公开(公告)号：US20210362092A1

公开(公告)日：2021-11-25

申请号：US16880275

申请日：2020-05-21

申请人： SAVANNAH RIVER NUCLEAR SOLUTIONS, LLC.

发明人： GEORGE K. LARSEN, III ,  Simona E. Hunyadi Murph

IPC分类号： B01D59/34 ,  C01B4/00

摘要： The present invention is directed to a method of separating hydrogen isotopes. The method comprises: providing an aqueous solution comprising a mixture of hydrogen isotopes comprising a first hydrogen isotope and a second hydrogen isotope and nanoparticles, and exposing the aqueous solution to at least one wavelength of light of the electromagnetic spectrum.

公开(公告)号：US20200206722A1

公开(公告)日：2020-07-02

申请号：US16612660

申请日：2018-05-11

申请人： William Marsh Rice University

发明人： Nancy Jean Halas ,  Peter Nordlander ,  Hossein Robatjazi ,  Dayne Francis Swearer ,  Chao Zhang ,  Hangqi Zhao ,  Linan Zhou

IPC分类号： B01J23/89 ,  B01J37/03 ,  B01J37/08 ,  B01J35/00 ,  B01J35/02 ,  B01J21/02 ,  B01J23/44 ,  B01J23/72 ,  B01J21/10 ,  C01B4/00 ,  C01B5/00 ,  C01B32/40 ,  C01B3/04 ,  C01B21/02 ,  C01B3/40

摘要： A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

公开(公告)号：US10381121B2

公开(公告)日：2019-08-13

申请号：US15034611

申请日：2013-11-13

申请人： SAVANNAH RIVER NUCLEAR SOLUTIONS, LLC

发明人： Xin Xiao

IPC分类号： B01D59/00 ,  G21F9/12 ,  C01B4/00 ,  G21F9/30 ,  B01D15/26 ,  B01D53/04 ,  B01D59/26 ,  B01D59/28 ,  C02F1/28 ,  C02F101/00

摘要： Methods and systems directed to the separation of tritium from an aqueous stream are described. The separation method is a multi-stage method that includes a first stage during which tritium of a tritium-contaminated aqueous stream is adsorbed onto a separation phase, a second stage during which the adsorbed tritium is exchanged with hydrogen in a gaseous stream to provide a gaseous stream with a high tritium concentration, and a third stage during which the tritium of the gaseous stream is separated from the gaseous stream as a gaseous tritium product.

公开(公告)号：US20160310898A1

公开(公告)日：2016-10-27

申请号：US15171183

申请日：2016-06-02

申请人： Kurion, Inc.

发明人： Mark S. Denton ,  Gaetan Bonhomme ,  Wesley L. Bratton ,  Nicephore Bonnet

IPC分类号： B01D59/50 ,  B01D59/30 ,  C02F1/461 ,  C01B4/00 ,  B01D59/40 ,  B01D59/12 ,  G21F9/12 ,  G21F9/02 ,  B01D59/32 ,  C02F1/72

CPC分类号： B01D59/50 ,  B01D59/12 ,  B01D59/30 ,  B01D59/32 ,  B01D59/40 ,  B01D2255/102 ,  C01B4/00 ,  C01B5/00 ,  C02F1/42 ,  C02F1/461 ,  C02F1/46104 ,  C02F1/4672 ,  C02F1/725 ,  C02F2001/46142 ,  C02F2101/006 ,  C02F2103/18 ,  C02F2201/46115 ,  C02F2201/46195 ,  C02F2209/001 ,  G21F9/02 ,  G21F9/06 ,  G21F9/12 ,  G21G1/001 ,  G21G2001/0094

摘要： A liquid phase catalytic exchange column with a catalyst is configured to receive hydrogen gas. The system uses the catalyst to exchange the hydrogen gas with the tritiated source yielding HT gas and tritiated water. The system monitors tritium content of the tritiated water. When a predetermined tritium level is detected, the tritiated water is released. The system also includes a gaseous permeation system comprising a permeable barrier for the selective extraction of gases.

