公开(公告)号：US20240279193A1

公开(公告)日：2024-08-22

申请号：US18571443

申请日：2022-09-19

申请人： Dow Global Technologies LLC

发明人： Wen -Sheng Lee ,  Mark H. McAdon ,  Edward M. Calverley ,  Vera Santos Castro

IPC分类号： C07D301/10 ,  B01J23/68 ,  B01J37/24

CPC分类号： C07D301/10 ,  B01J23/688 ,  B01J37/24

摘要： Disclosed herein are methods of improving the life of high selectivity, silver catalysts for making ethylene oxide. Ethylene and oxygen are reacted over the high efficiency catalyst with at least one organic chloride modifier, and during a catalyst aging period of no less than 0.03 kt ethylene oxide/cubic meter catalyst, the overall catalyst chloriding effectiveness never exceeds an efficiency-maximizing optimum overall catalyst chloriding effectiveness value that corresponds to a reference feed gas composition and a set of reference reaction condition values. Reaction temperature and/or feed gas oxygen concentration are adjusted to obtain or maintain a desired value of an ethylene oxide production parameter. Once the reaction temperature and/or oxygen concentration vary by a specified amount from their respective reference values in the set of reference reaction condition values, the overall catalyst chloriding effectiveness is changed to account for a shift in the optimum (efficiency-maximizing) value.

公开(公告)号：US11642661B2

公开(公告)日：2023-05-09

申请号：US17093849

申请日：2020-11-10

申请人： Murata Manufacturing Co., Ltd.

发明人： Satoshi Kuretake ,  Kentaro Ishihara ,  Nario Sugahara

IPC分类号： B01J23/889 ,  A61L9/03 ,  B01D53/86 ,  B01J23/00 ,  B01J23/34 ,  B01J23/68 ,  B01J23/78 ,  B01J35/10 ,  C01G45/12 ,  C01G51/00 ,  C01G53/00 ,  B01J21/06 ,  B01J35/04 ,  B01D53/94 ,  B01J21/04 ,  B01J35/02 ,  B01J37/00 ,  B01J21/16

CPC分类号： B01J23/8892 ,  A61L9/03 ,  B01D53/865 ,  B01D53/8668 ,  B01D53/8687 ,  B01D53/8696 ,  B01D53/94 ,  B01J21/04 ,  B01J21/066 ,  B01J23/002 ,  B01J23/34 ,  B01J23/688 ,  B01J23/78 ,  B01J35/026 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  C01G45/125 ,  C01G45/1207 ,  C01G51/66 ,  C01G53/66 ,  B01D2255/104 ,  B01D2255/2042 ,  B01D2255/2047 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2073 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20792 ,  B01D2255/402 ,  B01D2255/9202 ,  B01D2255/9207 ,  B01D2257/7027 ,  B01D2258/01 ,  B01D2258/02 ,  B01J21/16 ,  B01J37/009 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16

摘要： A supported catalyst for decomposing an organic substance that includes a support and a catalyst particle supported on the support. The catalyst particle contains a perovskite-type composite oxide represented by AxByMzOw, where the A contains at least one selected from Ba and Sr, the B contains Zr, the M is at least one selected from Mn, Co, Ni and Fe, y+z=1, x≥0.995, z≤0.4, and w is a positive value satisfying electrical neutrality. A film thickness of a catalyst-supporting film supported on the support and containing the catalyst particle is 5 μm or more, or a supported amount as determined by normalizing a mass of the catalyst particle supported on the support by a volume of the support is 45 g/L or more.

