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    METHOD FOR OLEFINS PRODUCTION
    5.
    发明申请
    METHOD FOR OLEFINS PRODUCTION 有权
    油脂生产方法

    公开(公告)号：US20140018594A1

    公开(公告)日：2014-01-16

    申请号：US14005542

    申请日：2012-03-28

    Applicant: Emma Palo ,  Gaetano Iaquaniello

    Inventor： Emma Palo ,  Gaetano Iaquaniello

    IPC: C07C5/32

    CPC classification number: C07C5/321 ,  B01D53/22 ,  B01D2256/24 ,  B01D2257/108 ,  C07C5/3335 ,  C07C5/3337 ,  C07C2523/26 ,  C07C2523/42 ,  Y10T29/49718 ,  C07C11/02

    Abstract: Disclosed is a process for the catalytic dehydrogenation of alkanes so as to form the corresponding olefins. The reaction mixture is subjected to membrane separation of hydrogen, in a separate unit. Preferably a plurality of alternating reaction and separation units is used. The process of the invention serves the purpose of reducing coke formation on the catalyst, and also of achieving a higher alkane conversion without a similar increase in coke formation. The process can also be used for the production of hydrogen.

    Abstract translation: 公开了烷烃的催化脱氢以形成相应的烯烃的方法。 将反应混合物在单独的单元中进行氢分离。 优选地，使用多个交替的反应和分离单元。 本发明的方法用于减少催化剂上的焦炭形成，并且还实现了较高的烷烃转化率而没有类似的焦炭形成增加。 该方法也可用于生产氢气。

    HYDROGEN REMOVAL FROM DEHYDROGENATION REACTOR PRODUCT
    6.
    发明申请
    HYDROGEN REMOVAL FROM DEHYDROGENATION REACTOR PRODUCT 审中-公开
    从脱氢反应器产物中除去氢

    公开(公告)号：US20120190904A1

    公开(公告)日：2012-07-26

    申请号：US13352339

    申请日：2012-01-18

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C5/333 ,  B01D53/22 ,  B01J19/00

    CPC classification number: B01D53/22 ,  B01D2311/04 ,  B01D2311/103 ,  B01D2311/263 ,  B01D2311/2673 ,  B01J2219/00006 ,  C01B3/503 ,  C01B3/505 ,  C01B2203/0405 ,  C01B2203/048 ,  C07C5/3335 ,  C07C7/144 ,  C10G45/00 ,  C10G2300/1081 ,  C10G2300/1096 ,  C10G2300/807 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  C07C15/46

    Abstract: Disclosed is a dehydrogenation method that includes supplying a feed containing a hydrocarbon and steam into a dehydrogenation reactor containing a dehydrogenation catalyst, contacting the hydrocarbon and steam with the dehydrogenation catalyst to form a dehydrogenation product, wherein the dehydrogenation product comprises a dehydrogenated hydrocarbon, unreacted feed, steam and hydrogen, passing the dehydrogenation product through a membrane separator, and permeating hydrogen through a membrane positioned in the membrane separator. The hydrocarbon can be an alkyl aromatic and the dehydrogenated hydrocarbon can be a vinyl aromatic hydrocarbon, optionally the hydrocarbon can be an alkane and the dehydrogenated hydrocarbon can be an alkene.

    Abstract translation: 公开了一种脱氢方法，其包括将含有烃和蒸汽的进料供应到含有脱氢催化剂的脱氢反应器中，使烃和蒸汽与脱氢催化剂接触以形成脱氢产物，其中脱氢产物包含脱氢烃，未反应的原料 ，蒸汽和氢气，使脱氢产物通过膜分离器，并通过位于膜分离器中的膜渗透氢气。 烃可以是烷基芳族化合物，脱氢的烃可以是乙烯基芳族烃，任选的烃可以是烷烃，脱氢的烃可以是烯烃。

    Bismuth molybdate-based catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof
    8.
    发明授权
    Bismuth molybdate-based catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof 有权
    钼酸铋基催化剂，其制备方法和使用该催化剂制备1,3-丁二烯的方法

    公开(公告)号：US08003840B2

    公开(公告)日：2011-08-23

    申请号：US12297352

    申请日：2007-03-16

    Applicant: Seung Hoon Oh ,  Seong Jun Lee ,  Tae Jin Kim ,  Ahn Seop Choi ,  Young Min Chung ,  In Kyu Song ,  Ji Chul Jung ,  Hee Soo Kim