摘要翻译： 具有催化剂的液相催化交换柱构造成接收氢气。 该系统使用催化剂与氚化的源交换氢气产生HT气体和氚化水。 该系统监测氚化水的氚含量。 当检测到预定的氚水平时，释放出氚化的水。 该系统还包括气体渗透系统，其包括用于选择性提取气体的可渗透屏障。

公开(公告)号：US20160284433A1

公开(公告)日：2016-09-29

申请号：US15034611

申请日：2013-11-13

申请人： SAVANNAH RIVER NUCLEAR SOLUTIONS, LLC

发明人： Xin Xiao

IPC分类号： G21F9/12 ,  B01D59/26 ,  C01B4/00 ,  B01D53/04 ,  B01D15/26 ,  C02F1/28 ,  G21F9/30 ,  B01D59/28

CPC分类号： G21F9/12 ,  B01D15/26 ,  B01D53/0423 ,  B01D53/0462 ,  B01D59/26 ,  B01D59/28 ,  B01D2253/1122 ,  B01D2257/108 ,  C01B4/00 ,  C02F1/281 ,  C02F1/285 ,  C02F2101/006 ,  G21F9/301

摘要： Methods and systems directed to the separation of tritium from an aqueous stream are described. The separation method is a multi-stage method that includes a first stage during which tritium of a tritium-contaminated aqueous stream is adsorbed onto a separation phase, a second stage during which the adsorbed tritium is exchanged with hydrogen in a gaseous stream to provide a gaseous stream with a high tritium concentration, and a third stage during which the tritium of the gaseous stream is separated from the gaseous stream as a gaseous tritium product.

摘要翻译： 描述了从含水流中分离氚的方法和系统。 分离方法是多阶段方法，其包括第一阶段，其中氚污染的水流的氚被吸附到分离相上，第二阶段中吸附的氚与氢气在气流中交换以提供 具有高氚浓度的气流，以及第三阶段，其中气态氚的氚作为气态氚产物与气流分离。

公开(公告)号：US09371272B2

公开(公告)日：2016-06-21

申请号：US14378877

申请日：2013-02-08

申请人： Shiono Chemical Co., Ltd.

发明人： Hironao Sajiki ,  Yasunari Monguchi ,  Yoshinari Sawama ,  Shinichi Kondo ,  Yasushi Sasai

IPC分类号： C07C221/00 ,  C07C67/317 ,  C07C213/02 ,  C07C51/377 ,  C01B3/02 ,  B01J37/00 ,  C01B3/04 ,  C01B4/00 ,  C07C5/05 ,  C07C51/347 ,  C07C69/78 ,  C07B31/00 ,  C07C5/08 ,  C07C5/09 ,  B01J23/06 ,  B01J23/26 ,  B01J23/755 ,  B01J23/02 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46

CPC分类号： C07C221/00 ,  B01J23/02 ,  B01J23/06 ,  B01J23/26 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/755 ,  B01J37/0036 ,  C01B3/02 ,  C01B3/042 ,  C01B4/00 ,  C07B31/00 ,  C07B2200/05 ,  C07C5/05 ,  C07C5/08 ,  C07C5/09 ,  C07C51/347 ,  C07C51/377 ,  C07C67/317 ,  C07C69/78 ,  C07C213/02 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/44 ,  Y02E60/364 ,  Y02P20/52 ,  C07C217/84 ,  C07C225/22 ,  C07C63/06 ,  C07C15/18 ,  C07C15/50

摘要： Objects are to provide efficient methods for producing hydrogen or heavy hydrogens and for hydrogenating (protiating, deuterating or tritiating) an organic compound, and to provide an equipment and the like used therefor. A method for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, in which an energy density of a rotational acceleration of 75 G or more is applied to water or heavy water for 25 minutes or more, a method for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, a method for hydrogenating (protiating, deuterating or tritiating) an organic compound, a method for dehalogenating an organic compound having halogen, and a ball for mechanochemical reaction are provided.

