摘要:
A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.
摘要:
A system including a catalytic heat exchanger reactor configured to carry out exothermic decomposition of stable chemical species possessing positive heats of formation. In an embodiment, the reactor is configured to enhance decomposition reaction rates by contacting gas entering with a hot surface. The catalytic heat exchanger is configured to receive N2O and create N2 and O2. A torch is created by fuel together with the hot N2 and the O2. In an embodiment, the reactor is configured to, after an initial period of time, to allow a rapid transfer of products of the decomposition reaction into an engine. In an embodiment, the reactor is configured to enhance decomposition reaction rates by contacting gas entering with a hot surface, and the catalytic heat exchanger reactor is configured to promote the atomization and vaporization of liquid and gelled fuels with gas. Other embodiments are also disclosed.
摘要:
This invention relates to a method and apparatus for recycling plastics, electronics, munitions or propellants. In particular, the method comprises reacting a feed stock with a molten aluminum or aluminum alloy bath. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.
摘要:
The present invention applies carbon nanotubes to catalyst particles, thereby providing catalyst particles which are usable in fluidized bed reactions, have high catalytic activity, and are easy to handle. The catalyst particles are carbon nanotube-coated catalyst particles which each comprise a carrier particle and a coating layer disposed on the surface of the carrier particle, wherein the carrier particles are flowable in fluidized beds and the coating layer comprises carbon nanotubes which have metal nanoparticles supported thereon and/or which have been doped with nitrogen or boron. The carbon nanotube-coated catalyst particles are flowable in fluidized bed reactions.
摘要:
A method of reducing the concentration of NOx nitrogen oxides in tail gas obtained during the startup of a plant for preparation of nitric acid may involve heating the tail gas as a result of measures for preparation of nitric acid from a starting temperature T0, through a threshold temperature TG, and to an operating temperature TB at which steady-state operation of the plant can be effected (T0
摘要:
In a method for capturing carbon, sulfur, and/or nitrogen from a target source, a matrix including activated metal dispersed in a metal activating agent is provided. The target source may be or include a carbon, sulfur, and/or nitrogen target compound. The target source is contacted with the matrix, wherein the activated metal reacts with the target source to produce elemental carbon, elemental sulfur, elemental nitrogen, and/or one or more compounds transformed from the target compound(s). The matrix may be produced by contacting a metal with the metal activating agent, and maintaining contact between the metal and the metal activating agent for a period of time sufficient for metal atoms from the solid metal to disperse in the metal activating agent. The reaction may also produce a metal compound. The activated metal may also be utilized in alkylation and other synthesis processes.
摘要:
A method to produce N2O from organic nitrogen and/or reactive nitrogen in waste uses a bioreactor coupled to a hardware reactor device in which the N2O is consumed in a gas phase chemical reaction, e.g., catalytic decomposition to form oxygen and nitrogen gas. Heat from the exothermic reaction may be used to generate power. The N2O may alternatively be used as an oxidant or co-oxidant in a combustion reaction, e.g., in the combustion of methane.
摘要:
A copper-based catalyst which is suitable for converting ammonia of high concentration and with better selectivity, thereby solving a problem of pollution and toxicity due to nitrogen oxides by a conventional catalyst reacting under high temperature is disclosed. The copper-based catalyst comprises: a porous oxide support and a low valent copper compound mixing with the porous oxide support by an acid hydrothermal method; wherein the low valent copper compound with is Cu and Cu2O.
摘要:
A method for completely reducing an inorganic halide to obtain a non-halogen inorganic substance and/or hydride thereof and preferably anhydrous hydrogen halide fluid using inorganic halide substances, such as sulfur hexafluoride, nitrogen trifluoride, tungsten hexafluoride, uranium hexafluoride and others by reduction with a reducing agent at a proper temperature. The reducing agents may be molecular hydrogen, inorganic hydrides and inorganic metallic elements; molecular hydrogen is preferable, but in certain instances the inorganic hydrides are used, as well as inorganic metallic elements such as calcium and magnesium.
摘要:
A method and device for the catalytic decomposition of laughing gas in a laughing-gas-bearing gas. The method includes diluting the laughing-gas-bearing gas with a diluting gas, while forming a laughing-gas-bearing charge gas. The laughing-gas bearing charge gas is passed through a heat-exchange step where heat exchange occurs with an exhaust. A heating step occurs for occasional heating of the laughing-gas-bearing charge gas in a fixed-bed reactor for catalytic decomposition of the laughing gas. In some embodiments the diluting gas is dried, and at least a part of the exhaust from the catalytic decomposition of the laughing gas is mixed with the laughing-gas-bearing charge gas upstream of the catalytic decomposition of the laughing gas.