公开(公告)号：US20180354878A1

公开(公告)日：2018-12-13

申请号：US15778562

申请日：2016-11-01

申请人： EVONIK DEGUSSA GMBH

发明人： Holger Wiederhold ,  David BOLZ ,  Bernd JAEGER ,  Hnas-Jürgen KÖHLE ,  Sebastian IMM ,  Georg Friedrich THIELE

IPC分类号： C07C29/48 ,  C07C29/76

CPC分类号： C07C29/48 ,  C07C29/106 ,  C07C29/76 ,  C07C31/205

摘要： The process for preparing 1,2-propanediol from propene and hydrogen peroxide comprises the steps of a) reacting propene with hydrogen peroxide in the presence of a catalyst mixture comprising a phase transfer catalyst and a heteropolytungstate, wherein the reaction is carried out in a liquid mixture comprising an aqueous phase having a pH of at most 6 and an organic phase, b) separating the biphasic mixture from step a) into an aqueous phase and an organic phase comprising propene oxide, c) recycling the propene oxide present in the separated organic phase into the reaction of step a) and d) separating 1,2-propanediol from the aqueous phase separated in step b).

公开(公告)号：US09233900B2

公开(公告)日：2016-01-12

申请号：US14399567

申请日：2013-05-10

申请人： Sumitomo Chemical Company Limited

发明人： Shigeru Goto ,  Kenji Itoh ,  Koji Shinohara ,  Masayuki Yoshii ,  Shinjiro Ishihara

IPC分类号： C07C41/02 ,  C07C29/80 ,  C07C41/42 ,  C07C41/03 ,  C07C29/10

CPC分类号： C07C41/02 ,  C07C29/106 ,  C07C29/80 ,  C07C41/03 ,  C07C41/42 ,  C07C31/205 ,  C07C43/11

摘要： There is provided a method for producing dipropylene glycol (DPG) and/or tripropylene glycol (TPG) including: (A) reacting a raw material liquid including propylene oxide and water to obtain a reaction liquid including unreacted water, propylene glycol (PG), DPG and/or TPG, and an alcohol compound excluding PG, DPG, and TPG; (B) separating, from the reaction liquid, a first liquid containing water and the alcohol compound and a second liquid containing the PG, DPG and/or TPG and optionally the alcohol compound; (C) removing a part of the alcohol compound from the first liquid to obtain a third liquid containing water and optionally a part of the alcohol compound; (D) separating, from the second liquid, a fourth liquid containing the PG and optionally the alcohol compound, and a fifth liquid containing the DPG and/or TPG and optionally the alcohol compound; and (E) recycling a part of the third liquid to step (A).

摘要翻译： 提供了制备二丙二醇（DPG）和/或三丙二醇（TPG）的方法，包括：（A）使包含环氧丙烷和水的原料液体反应，得到包含未反应水，丙二醇（PG）， DPG和/或TPG，以及不包括PG，DPG和TPG的醇化合物; （B）从反应液中分离含有水和醇化合物的第一液体和含有PG，DPG和/或TPG以及任选的醇化合物的第二液体; （C）从第一液体中除去一部分醇化合物，得到含有水和任意一部分醇化合物的第三液体; （D）从第二液体中分离含有PG和任选的醇化合物的第四液体和含有DPG和/或TPG和任选的醇化合物的第五液体; 和（E）将第三液体的一部分再循环到步骤（A）。

公开(公告)号：US20150284350A1

公开(公告)日：2015-10-08

申请号：US14679250

申请日：2015-04-06

申请人： SHELL OIL COMPANY

发明人： Naga Roobini ARULESWARAN ,  Paul Theodore SHARKO ,  James Grace CRUMP

IPC分类号： C07D307/20 ,  C07D301/12 ,  C07C303/02 ,  C07C303/20 ,  C07C45/58 ,  C07C41/03 ,  C07C213/04 ,  C07C2/86 ,  C07C29/00

CPC分类号： C07D307/20 ,  C07C29/106 ,  C07C29/132 ,  C07C29/38 ,  C07C37/14 ,  C07C51/14 ,  C07C213/04 ,  C07C231/08 ,  C07C303/02 ,  C07C303/06 ,  C07D301/12 ,  C07C309/08 ,  C07C215/40 ,  C07C215/08 ,  C07C215/10 ,  C07C309/20 ,  C07C233/38 ,  C07C31/20 ,  C07C31/125 ,  C07C53/128 ,  C07C39/06

摘要： The present invention provides a process for producing vinylidene dimer derivatives, which process includes subjecting one or more vinylidene dimers to an epoxidation reaction to obtain a vinylidene-derived epoxide.In another aspect the invention provides further process for producing vinylidene dimer derivatives.