摘要翻译： 目的是提供用于产生氢或重氢的有效方法，并且用于氢化（促进，氘化或起泡）有机化合物，并提供用于其的设备等。 一种生产氢或重氢的方法，包括在催化剂金属存在下使水或重水进行机械化学反应，其中75或更高的旋转加速度的能量密度施加到水或重水上25分钟 以上的氢化（肟化，氘化或氚化）有机化合物的制造方法，有机化合物的氢化（保护，氘化或起泡）的方法，具有卤素的有机化合物脱卤的方法和用于机械化学反应的球 被提供。

公开(公告)号：US08979984B2

公开(公告)日：2015-03-17

申请号：US13704706

申请日：2011-06-16

申请人： Silvano Tosti ,  Nicolas Ghirelli ,  Fabio Borgognoni ,  Pierre Trabuc ,  Alessia Santucci ,  Karine Liger ,  Fabrizio Marini

发明人： Silvano Tosti ,  Nicolas Ghirelli ,  Fabio Borgognoni ,  Pierre Trabuc ,  Alessia Santucci ,  Karine Liger ,  Fabrizio Marini

IPC分类号： B01D53/22 ,  B01D69/04 ,  B01D59/32 ,  B01D63/06 ,  B01D65/00 ,  B01D71/02 ,  B01J19/18 ,  C01B3/50 ,  C01B4/00 ,  H01M4/94 ,  H01M8/06

CPC分类号： B01D69/04 ,  B01D53/228 ,  B01D59/32 ,  B01D63/06 ,  B01D65/00 ,  B01D65/003 ,  B01D71/022 ,  B01D2256/16 ,  B01D2311/13 ,  B01D2313/025 ,  B01D2313/34 ,  B01J19/1893 ,  B01J2219/0254 ,  B01J2219/0286 ,  C01B3/505 ,  C01B4/00 ,  C01B2203/041 ,  H01M4/94 ,  H01M8/0681 ,  H01M8/0687 ,  Y02E60/50

摘要： An apparatus for recovery of tritium from contaminated gaseous mixtures by way of isotope-exchange processes includes a container having a preferably cylindrical shape made of steel or other suitable metal or glass, referred to as “module” (1), which contains at least one permeator tube (T) made of metal or metal alloy selectively permeable to hydrogen and its isotopes, wherein the tube (T) is set in cantilever fashion with its free end closed, there being further provided elements for applying an axial tensile force on the free end of the permeator tube (T) and elements for electrical connection of the free end of the tube (T) to an end flange (FF) of the module (1) adjacent thereto.

摘要翻译： 用于通过同位素交换方法从受污染的气体混合物回收氚的装置包括具有优选圆柱形形状的容器，其由钢或其它合适的金属或玻璃制成，称为“模块”（1），其包含至少一个 由氢气及其同位素选择性渗透的金属或金属合金制成的渗透管（T），其中管（T）以悬臂方式设置，其自由端封闭，还提供了用于在自由端上施加轴向张力的元件 渗透管（T）的端部和用于将管（T）的自由端电连接到与其相邻的模块（1）的端部法兰（FF）的元件。

公开(公告)号：US20150025264A1

公开(公告)日：2015-01-22

申请号：US14378877

申请日：2013-02-08

申请人： Shiono Chemical Co., Ltd.

发明人： Hironao Sajiki ,  Yasunari Monguchi ,  Yoshinari Sawama ,  Shinichi Kondo ,  Yasushi Sasai

IPC分类号： C07C221/00 ,  C07C5/05 ,  C07C51/347 ,  C07C69/78 ,  C01B4/00 ,  C01B3/04

CPC分类号： C07C221/00 ,  B01J23/02 ,  B01J23/06 ,  B01J23/26 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/755 ,  B01J37/0036 ,  C01B3/02 ,  C01B3/042 ,  C01B4/00 ,  C07B31/00 ,  C07B2200/05 ,  C07C5/05 ,  C07C5/08 ,  C07C5/09 ,  C07C51/347 ,  C07C51/377 ,  C07C67/317 ,  C07C69/78 ,  C07C213/02 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/44 ,  Y02E60/364 ,  Y02P20/52 ,  C07C217/84 ,  C07C225/22 ,  C07C63/06 ,  C07C15/18 ,  C07C15/50