公开(公告)号：US20180237372A1

公开(公告)日：2018-08-23

申请号：US15752181

申请日：2017-01-31

申请人： LG CHEM, LTD. ,  KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Won Jae LEE ,  Dong Su SONG ,  Yong Jin CHOE ,  Hyun Joo LEE ,  Min Su KIM

IPC分类号： C07C51/25 ,  C07C51/44 ,  C07C51/50 ,  B01J23/44 ,  B01J23/52

CPC分类号： C07C51/25 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/58 ,  B01J23/60 ,  B01J23/66 ,  B01J23/682 ,  B01J23/685 ,  B01J23/686 ,  B01J23/688 ,  B01J23/74 ,  B01J23/78 ,  B01J23/80 ,  B01J23/89 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8946 ,  B01J23/8953 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/0211 ,  B01J37/16 ,  B01J2523/00 ,  C07C51/44 ,  C07C51/50 ,  C07C57/04 ,  B01J2523/19 ,  B01J2523/22 ,  B01J2523/824

摘要： A method for preparing acrylic acid, more specifically, to a method for preparing acrylic acid under a neutral condition at high yield in a short time without using a base, unlike the prior art in which a base is essentially used. The acrylic acid is produced using a supported catalyst having a specific composition when preparing acrylic acid by oxidation of allyl alcohol. Particularly, the preparation method can recover acrylic acid rather than acrylic acid salt as a final product, and thus has an advantage that the overall process cost can be reduced by eliminating essential processes in the prior art, such as ion exchange after the acidification process required for the conversion of acrylic acid salt to acrylic acid.

公开(公告)号：US20170312689A1

公开(公告)日：2017-11-02

申请号：US15533883

申请日：2015-09-16

申请人： MITSUBISHI HEAVY INDUSTRIES, LTD.

发明人： Masatoshi KATSUKI ,  Shuuji FUJII ,  Kazuki NISHIZAWA

IPC分类号： B01D53/94 ,  F01N3/20 ,  B01J23/00 ,  B01J37/08 ,  B01J37/04 ,  B01J23/68 ,  F23R3/40 ,  F01K23/10

CPC分类号： B01D53/944 ,  B01D53/86 ,  B01D2255/104 ,  B01D2255/206 ,  B01D2255/2073 ,  B01D2255/402 ,  B01D2257/708 ,  B01J23/002 ,  B01J23/68 ,  B01J23/688 ,  B01J37/04 ,  B01J37/08 ,  F01K23/10 ,  F01N3/20 ,  F23G7/07 ,  F23R3/40 ,  Y02E20/12 ,  Y02E20/16

摘要： An exhaust gas treatment device capable of treating exhaust gas of a gas turbine or a gas engine includes an exhaust gas treatment catalyst comprising a perovskite composite oxide containing at least Ag and Dy in an A site and at least Mn in a B site.

公开(公告)号：US20170166504A1

公开(公告)日：2017-06-15

申请号：US15375252

申请日：2016-12-12

申请人： International Flavors & Fragrances Inc.

发明人： Avelino Corma Canós ,  Sara Iborra Chornet ,  Alexandra Velty ,  Manuel Querol Sans ,  Amadeo Fernández Miranda ,  Jaime Renovell Gomez

IPC分类号： C07C45/29 ,  B01J23/10 ,  B01J23/66 ,  B01J27/18 ,  B01J37/02 ,  B01J23/89 ,  B01J21/18 ,  B01J35/00 ,  B01J37/04 ,  B01J37/00 ,  B01J23/52 ,  B01J23/68

CPC分类号： C07C45/29 ,  B01J21/18 ,  B01J23/10 ,  B01J23/52 ,  B01J23/66 ,  B01J23/688 ,  B01J23/8906 ,  B01J23/894 ,  B01J27/1806 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0072 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  C07C45/39 ,  C07C49/203

摘要： A method of preparing 4-methyl-3-decen-5-one. The method includes the step of oxidizing 4-methyl-3-decen-5-ol in the presence of (i) oxygen and (ii) a metal catalyst, wherein the metal catalyst contains a catalytic metal deposited on nanoparticle support.

公开(公告)号：US09498767B2

公开(公告)日：2016-11-22

申请号：US13904271

申请日：2013-05-29

申请人： Clean Diesel Technologies, Inc.

