Positive Active Material for Secondary Lithium Battery, Method for Preparing the Same and Secondary Lithium Battery Containing the Positive Active Material
    6.
    发明申请
    Positive Active Material for Secondary Lithium Battery, Method for Preparing the Same and Secondary Lithium Battery Containing the Positive Active Material 审中-公开
    二次锂电池的正极活性物质,制备包含正极活性物质的相同和次级锂电池的方法

    公开(公告)号:US20160240842A1

    公开(公告)日:2016-08-18

    申请号:US14831871

    申请日:2015-08-20

    Abstract: The present invention provides a positive active material for use in a secondary lithium battery, a method for preparing the positive active material and a secondary lithium battery containing the positive active material. The positive active material includes a core of lithium transition metal oxide represented by Formula LixMyN1-yO2-αAβ and a coating layer of lithium transition metal silicate represented by Formula x′Li2O.y′N′Oa.SiO2-λBζwhich in-situ formed on the core, wherein 0.8≦x≦1.3, 0.6≦y≦1.0, 0.01≦x′≦2.1, 0.2≦y′≦1.5, 0.1≦a≦3.0, 0≦α≦0.2, 0≦β≦0.4, 0≦λ≦0.5, 0≦ζ≦0.5. The positive active material according to the present invention has high capacity, desirable cycling performance and safety performance, as well as desirable thermal stability.

    Abstract translation: 本发明提供了用于二次锂电池的正极活性物质,制备正极活性物质的方法和含有正极活性物质的二次锂电池。 正极活性物质包括由式LixMyN1-yO2-αAβ表示的锂过渡金属氧化物的核心和由式x'Li2O.y'N'O'SiO_2-λBζ表示的锂过渡金属硅酸盐的涂层,其原位形成在 芯,其中0.8≤x≤1.3,0.6≤y≤1.0,0.01≤x≤1.1,0.2≤y≤1.5,0.1≤a≤3.0,0≤a≤0.2,0≤β≤0.4,0≤ λ≤0.5,0≤ζ≤0.5。 根据本发明的正极活性材料具有高容量,期望的循环性能和安全性能以及期望的热稳定性。

    LITHIUM TRANSITION METAL COMPOSITE OXIDE, ELECTROCHEMICAL DEVICE, AND ELECTRONIC DEVICE

    公开(公告)号:US20240136518A1

    公开(公告)日:2024-04-25

    申请号:US18400630

    申请日:2023-12-29

    Inventor: Kai WANG

    Abstract: A lithium transition metal composite oxide, comprising a twin crystal structure. The twin crystal structure includes a first crystalline region and a second crystalline region. A grain boundary exists between the first crystalline region and the second crystalline region. The first crystalline region includes a first region located within 20 nm from the grain boundary. The second crystalline region includes a second region located within 20 nm from the grain boundary. An angle between a transition metal layer in the first region and a transition metal layer in the second region is 65° to 80°. By adjusting the angle between the transition metal layer in the first region and the transition metal layer in the second region to fall within 65° to 80°, it can improve stability of the twin crystal structure, and in turn, improve the cycle performance of the electrochemical device at a high voltage.

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