摘要： Objects are to provide efficient methods for producing hydrogen or heavy hydrogens and for hydrogenating (protiating, deuterating or tritiating) an organic compound, and to provide an equipment and the like used therefor. A method for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, in which an energy density of a rotational acceleration of 75 G or more is applied to water or heavy water for 25 minutes or more, a method for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, a method for hydrogenating (protiating, deuterating or tritiating) an organic compound, a method for dehalogenating an organic compound having halogen, and a ball for mechanochemical reaction are provided.

摘要翻译： 目的是提供用于产生氢或重氢的有效方法，并且用于氢化（促进，氘化或起泡）有机化合物，并提供用于其的设备等。 一种生产氢或重氢的方法，包括在催化剂金属存在下使水或重水进行机械化学反应，其中75或更高的旋转加速度的能量密度施加到水或重水上25分钟 以上的氢化（肟化，氘化或氚化）有机化合物的制造方法，有机化合物的氢化（保护，氘化或起泡）的方法，具有卤素的有机化合物脱卤的方法和用于机械化学反应的球 被提供。

公开(公告)号：US08592487B2

公开(公告)日：2013-11-26

申请号：US12387327

申请日：2009-04-28

申请人： Scott L. Harbeson

发明人： Scott L. Harbeson

IPC分类号： A61K31/34 ,  A01N43/08 ,  C07D493/00 ,  C01B4/00

CPC分类号： C07B59/002 ,  C07D493/04

摘要： This invention relates to novel compounds that are hydroxyethylamino sulfonamide derivatives and pharmaceutically acceptable salts thereof. More specifically, this invention relates to novel hydroxyethylamino sulfonamide derivatives that are derivatives of darunavir. This invention also provides compositions comprising one or more compounds of this invention and a carrier and the use of the disclosed compounds and compositions in methods of treating diseases and conditions that are beneficially treated by administering a human immunodeficiency virus (HIV) protease inhibitor, such as darunavir.

公开(公告)号：US20120164063A1

公开(公告)日：2012-06-28

申请号：US13414300

申请日：2012-03-07

申请人： George H. Miley ,  Xiaoling Yang

发明人： George H. Miley ,  Xiaoling Yang

IPC分类号： C01B4/00 ,  B01J19/00 ,  C01B3/02 ,  B82Y30/00

CPC分类号： C01B4/00 ,  B01J23/44 ,  B01J23/755 ,  B01J23/892 ,  B82Y30/00

摘要： A method includes operating a gas loading system with a source of one or more isotopes of hydrogen, a gas loading chamber containing a number of metallic nanoparticles, the metallic nanoparticles being selected to provide for a predetermined hydrogen cluster formation density, a vacuum system, and a valve system in communication with the gas loading chamber, the source of one or more isotopes of hydrogen and the vacuum system; providing the gas loading chamber with a first quantity of the one or more isotopes of hydrogen from the source of one or more isotopes of hydrogen; monitoring an operating temperature; and cycling a loading pressure of the gas loading chamber using the source of one or more isotopes of hydrogen in response to providing the gas loading chamber and monitoring the operating temperature.

摘要翻译： 一种方法包括操作具有一个或多个氢同位素源的气体装载系统，包含多个金属纳米颗粒的气体加载室，选择该金属纳米颗粒以提供预定的氢簇形成密度，真空系统和 与气体加载室连通的阀门系统，一个或多个氢同位素源和真空系统; 向所述气体装载室提供来自氢的一种或多种同位素的来源的第一量的一种或多种氢的同位素; 监测工作温度; 以及响应于提供所述气体负载室并监测所述工作温度，使用所述一个或多个氢同位素的源循环所述气体负载室的负载压力。