公开(公告)号：US12109558B2

公开(公告)日：2024-10-08

申请号：US16991555

申请日：2020-08-12

申请人： William Marsh Rice University

发明人： Nancy Jean Halas ,  Peter Nordlander ,  Hossein Robatjazi ,  Dayne Francis Swearer ,  Chao Zhang ,  Hangqi Zhao ,  Linan Zhou

IPC分类号： B01J35/39 ,  B01J19/12 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/00 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/89 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/00 ,  B01J35/23 ,  B01J35/30 ,  B01J35/33 ,  B01J35/50 ,  B01J35/64 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/34 ,  C01B3/04 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/16

CPC分类号： B01J35/39 ,  B01J19/123 ,  B01J19/127 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/002 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/8926 ,  B01J23/8946 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/19 ,  B01J35/23 ,  B01J35/30 ,  B01J35/33 ,  B01J35/393 ,  B01J35/397 ,  B01J35/50 ,  B01J35/651 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/344 ,  C01B3/047 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/1691 ,  B01J2219/00635 ,  B01J2523/00 ,  B01J2540/66 ,  C01B2203/0238 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/821

摘要： A multicomponent photocatalyst includes a reactive component optically, electronically, or thermally coupled to a plasmonic material. A method of performing a catalytic reaction includes loading a multicomponent photocatalyst including a reactive component optically, electronically, or thermally coupled to a plasmonic material into a reaction chamber; introducing molecular reactants into the reaction chamber; and illuminating the reaction chamber with a light source.

公开(公告)号：US11980872B2

公开(公告)日：2024-05-14

申请号：US16931677

申请日：2020-07-17

申请人： Lyondell Chemical Technology, L.P.

发明人： Sandor Nagy ,  Barbara Kimmich

IPC分类号： B01J23/66 ,  B01J21/16 ,  B01J23/50 ,  B01J23/68 ,  B01J23/89 ,  B01J31/26 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  C07D301/03 ,  C07D301/10

CPC分类号： B01J23/66 ,  B01J21/16 ,  B01J23/50 ,  B01J23/688 ,  B01J35/19 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/088 ,  C07D301/03 ,  C07D301/10 ,  B01J23/687 ,  B01J23/89 ,  B01J31/26 ,  B01J37/0213

摘要： Epoxidation methods and catalyst are described herein. The epoxidation catalysts generally include a metal component including silver and a support material including kaolinite, wherein the epoxidation catalyst includes less than 55 wt. % metal component.

公开(公告)号：US20240132424A1

公开(公告)日：2024-04-25

申请号：US18546075

申请日：2022-01-13

申请人： PETRÓLEO BRASILEIRO S.A. – PETROBRAS ,  UNIVERSIDADE FEDERAL DE MINAS GERAIS - UFMG

发明人： Carlos RENE KLOTZ RABELLO ,  Eduardo NICOLAU DOS SANTOS ,  Leonildo ALVES FERREIRA ,  Kelley Cristina BATISTA DE OLIVEIRA ,  Lucas Henrique REBUITI PASSOS ,  Marlito GOMES, Jr. ,  Artur VICARI GRANATO

IPC分类号： C07C1/213 ,  B01D3/14 ,  B01J21/04 ,  B01J21/18 ,  B01J23/44 ,  B01J23/50 ,  B01J31/22 ,  B01J31/24 ,  C07C7/04 ,  C07C68/00 ,  C07C68/08

CPC分类号： C07C1/213 ,  B01D3/14 ,  B01J21/04 ,  B01J21/18 ,  B01J23/44 ,  B01J23/50 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/2291 ,  B01J31/2404 ,  B01J31/2414 ,  C07C7/04 ,  C07C68/00 ,  C07C68/08 ,  B01J2231/543 ,  B01J2531/821

摘要： The present invention addresses to a process for producing olefins and esters in the C10 to C13 range from fatty acid esters through a catalytic hydrogenation reaction followed by cross-metathesis of the hydrogenated product with light olefins.