摘要翻译： 本发明提供一种亚乙烯基二聚体衍生物的制备方法，该方法包括使一种或多种亚乙烯基二聚体进行环氧化反应，得到亚乙烯基衍生的环氧化物。 在另一方面，本发明提供了制备亚乙烯基二聚体衍生物的进一步方法。

公开(公告)号：US09096564B2

公开(公告)日：2015-08-04

申请号：US13362835

申请日：2012-01-31

申请人： Jan Van Ogtrop ,  Hendrik Stichter ,  Jacqueline Hessing

发明人： Jan Van Ogtrop ,  Abraham Adriaan Smaardijk ,  Hendrik Stichter

IPC分类号： C07C29/09 ,  C07D301/22 ,  C07C29/12 ,  C07D301/04 ,  C07C29/10

CPC分类号： C07D301/22 ,  C07C29/106 ,  C07C29/12 ,  C07D301/04 ,  Y02P20/52 ,  C07C31/202

摘要： A process for the production of ethylene glycol comprising: (i) supplying ethylene and oxygen and an organic chloride moderator to an EO reactor, thereby producing a reactor product stream; (ii) supplying the reactor product stream to an EO absorber, thereby producing a fat absorbent stream; (iii) supplying the fat absorbent stream to an EO stripper, thereby producing a concentrated ethylene oxide stream and a lean absorbent stream; (iv) recirculating the lean absorbent stream to the EO absorber; and (v) supplying the ethylene oxide stream and/or the ethylene carbonate stream to hydrolysis reactors with an alkali metal salt hydrolysis catalyst to form an ethylene glycol stream; wherein the process additionally comprises: (vi) removing a glycol bleed stream from the ethylene oxide stripper; and (vii) adding a base to the ethylene oxide stripper such that the pH in the bottom section of the stripper is maintained from 9.5 to 12.0.

摘要翻译： 一种生产乙二醇的方法，包括：（i）向EO反应器供应乙烯和氧气和有机氯化物慢化剂，从而产生反应器产物流; （ii）将反应器产物流供应到EO吸收剂，从而产生吸收脂肪的物流; （iii）将脂肪吸收剂流供应到EO汽提器，从而产生浓缩的环氧乙烷流和贫吸收物流; （iv）将贫吸收物流再循环到EO吸收器; 和（v）用碱金属盐水解催化剂将环氧乙烷物流和/或碳酸亚乙酯物流供应至水解反应器以形成乙二醇物流; 其中所述方法还包括：（vi）从所述环氧乙烷剥离剂中除去二醇流出物; 和（vii）向环氧乙烷汽提器中加入碱，使得汽提塔底部的pH保持在9.5至12.0。

公开(公告)号：US09067902B2

公开(公告)日：2015-06-30

申请号：US14152519

申请日：2014-01-10

申请人： Scientific Design Company, Inc.

发明人： Ashok S. Padia ,  Hassan Eisa Al-Ahmadi

IPC分类号： C07D301/03 ,  C07C43/00 ,  C07C29/00 ,  C07D301/10 ,  C07D301/08 ,  C07C29/10

CPC分类号： C07D301/10 ,  C07C29/106 ,  C07D301/08 ,  C07C31/202

摘要： A method for the epoxidation of an olefin comprising the steps of reacting a feed gas composition containing an olefin, oxygen, and a moderator having a post-conditioning step where the catalyst is exposed to reactor feed having a chlorides concentration of from about 5 ppm to about 7 ppm and at a temperature of about 215° C. to about 225° C.

摘要翻译： 一种用于烯烃环氧化的方法，包括以下步骤：使含有烯烃，氧和具有后处理步骤的缓和剂的进料气体组合物反应，其中催化剂暴露于反应器进料中，氯化物浓度为约5ppm至 约7ppm和约215℃至约225℃的温度

公开(公告)号：US08999887B2

公开(公告)日：2015-04-07

申请号：US14524226

申请日：2014-10-27

申请人： Saint-Gobain Ceramics & Plastics, Inc.

发明人： Michael A. Richard ,  John David Covey

IPC分类号： B01J23/02 ,  B01J23/10 ,  B01J23/48 ,  B01J23/50 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J35/10 ,  C07D301/04 ,  C07C29/10 ,  C07C41/03 ,  C07C213/04

CPC分类号： B01J35/04 ,  B01J23/50 ,  B01J23/688 ,  B01J35/00 ,  B01J35/0066 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/024 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/04 ,  C07D301/08 ,  C07C215/08

摘要： A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

摘要翻译： 公开了一种载体，其具有至少三个叶片，第一端部，第二端部，端部之间的壁和在端部和壁部的交叉点处的不均匀的过渡半径。 还公开了包含载体，银和沉积在载体上并可用于烯烃的环氧化的助催化剂的催化剂。 还公开了制备载体的方法，制备催化剂的方法以及与催化剂烯烃的环氧化方法。