发明人： Zahra Nazarpoor

IPC分类号： B01J23/68 ,  B01J23/00 ,  B01D53/94

CPC分类号： B01J23/688 ,  B01D53/944 ,  B01D2255/104 ,  B01D2255/2061 ,  B01D2255/2073 ,  B01D2255/402 ,  B01D2255/65 ,  B01D2258/012 ,  B01J23/002 ,  B01J2523/00 ,  B01J2523/18 ,  B01J2523/36 ,  B01J2523/72

摘要： Diesel oxidation ZPGM catalyst systems using Y1-x AgxMnO3 perovskite are disclosed. The ZPGM catalyst system compositions may include Y1-x AgxMnO3 perovskite in impregnation component and at least one carrier material oxide in washcoat. The ZPGM catalyst system compositions may also include Y1-x AgxMnO3 perovskite co-precipitated in a carrier material oxide as washcoat. The catalyst activity is measured with an inlet gas mixture containing diesel exhaust composition and characterized according to performance in NO oxidation, NO2 production, NO storage capability and diesel oxidation applications.

摘要翻译： 公开了使用Y1-x AgxMnO3钙钛矿的柴油氧化ZPGM催化剂体系。 ZPGM催化剂体系组合物可以包括在浸渍组分中的Y1-x Ag x MnO 3钙钛矿和在修补基面涂层中的至少一种载体材料氧化物。 ZPGM催化剂体系组合物还可以包括在作为修补基面涂层的载体材料氧化物中共沉淀的Y1-x AgxMnO3钙钛矿。 催化剂活性用含有柴油机废气组成的入口气体混合物测量，并根据NO氧化，NO2生产，NO储存能力和柴油氧化应用的性能进行表征。

公开(公告)号：US09233942B2

公开(公告)日：2016-01-12

申请号：US13251140

申请日：2011-09-30

申请人： Wei Lin ,  Jinbing Li ,  Jianshe Chen ,  Zhixiang Zhang ,  Qiang Lin ,  Jun Jiang ,  Shuyuan Cao ,  Qian Xue ,  Shujuan Wang ,  Zhiqiang Tang

发明人： Wei Lin ,  Jinbing Li ,  Jianshe Chen ,  Zhixiang Zhang ,  Qiang Lin ,  Jun Jiang ,  Shuyuan Cao ,  Qian Xue ,  Shujuan Wang ,  Zhiqiang Tang

IPC分类号： B01J23/50 ,  C07D301/03 ,  B01J21/04 ,  B01J23/02 ,  B01J23/04 ,  B01J23/66 ,  B01J23/68 ,  B01J35/10 ,  B01J37/00 ,  B01J37/14

CPC分类号： C07D301/03 ,  B01J21/04 ,  B01J23/02 ,  B01J23/04 ,  B01J23/50 ,  B01J23/66 ,  B01J23/688 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/14 ,  Y02P20/52

摘要： The present invention relates to an alumina support for silver catalyst, a process for preparing said alumina support, a silver catalyst made from said alumina support, and a use of said silver catalyst in the production of ethylene oxide by the oxidization of ethylene. According to the present invention, the silver catalyst made from the support prepared by potassium melt technology can have a high selectivity.

摘要翻译： 本发明涉及一种用于银催化剂的氧化铝载体，一种制备所述氧化铝载体的方法，由所述氧化铝载体制备的银催化剂，以及所述银催化剂通过乙烯氧化生产环氧乙烷的用途。 根据本发明，由通过钾熔融技术制备的载体制备的银催化剂可以具有高选择性。

公开(公告)号：US20150274689A1

公开(公告)日：2015-10-01

申请号：US14434556

申请日：2013-10-09

申请人： KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION ,  UBE INDUSTRIES, LTD.

发明人： Tamao Ishida ,  Makoto Tokunaga ,  Akiyuki Hamasaki ,  Syohei Aikawa ,  Yoshiyuki Mise ,  Tetsuro Tsuji ,  Yasushi Yamamoto ,  Mitsuru Miyasaka

IPC分类号： C07D307/89 ,  C07C17/269 ,  C07C37/11 ,  B01J23/52 ,  B01J23/89 ,  B01J23/68 ,  B01J23/66 ,  C07C67/465 ,  C07C2/84

