Method for preparing dialkyl carbonate
    5.
    发明授权
    Method for preparing dialkyl carbonate 有权
    碳酸二烷基酯的制备方法

    公开(公告)号:US09371269B2

    公开(公告)日:2016-06-21

    申请号:US14100078

    申请日:2013-12-09

    IPC分类号: C07C68/00

    CPC分类号: C07C68/00 C07C69/96

    摘要: The present invention provides a method for preparing dialkyl carbonate from urea or alkyl carbamate and alkyl alcohol using an ionic liquid comprising a cation, which produces a hydrogen ion, and a hydrophobic anion containing fluorine with high temperature stability in the presence of catalyst containing a metal oxide or hydrotalcite. Since the present invention can prepare dialkyl carbonate at a pressure lower than those of existing methods, it does not require an expensive pressure control device and peripheral devices for maintaining high pressure including the installation cost. It is also the method for preparing a dialkyl carbonate with high yield, thus improving economical efficiency. Moreover, the method of the present invention hardly produces any waste during the process and is thus an eco-friendly method.

    摘要翻译: 本发明提供一种在含有金属的催化剂存在下,使用含有产生氢离子的阳离子的离子液体和含有氟的疏水性阴离子,由脲或烷基氨基甲酸酯和烷基醇制备碳酸二烷基酯的方法, 氧化物或水滑石。 由于本发明可以以比现有方法低的压力制备碳酸二烷基酯,所以不需要昂贵的压力控制装置和用于保持高压的外围装置,包括安装成本。 也是以高产率制备碳酸二烷基酯的方法,从而提高了经济性。 此外,本发明的方法在该方法中几乎不产生浪费,因此是一种环保方法。

    Method for preparing dialkyl carbonate
    6.
    发明授权
    Method for preparing dialkyl carbonate 有权
    碳酸二烷基酯的制备方法

    公开(公告)号:US09334228B2

    公开(公告)日:2016-05-10

    申请号:US14057111

    申请日:2013-10-18

    IPC分类号: C07C68/00

    摘要: Disclosed is a method for preparing a dialkyl carbonate, in which a dialkyl carbonate such as dimethyl carbonate is economically prepared in an environmentally-friendly manner at a higher yield while reducing generation of a by-product. The method for preparing the dialkyl carbonate includes reacting urea, an alkyl carbamate having 1 to 3 carbon atoms, or a mixture thereof with a monovalent alcohol having 1 to 3 carbon atoms in the presence of a room temperature ionic liquid and a catalyst including a salt of a transition metal or a rare earth metal.

    摘要翻译: 公开了一种制备碳酸二烷基酯的方法,其中碳酸二烷基酯如碳酸二甲酯以较高的产率以环保的方式经济地制备,同时减少副产物的产生。 制备碳酸二烷基酯的方法包括在室温离子液体和包含盐的催化剂存在下使脲,具有1至3个碳原子的氨基甲酸烷基酯或其混合物与具有1至3个碳原子的一元醇反应 过渡金属或稀土金属。

    METHOD FOR PREPARING DIALKYL CARBONATE
    9.
    发明申请
    METHOD FOR PREPARING DIALKYL CARBONATE 有权
    制备碳酸二乙酯的方法

    公开(公告)号:US20140051880A1

    公开(公告)日:2014-02-20

    申请号:US14057111

    申请日:2013-10-18

    IPC分类号: C07C68/00

    摘要: Disclosed is a method for preparing a dialkyl carbonate, in which a dialkyl carbonate such as dimethyl carbonate is economically prepared in an environmentally-friendly manner at a higher yield while reducing generation of a by-product. The method for preparing the dialkyl carbonate includes reacting urea, an alkyl carbamate having 1 to 3 carbon atoms, or a mixture thereof with a monovalent alcohol having 1 to 3 carbon atoms in the presence of a room temperature ionic liquid and a catalyst including a salt of a transition metal or a rare earth metal.

    摘要翻译: 公开了一种制备碳酸二烷基酯的方法,其中碳酸二烷基酯如碳酸二甲酯以较高的产率以环保的方式经济地制备,同时减少副产物的产生。 制备碳酸二烷基酯的方法包括在室温离子液体和包含盐的催化剂存在下使脲,具有1至3个碳原子的氨基甲酸烷基酯或其混合物与具有1至3个碳原子的一元醇反应 的过渡金属或稀土金属。

    Process for producing diphenyl carbonate
    10.
    发明授权
    Process for producing diphenyl carbonate 有权
    生产碳酸二苯酯的方法

    公开(公告)号:US08569534B2

    公开(公告)日:2013-10-29

    申请号:US13364997

    申请日:2012-02-02

    申请人: J. Yong Ryu

    发明人: J. Yong Ryu

    IPC分类号: C07C69/96

    摘要: Processes for producing diaryl carbonates are disclosed, where such processes may provide for the production of diaryl carbonates from green house gases, such as carbon dioxide. The processes disclosed advantageously integrate diethyl carbonate and diaryl carbonate production, eliminating the need for solvent-based extractive distillation, as is commonly required when producing diaryl carbonates from dimethyl carbonate, providing for the integration of separation equipment and raw material usage, and reducing the operating and capital requirements for such processes. In some embodiments, processes disclosed herein may be operated essentially closed-loop with respect to ethanol usage, for example.

    摘要翻译: 公开了制备碳酸二芳基酯的方法,其中这些方法可以提供从温室气体如二氧化碳生产碳酸二芳基酯。 所公开的方法有利地整合碳酸二乙酯和碳酸二芳基酯生产,消除了对从碳酸二甲酯制备碳酸二芳基酯时通常需要的溶剂型萃取蒸馏的需要,提供了分离设备和原料的使用的一体化,并且减少了操作 以及此类流程的资本要求。 在一些实施方案中,例如,本文公开的方法可以相对于乙醇使用基本上闭环操作。