    Inventor： Seung Hoon Oh ,  Seong Jun Lee ,  Tae Jin Kim ,  Ahn Seop Choi ,  Young Min Chung ,  In Kyu Song ,  Ji Chul Jung ,  Hee Soo Kim

    IPC: C07C5/09 ,  C07C5/327

    CPC classification number: B01J35/0006 ,  B01J23/31 ,  B01J35/002 ,  B01J37/03 ,  C07C5/3335 ,  C07C2523/644 ,  C07C11/167

    Abstract: This invention relates to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, and to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, in which 1,3-butadiene can be prepared through oxidative dehydrogenation directly using a C4 mixture including n-butene and n-butane as a reactant in the presence of a mixed-phase bismuth molybdate catalyst including α-bismuth molybdate (Bi2Mo3On) and γ-bismuth molybdate (Bi2MoO6). According to this invention, the C4 raffinate, containing many impurities, is used as a reactant, without an additional n-butane separation process, thus obtaining 1,3-butadiene at high yield. Unlike complicated multicomponent-based metal oxides, the catalyst of the invention has simple constituents and synthesis routes, and can be easily formed through physical mixing, and thus is very advantageous in assuring reproducibility and can be directly applied to commercial processes.

    Abstract translation: 本发明涉及钼酸铋催化剂及其制备方法，以及使用其制备1,3-丁二烯的方法，以及钼酸铋催化剂及其制备方法以及制备1,3-丁二烯的方法 使用它们，其中1,3-丁二烯可以通过氧化脱氢直接使用包含正丁烯和正丁烷的C4混合物作为反应物在钼酸铋钼酸盐混合物存在下进行制备（其中， Bi2Mo3On）和γ-钼酸铋（Bi2MoO6）。 根据本发明，不含额外的正丁烷分离方法，将含有许多杂质的C4萃余液用作反应物，从而以高产率获得1,3-丁二烯。 不同于复合多组分金属氧化物，本发明的催化剂具有简单的组成和合成路线，并且可以通过物理混合容易地形成，因此在确保再现性方面是非常有利的，并且可以直接应用于商业过程。

    Hybrid autothermal catalytic process for converting alkanes to alkenes and catalysts useful for same
    10.
    发明申请
    Hybrid autothermal catalytic process for converting alkanes to alkenes and catalysts useful for same 审中-公开
    用于将烷烃转化为烯烃的混合自热催化方法和对其有用的催化剂

    公开(公告)号：US20100030004A1

    公开(公告)日：2010-02-04

    申请号：US12459969

    申请日：2009-07-10

    Applicant: Scott Han ,  Wolfgang Ruettinger

    Inventor： Scott Han ,  Wolfgang Ruettinger

    IPC: C07C5/333

    CPC classification number: C07C5/3332 ,  C07C5/3335 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/02 ,  C07C2523/08 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/745 ,  C07C2523/755 ,  Y02P20/51 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/06

    Abstract: The present invention relates to a thermally integrated multi-zone process for conversion of alkanes to their corresponding alkenes, involving endothermically converting an alkane to its corresponding alkene by soft oxidant conversion in an endothermic reaction zone, in the presence of a weak oxidant, a suitable catalyst, and heat, to produce an intermediate product gas comprising the corresponding alkene and hydrogen. The weak oxidant may be, for example, carbon dioxide. The hydrogen is then removed from the intermediate product gas by contacting the intermediate product gas, in an exothermic reaction zone, with different second catalyst, and oxygen, to combust the hydrogen and produce a heated product stream comprising the corresponding alkene, water and heat. Heat is recovered from the heated product stream and recycled back to the endothermic reaction zone, while the resulting cooled product stream comprising the corresponding alkene may be subjected to further reaction and/or processing.

    Abstract translation: 本发明涉及一种用于将烷烃转化成其相应烯烃的热集成多区域方法，包括在弱氧化剂存在下，通过在吸热反应区中的软氧化剂转化将烷烃吸附转化成其相应的烯烃，合适的 催化剂和热，以产生包含相应的烯烃和氢气的中间产物气体。 弱氧化剂可以是例如二氧化碳。 然后通过使中间产物气体，在放热反应区中与不同的第二催化剂和氧气接触，将氢气从中间产物气体中除去，以燃烧氢气并产生包含相应的烯烃，水和热的加热产物流。 从加热的产物流中回收热量并再循环回到吸热反应区，而包含相应烯烃的所得冷却产物流可进行进一步的反应和/或处理。

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