公开(公告)号：US08871677B2

公开(公告)日：2014-10-28

申请号：US13316783

申请日：2011-12-12

申请人： Michael A. Richard ,  John David Covey

发明人： Michael A. Richard ,  John David Covey

IPC分类号： B01J23/02 ,  B01J23/10 ,  B01J23/48 ,  B01J23/50 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J35/10 ,  C07D301/08 ,  C07C213/04 ,  B01J37/02 ,  B01J23/68

CPC分类号： B01J35/04 ,  B01J23/50 ,  B01J23/688 ,  B01J35/00 ,  B01J35/0066 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/024 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/04 ,  C07D301/08 ,  C07C215/08

摘要： A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

摘要翻译： 公开了一种载体，其具有至少三个叶片，第一端部，第二端部，端部之间的壁和在端部和壁部的交叉点处的不均匀的过渡半径。 还公开了包含载体，银和沉积在载体上并可用于烯烃的环氧化的助催化剂的催化剂。 还公开了制备载体的方法，制备催化剂的方法以及与催化剂烯烃的环氧化方法。

公开(公告)号：US20140107356A1

公开(公告)日：2014-04-17

申请号：US14114717

申请日：2012-05-25

申请人： Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

发明人： Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

IPC分类号： B01J31/22 ,  C07C213/02 ,  C07C41/02 ,  C07C68/00 ,  C07D301/04 ,  C07C29/10

CPC分类号： C07D301/04 ,  B01J23/002 ,  B01J23/688 ,  B01J27/055 ,  B01J31/2213 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/024 ,  B01J2523/00 ,  C07C29/106 ,  C07C41/02 ,  C07C68/00 ,  C07C213/02 ,  C07D301/10 ,  Y02P20/52 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/15 ,  B01J2523/18 ,  B01J2523/72 ,  B01J2523/74

摘要： A method for producing epoxidation catalysts is provided. The catalyst comprises a support, a catalytic species, maganese and at least one alkali metal and/or promoter. The catalytic species may be silver. The catalyst is prepared by a method wherein at least a portion of the manganese is impregnated in a step separate from the at least one alkali metal and/or promoter. Advantageously, catalysts produced by the present method may exhibit greater efficiencies than catalysts produced by conventional methods. A method for the epoxidation of alkylenes using the catalysts so produced is provided as is a method for using the alkylene oxides for the production of 1,2-diols, 1,2-carbonates, 1,2-diol ethers, or alka-nolamines.

摘要翻译： 提供了制备环氧化催化剂的方法。 催化剂包括载体，催化物质，锰和至少一种碱金属和/或助催化剂。 催化物质可以是银。 催化剂通过一种方法制备，其中至少一部分锰以与至少一种碱金属和/或助催化剂分离的步骤浸渍。 有利地，通过本方法生产的催化剂可以表现出比通过常规方法生产的催化剂更高的效率。 提供使用如此制备的催化剂来环氧化亚烷基的方法，就是使用环氧烷生产1,2-二醇，1,2-碳酸酯，1,2-二醇醚或烷醇胺的方法 。

公开(公告)号：US08536083B2

公开(公告)日：2013-09-17

申请号：US12502850

申请日：2009-07-14

申请人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

发明人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

IPC分类号： B01J23/00 ,  B01J23/10

CPC分类号： B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/50 ,  B01J23/688 ,  B01J27/138 ,  B01J35/002 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

摘要： A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

公开(公告)号：US20130030223A1

公开(公告)日：2013-01-31

申请号：US13631828

申请日：2012-09-28

申请人： H R D Corporation

发明人： Abbas HASSAN ,  Aziz Hassan ,  Rayford G. Anthony ,  Krishnan Viswanathan ,  Gregory G. Borsinger

IPC分类号： C07C29/10

CPC分类号： B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  B01J8/025 ,  B01J8/20 ,  B01J19/0066 ,  B01J19/1806 ,  B01J2219/00006 ,  B01J2219/00779 ,  C07C29/106 ,  C08G65/2696 ,  C07C31/202 ,  C07C31/205 ,  C07C31/207

摘要： Herein disclosed is a method of hydrating an alkylene oxide that includes introducing an alkylene oxide into water to form a first stream; flowing the first stream through a high shear device to produce a second stream; and contacting the second stream with a catalyst in a reactor to hydrate the alkylene oxide and form an alkylene glycol.

摘要翻译： 本文公开了一种水合烯化氧的方法，其包括将烯化氧引入水中以形成第一料流; 使第一流流过高剪切装置以产生第二流; 以及使第二料流与反应器中的催化剂接触以使烯化氧水合并形成亚烷基二醇。