公开(公告)号：US11896961B1

公开(公告)日：2024-02-13

申请号：US18481407

申请日：2023-10-05

申请人： Jazan University

发明人： Ahmed Hussain Jawhari ,  Ibrahim Ali Radini ,  Nazim Hasan ,  Maqsood Ahmad Malik ,  Katabathini Narasimharao

IPC分类号： B01J27/18 ,  B01J23/50 ,  B01J37/34 ,  B01J37/02 ,  B01J35/06 ,  B01J35/00 ,  B01J23/30 ,  B01J31/02 ,  B01J23/42

CPC分类号： B01J27/1817 ,  B01J23/30 ,  B01J23/42 ,  B01J23/50 ,  B01J31/02 ,  B01J35/004 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/06 ,  B01J37/0221 ,  B01J37/342 ,  B01J37/343 ,  B01J37/346

摘要： The present invention combines the advantages of fabrication of semiconductor heterostructure (Ag3PO4—WO3) with plasmonic metals (Pt and Ag) with optical interference to optimize the visible light photo response of plasmonic metals deposited semiconductor (Pt—Ag/Ag3PO4—WO3) for visible light assisted H2 generation utilizing the aqueous bio-alcohols. Crystalline Ag3PO4 and WO3 nanofibers were synthesized by microwave and electrospinning methods. Three different WO3 nanofibers composition (5, 10 and 15 wt. %) were used to obtain Ag3PO4/WO3 nanocomposite heterostructures, which are effective visible light active photo catalysts. Further, a simple, enviro-friendly, and cost-effective biogenic synthesis method have been achieved using Salvia officinalis extract to decorate Pt and Ag metal nanoparticles on the surface of Ag3PO4—WO3 composites. Presence of bioactive agents in the extract are responsible for the Pt and Ag3PO4 reduction and for prevention of the Pt nanoparticles from aggregation in aqueous medium.

公开(公告)号：US20230405561A1

公开(公告)日：2023-12-21

申请号：US18450902

申请日：2023-08-16

申请人： AVN Corporation

发明人： Madan Mohan Bhasin

IPC分类号： B01J27/224 ,  C07D301/06 ,  B01J35/10 ,  C07C5/333 ,  B01J23/50 ,  B01J37/08 ,  C10G45/04 ,  B01J35/02 ,  C10G11/02 ,  B01J37/02 ,  C10G47/02

CPC分类号： B01J27/224 ,  C07D301/06 ,  B01J35/1038 ,  C07C5/3335 ,  B01J23/50 ,  B01J37/08 ,  C10G45/04 ,  B01J35/1014 ,  B01J35/1009 ,  B01J35/023 ,  B01J35/1042 ,  C10G11/02 ,  B01J37/0203 ,  C10G47/02 ,  C10G2300/207 ,  C07C2521/08 ,  C07C2521/18 ,  C10G2300/202 ,  C07C2523/50

摘要： A catalyst support comprising at least 95% silicon carbide, having surface areas of ≤10 m2/g and pore volumes of ≤1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C., and removing residual carbon from the heated support under temperatures below 1000° C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).

公开(公告)号：US20230372918A1

公开(公告)日：2023-11-23

申请号：US18028243

申请日：2021-08-24

申请人： NANJING UNIVERSITY ,  NANHUAN YANCHENG ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD. ,  NANJING UNIVERSITY & YANCHENG ACADEMY OF ENVIRONMENTAL PROTECTION TECHNOLOGY AND ENGINEERING

发明人： Jinnan WANG ,  Zhiang HOU ,  Weilin BIAN ,  Yi WANG ,  Jiangfeng CHU ,  Cong LIU

IPC分类号： B01J35/00 ,  B01J23/50 ,  B01J37/10 ,  C02F1/30

CPC分类号： B01J35/004 ,  B01J23/50 ,  B01J37/10 ,  C02F1/30 ,  C02F2101/163

摘要： A photocatalytic material for efficient photocatalytic removal of a high-concentration nitrate, and a preparation method and use thereof are disclosed. The preparation method includes the following steps: step 1: preparation of a citrate-stabilized silver nanoparticle; step 2: synthesis and functionalization modification of SiO2 step 3: preparation of Ag/SiO2; and step 4: preparation of an Ag/SiO2@cTiO2 core-shell structure. The photocatalytic material prepared by the present disclosure has high reduction catalytic activity and can quickly remove a high-concentration nitrate and achieve high nitrogen selectivity. In addition, due to protection of a titanium dioxide shell, the photocatalytic material has excellent stability and can remove a high-concentration nitrate in water when the nitrate coexists with a high-concentration chloride ion.

