis feed containing normal butenes, and contacting the metathesis feed with a metathesis catalyst and a cracking catalyst directly downstream of the metathesis catalyst to produce a metathesis reaction effluent. Contacting with the metathesis catalyst causes metathesis of normal butenes to produce ethylene, propene, and C5+ olefins, and contacting with the cracking catalyst causes C5+ olefins produced through metathesis to undergo cracking reactions to produce additional propene, ethylene, or both.
-
6.
公开(公告)号:US20210238485A1
公开(公告)日:2021-08-05
申请号:US16775677
申请日:2020-01-29
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K. Shaikh , Raed H. Abudawoud , Zhonglin Zhang , Munir D. Khokhar , Furqan Aljumah
Abstract: Processes for producing olefins include introducing a hydrocarbon feed to a high-severity fluidized catalytic cracking system, contacting the hydrocarbon feed with a cracking catalyst under high-severity conditions in the high-severity fluidized catalytic cracking system to produce a cracking reaction effluent comprising butene, and passing at least a portion of the cracking reaction effluent, which includes at least butene, to a metathesis system. The processes further include contacting the portion of the cracking reaction effluent with a metathesis catalyst in the metathesis system, which causes at least a portion of the butene in the cracking C4 effluent to undergo a metathesis reaction to produce a metathesis reaction effluent comprising at least one of ethylene, propene, or both. The processes may further include separating a metathesis C5+ effluent from the metathesis reaction effluent and passing the metathesis C5+ effluent back to the high-severity fluidized catalytic cracking unit.
-
公开(公告)号:US20240335823A1
公开(公告)日:2024-10-10
申请号:US18296146
申请日:2023-04-05
Applicant: Saudi Arabian Oil Company
Inventor: Furqan Aljumah , Sohel Shaikh , Munir Khokhar , Zhonglin Zhang , Shatha Alabbad
CPC classification number: B01J29/40 , B01J21/08 , B01J23/54 , B01J38/02 , B01J38/40 , C10G11/05 , C10G2400/20
Abstract: A catalyst system may be regenerated by a method that includes exposing the catalyst system to a de-coking treatment. The de-coking treatment may include three consecutive treatment conditions including a first treatment condition, a second treatment condition, and a third treatment condition. The catalyst system may include a metathesis catalyst and a cracking catalyst. The metathesis catalyst may include tungsten oxide and silica carrier, and the cracking catalyst may include ZSM-5 zeolite.
-
公开(公告)号:US20240076251A1
公开(公告)日:2024-03-07
申请号:US18501691
申请日:2023-11-03
Applicant: Saudi Arabian Oil Company
Inventor: Furqan Aljumah , Sohel Shaikh , Zhonglin Zhang
CPC classification number: C07C4/06 , B01J19/0013 , C07C4/08 , C07C5/13 , C07C6/04 , B01J2219/00051 , B01J2219/00162 , B01J2219/00189
Abstract: Processes for producing olefins include passing a hydrocarbon feed to a hydrocarbon cracking unit that cracks the hydrocarbon feed to produce a cracker effluent, passing the cracker effluent to a cracker effluent separation system that separates the cracker effluent to produce at least a cracking C4 effluent including 1-butene, 1,3-butadiene, and isobutene, passing the cracking C4 effluent to an SHIU that contacts the cracking C4 effluent with hydrogen in the presence of a selective hydrogenation catalyst to produce a hydrogenation effluent having a 2-butenes concentration greater than or equal to the sum of the concentrations of 1-butene and isobutene. The processes include passing the hydrogenation effluent to a metathesis unit that contacts the hydrogenation effluent with a metathesis catalyst and a cracking catalyst downstream of the metathesis catalyst to produce a metathesis reaction effluent comprising at least propene.
-
公开(公告)号:US11845705B2
公开(公告)日:2023-12-19
申请号:US17404379
申请日:2021-08-17
Applicant: Saudi Arabian Oil Company
Inventor: Furqan Aljumah , Sohel Shaikh , Zhonglin Zhang
CPC classification number: C07C4/06 , B01J19/0013 , C07C4/08 , C07C5/13 , C07C6/04 , B01J2219/00051 , B01J2219/00162 , B01J2219/00189
Abstract: Processes for producing olefins include passing a hydrocarbon feed to a hydrocarbon cracking unit that cracks the hydrocarbon feed to produce a cracker effluent, passing the cracker effluent to a cracker effluent separation system that separates the cracker effluent to produce at least a cracking C4 effluent including 1-butene, 1,3-butadiene, and isobutene, passing the cracking C4 effluent to an SHIU that contacts the cracking C4 effluent with hydrogen in the presence of a selective hydrogenation catalyst to produce a hydrogenation effluent having a 2-butenes concentration greater than or equal to the sum of the concentrations of 1-butene and isobutene. The processes include passing the hydrogenation effluent to a metathesis unit that contacts the hydrogenation effluent with a metathesis catalyst and a cracking catalyst downstream of the metathesis catalyst to produce a metathesis reaction effluent comprising at least propene.
-
10.
公开(公告)号:US20210301213A1
公开(公告)日:2021-09-30
申请号:US16830759
申请日:2020-03-26
Applicant: Saudi Arabian Oil Company
Inventor: Sohel K Shaikh , Raed H Abudawoud , Zhonglin Zhang , Munir D Khokhar , Furqan Aljumah
Abstract: Processes for producing olefins include integration of steam cracking with a dual catalyst metathesis process. The processes include steam cracking a hydrocarbon feed to form a cracking reaction effluent containing butenes, separating the cracking reaction effluent to produce a cracking C4 effluent including normal butenes, isobutene, and 1,3-butadiene, subjecting the cracking C4 effluent to selective hydrogenation to convert 1,3-butadiene in the cracking C4 effluent to normal butenes, removing isobutene from a hydrogenation effluent to produce a metathesis feed containing normal butenes, and contacting the metathesis feed with a metathesis catalyst and a cracking catalyst directly downstream of the metathesis catalyst to produce a metathesis reaction effluent. Contacting with the metathesis catalyst causes metathesis of normal butenes to produce ethylene, propene, and C5+ olefins, and contacting with the cracking catalyst causes C5+ olefins produced through metathesis to undergo cracking reactions to produce additional propene, ethylene, or both.
-
-
-
-
-
-
-
-
-