CPC分类号： C07D307/89 ,  B01J21/063 ,  B01J21/066 ,  B01J23/52 ,  B01J23/66 ,  B01J23/68 ,  B01J23/688 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/96 ,  B01J38/12 ,  B01J38/50 ,  B01J38/52 ,  B01J38/56 ,  B01J2523/00 ,  C07B37/04 ,  C07C2/84 ,  C07C17/269 ,  C07C37/11 ,  C07C67/343 ,  C07C67/465 ,  C07C2523/52 ,  C07C2523/66 ,  C07C2523/68 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52 ,  Y02P20/584 ,  C07C69/76 ,  C07C15/14 ,  C07C22/08 ,  C07C39/15 ,  B01J2523/19 ,  B01J2523/41 ,  B01J2523/845 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/3706

摘要： A method for producing a multisubstituted biphenyl compound is represented by the following formula (2), including a step of coupling a substituted benzene compound represented by the following formula (1) in the presence of a solid catalyst with gold immobilized onto a support.

摘要翻译： 制备多取代联苯化合物的方法由下式（2）表示，包括在固体催化剂存在下将取代的苯化合物与下述式（1）表示的取代苯化合物与固定在载体上的金偶联的步骤。

公开(公告)号：US09029287B2

公开(公告)日：2015-05-12

申请号：US12998718

申请日：2009-11-09

申请人： Axel Arndt ,  Christian Doye ,  Jens Dahl Jensen ,  Ursus Krüger ,  Uwe Pyritz ,  Oliver Stier

发明人： Axel Arndt ,  Christian Doye ,  Jens Dahl Jensen ,  Ursus Krüger ,  Uwe Pyritz ,  Oliver Stier

IPC分类号： B01J23/32 ,  B01J23/58 ,  B01J23/34 ,  B01D53/86 ,  B01J23/68 ,  B01J23/889 ,  B01J37/02 ,  C23C24/04

CPC分类号： B01J23/34 ,  B01D53/8675 ,  B01D2255/104 ,  B01D2255/2073 ,  B01D2255/20753 ,  B01D2255/9022 ,  B01D2255/9202 ,  B01D2257/106 ,  B01D2259/4575 ,  B01J23/688 ,  B01J23/8892 ,  B01J37/0225 ,  C23C24/04

摘要： A component part has a catalyst surface. This surface has metallic components and components of MnO2 (13) in contact with the former. The metallic components are preferably formed of Ag and/or Ni. These material pairs achieve a great improvement in catalyst action compared to the pure metals. Especially in the case of use of Ni, which is toxicologically safe, these surfaces, for example, may also find use in ambient air purification for reduction of the ozone content. The surface can be applied, for example, by a coating of the component part, in which case the metallic component and the component of MnO2 are applied in two layers.

摘要翻译： 组分部分具有催化剂表面。 该表面具有与前者接触的金属组分和MnO 2（13）的组分。 金属成分优选由Ag和/或Ni形成。 与纯金属相比，这些材料对实现了催化剂作用的极大改进。 特别是在使用毒理学上安全的Ni的情况下，这些表面也可用于环境空气净化以减少臭氧含量。 表面可以例如通过涂覆组分部分来施加，在这种情况下，金属组分和MnO2的组分分两层施加。

公开(公告)号：US08999887B2

公开(公告)日：2015-04-07

申请号：US14524226

申请日：2014-10-27

申请人： Saint-Gobain Ceramics & Plastics, Inc.

发明人： Michael A. Richard ,  John David Covey

IPC分类号： B01J23/02 ,  B01J23/10 ,  B01J23/48 ,  B01J23/50 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J35/10 ,  C07D301/04 ,  C07C29/10 ,  C07C41/03 ,  C07C213/04

CPC分类号： B01J35/04 ,  B01J23/50 ,  B01J23/688 ,  B01J35/00 ,  B01J35/0066 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/024 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/04 ,  C07D301/08 ,  C07C215/08

摘要： A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

摘要翻译： 公开了一种载体，其具有至少三个叶片，第一端部，第二端部，端部之间的壁和在端部和壁部的交叉点处的不均匀的过渡半径。 还公开了包含载体，银和沉积在载体上并可用于烯烃的环氧化的助催化剂的催化剂。 还公开了制备载体的方法，制备催化剂的方法以及与催化剂烯烃的环氧化方法。