公开(公告)号：US11633723B2

公开(公告)日：2023-04-25

申请号：US16760479

申请日：2018-10-03

申请人： Mitsui Mining & Smelting Co., Ltd.

发明人： Michitaka Yamaguchi ,  Satoshi Watanabe

IPC分类号： B01J23/50 ,  B01D53/94 ,  B01J21/04 ,  B01J23/34 ,  B01J35/02 ,  B01J37/00 ,  F01N3/28

摘要： A composition for exhaust gas purification containing Y—Mn—O and Al2O3 and having a specific surface area (SSA) retention satisfying inequality (1) SSA retention (%) >−61.54×(Y—Mn—O ratio)+75.55 and inequality (2) SSA retention (%) >45 (2), where SSA retention is represented by (SSA after aging)/(initial SSA)×100 (%). The SSA after aging and the initial SSA are as defined in the description. The Y—Mn—O ratio is a mass ratio of Y—Mn—O to the sum of Y—Mn—O and Al2O3 in the composition for exhaust gas purification, being represented by Y—Mn—O/(Y—Mn—O+Al2O3).

公开(公告)号：US11623902B2

公开(公告)日：2023-04-11

申请号：US16660119

申请日：2019-10-22

申请人： Clariant International Ltd

发明人： Darren Adams ,  Mingyong Sun ,  Uwe Duerr ,  Denise Cooper ,  Brian Heasley ,  Ling Xu ,  Tina Clinton

IPC分类号： C07C5/09 ,  B01J31/02 ,  B01J31/28 ,  B01J21/04 ,  B01J23/44 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J23/50

摘要： The present disclosure relates to methods for selectively hydrogenating acetylene, to methods for starting up a selective hydrogenation reactor, and to hydrogenation catalysts useful in such methods. In one aspect, the disclosure provides a method for selectively hydrogenating acetylene, the method comprising contacting a catalyst composition with a process gas. The catalyst composition comprises a porous support, palladium, and one or more ionic liquids. The process gas includes ethylene, present in the process gas in an amount of at least 20 mol. %; and acetylene, present in the process gas in an amount of at least 1 ppm. At least 90% of the acetylene present in the process gas is hydrogenated, and the selective hydrogenation is conducted without thermal runaway. Notably, the process gas is contacted with the catalyst at a gas hourly space velocity (GHSV) based on total catalyst volume in one bed or multiple beds of at least 7,100 h−1.

公开(公告)号：US11602741B2

公开(公告)日：2023-03-14

申请号：US17398412

申请日：2021-08-10

申请人： Tsinghua University ,  HON HAI PRECISION INDUSTRY CO., LTD.

发明人： Ying-Cheng Wang ,  Yuan-Hao Jin ,  Xiao-Yang Xiao ,  Tian-Fu Zhang ,  Qun-Qing Li ,  Shou-Shan Fan

IPC分类号： B01J35/00 ,  B01J21/18 ,  B01J23/52 ,  B01J23/50 ,  B01J23/72 ,  B01J23/745 ,  B01J23/755 ,  B01J21/02 ,  B01J21/06 ,  B01J23/06 ,  B01J23/14 ,  B01J27/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/34 ,  C25B1/55

摘要： The disclosure relates to a method for making a photocatalytic structure, the method comprising: providing a carbon nanotube structure comprising a plurality of carbon nanotubes intersected with each other; a plurality of openings being defined by the plurality of carbon nanotubes; forming a photocatalytic active layer on the surface of the carbon nanotube structure; applying a metal layer pre-form on the surface of the photocatalytic active layer; and annealing the metal layer pre-form.

公开(公告)号：US11559799B2

公开(公告)日：2023-01-24

申请号：US17130961

申请日：2020-12-22

申请人： Scientific Design Company, Inc.

发明人： Mohammad Ganjvar

IPC分类号： B01J8/06 ,  C07D301/10 ,  B01J37/02 ,  B01J23/50 ,  B01J37/08

摘要： An ethylene oxide (EO) reactor is provided in which a removable impingement basket is configured to be inserted into the reactor inlet pipe of the EO reactor. The removable impingement basket provides protection for the silver-based catalyst filled tubes and other components that are present inside the EO reactor as well as providing another access point into the EO reactor. The removable impingement basket also can provide better distribution of the inlet gas as compared to an EO reactor containing a non-removable impingement plate.