Abstract:
A method for retrofitting an existing steam methane reformer (SMR) for ammonia cracking is provided. In this embodiment, the existing SMR can include a pre-reformer, a desulfurization unit, a furnace, waste heat recovery sections, a water gas shift reactor, a pressure swing adsorption (PSA) unit, wherein the furnace has a plurality of SMR tubes and a plurality of burners. In certain embodiments, the method can include the steps of: providing the existing SMR; taking the desulfurization unit offline such that no fluid flows through the desulfurization during operation; taking the pre-reformer offline such that no fluid flows through the pre-reformer during operation; and adding means for providing a gaseous ammonia stream to the SMR tubes.
Abstract:
A method for converting an existing steam methane reformer (SMR) to produce hydrogen via ammonia cracking is provided. The method can include the steps of: providing the existing SMR, wherein the SMR was formerly used to produce hydrogen from a hydrocarbon feedstock; and improving the nitridation resistance of the inner surface of the equipment by adding a protective layer to an inner surface of equipment to be used in the existing SMR, wherein the equipment is selected from the group consisting of a catalyst tube, feed piping, a feed preheater, process gas heat exchangers, and combination thereof.
Abstract:
In various embodiments, a microreactor features a corrosion-resistant microchannel network encased within a thermally conductive matrix material that may define therewithin one or more hollow heat-exchange conduits.
Abstract:
A polymerization reactor of the present invention includes a container body 1 and a jacket 2 covering the outer surface of the container body 1 and defining a passage for passing a cooling/heating medium between itself and the outer surface of the container body. The container body 1 is made of a clad metal plate including a support metal layer 11a having an inner surface at an inner side of the container body and an outer surface at an outer side of the container body, and an inner corrosion-resistant metal skin layer 11b bonded to the inner surface of the support metal layer and being smaller in thickness than the support metal layer.
Abstract:
In one aspect, a method of producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including providing a carbonaceous material; mixing elemental sulfur with the carbonaceous material; and heating the mixed sulfur and the carbonaceous material at a temperature from about 445° C. to about 1000° C. for a period of time and under a pressure greater than 1 atm to generate a sulfur vapor to infuse the carbonaceous material to result in a sulfur-infused carbonaceous material. In another aspect, a reactor for producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including a reactor body capable of withstanding a pressure from about 1 atm to about 150 atm; and an inner sulfur-resistant layer at the inner surface of the reactor, wherein the inner layer is inert to sulfur vapor at a temperature from about 450° C. to about 1000° C.
Abstract:
In an embodiment, a method of producing carbonate can comprise: reacting a feed comprising carbon monoxide and chlorine in a tube of a reactor to produce a product composition comprising phosgene, wherein the tube has a particulate catalyst contained therein, wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst, and wherein carbon tetrachloride is present in the product composition in an amount of 0 to 10 ppm by volume based on the volume of the phosgene; and reacting a monohydroxy compound with the phosgene to produce the carbonate.
Abstract:
Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.
Abstract:
Systems and methods for reducing or eliminating corrosion of components of a reactor system, including a supercritical water gasification system, are described. The reactor system may include various system components, such as one or more pre-heaters, heat exchangers and reactor vessels. The system components may be configured to receive a reactor fluid corrosive to an inner surface thereof and to separately receive a protective fluid that has a higher density and is substantially immiscible with the reactor fluid. A rotating element may be configured to generate a rotational force that forces at least a portion of the protective fluid to flow in a layer between the reactor fluid and at least a portion of the inner surface, the layer operating to reduce corrosion by forming a barrier between the reactor fluid and at least a portion of the inner surface.
Abstract:
Reactor and method of forming reactor that includes at least one wall section having an inner surface bounding an interior space, a lining arranged on the inner surface of the at least one wall to face the interior space, and at least one fluid connection, to which a negative pressure is appliable, that is structured to run through the at least one wall section to open into a space between the inner surface and the lining.
Abstract:
A process for converting oxygenates to olefins comprising: a) providing an oxygenate containing stream to an oxygenate to olefins conversion reactor; b) passing the oxygenate containing stream through a feed introduction system comprising one or more nozzles and one or more corresponding caps; c) contacting the oxygenate containing stream with a molecular sieve catalyst in the oxygenate to olefins conversion reactor to form an olefin containing product stream; and d) removing the product stream from the reactor.