公开(公告)号：US12017970B2

公开(公告)日：2024-06-25

申请号：US18459534

申请日：2023-09-01

申请人： Chevron Phillips Chemical Company LP

发明人： Masud M. Monwar ,  Jared Barr ,  Carlos A. Cruz ,  Kathy S. Clear ,  Max P. McDaniel ,  William C. Ellis

IPC分类号： C07B33/00 ,  B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/39 ,  B01J35/61 ,  B01J35/63 ,  B01J37/08 ,  B01J37/16 ,  B01J37/34 ,  B01J38/02 ,  C07C29/48 ,  C07C29/50 ,  C07C45/27 ,  C07C45/28 ,  C07C51/16 ,  C07C51/225

CPC分类号： C07B33/00 ,  B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/39 ,  B01J35/613 ,  B01J35/615 ,  B01J35/617 ,  B01J35/618 ,  B01J35/633 ,  B01J35/635 ,  B01J35/638 ,  B01J37/082 ,  B01J37/16 ,  B01J37/34 ,  B01J37/345 ,  B01J38/02 ,  C07C29/48 ,  C07C29/50 ,  C07C45/27 ,  C07C45/28 ,  C07C51/16 ,  C07C51/225 ,  C07C29/50 ,  C07C31/20 ,  C07C29/50 ,  C07C33/025 ,  C07C45/28 ,  C07C47/02 ,  C07C45/28 ,  C07C49/04 ,  C07C29/50 ,  C07C31/08 ,  C07C29/50 ,  C07C31/10 ,  C07C51/225 ,  C07C53/02 ,  C07C51/225 ,  C07C53/08 ,  C07C51/225 ,  C07C53/124 ,  C07C29/50 ,  C07C31/04 ,  C07C29/50 ,  C07C31/125

摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.

公开(公告)号：US11999679B2

公开(公告)日：2024-06-04

申请号：US18454844

申请日：2023-08-24

申请人： Chevron Phillips Chemical Company LP

发明人： Carlos A. Cruz ,  Masud M. Monwar ,  Max P. McDaniel ,  Jared Barr ,  Kathy S. Clear ,  William C. Ellis

IPC分类号： C07C29/72 ,  B01J21/06 ,  B01J21/08 ,  B01J23/26 ,  B01J37/08 ,  B01J37/34 ,  B01J38/02 ,  C07C29/09 ,  C07C29/48 ,  C07C29/50 ,  C07C31/20 ,  C07C37/08 ,  C07C37/58 ,  C07C45/33 ,  C07C51/215 ,  B01J35/40 ,  B01J35/61 ,  B01J35/63 ,  C07C29/17 ,  C07C31/04 ,  C07C45/29

CPC分类号： C07C29/72 ,  B01J21/063 ,  B01J21/08 ,  B01J23/26 ,  B01J37/08 ,  B01J37/34 ,  B01J37/345 ,  B01J38/02 ,  C07C29/09 ,  C07C29/48 ,  C07C29/50 ,  C07C31/20 ,  C07C37/58 ,  C07C45/33 ,  C07C51/215 ,  B01J35/40 ,  B01J35/615 ,  B01J35/617 ,  B01J35/635 ,  C07C29/17 ,  C07C31/04 ,  C07C45/292 ,  C07C29/48 ,  C07C31/202 ,  C07C29/48 ,  C07C31/20 ,  C07C45/292 ,  C07C49/04 ,  C07C45/292 ,  C07C47/02

摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.

公开(公告)号：US11952329B2

公开(公告)日：2024-04-09

申请号：US18556453

申请日：2022-06-02

申请人： KH Neochem Co., Ltd.

发明人： Hirotaka Tanaka ,  Takashi Hakumura ,  Jun Kanada

IPC分类号： C07C31/20 ,  C07C29/74 ,  B01D15/08 ,  G01N30/02

CPC分类号： C07C31/207 ,  C07C29/74 ,  C07C31/20 ,  B01D15/08 ,  G01N30/02 ,  G01N2030/027

摘要： A product 1,3-butylene glycol, wherein, in an HPLC analysis under specific conditions after specific sample preparation, when a relative retention time of 2,4-dinitrophenylhydrazine is regarded as 1.0, a sum area value of absorbance peaks that appear within a relative retention time range of 4.4 to 12.0 is 1000 or less, and wherein



a dinitrophenylhydrazine derivative of a carbonyl compound having 4 to 6 carbon atoms is contained as a component that corresponds to the peaks that appear within the relative retention time range of 4.4 to 12.0.

公开(公告)号：US11767279B2

公开(公告)日：2023-09-26

申请号：US17864492

申请日：2022-07-14

申请人： Chevron Phillips Chemical Company LP

发明人： Max P. McDaniel ,  Carlos A. Cruz ,  Masud M. Monwar ,  Jared L. Barr ,  William C. Ellis

IPC分类号： C07C29/72 ,  C07C45/33 ,  B01J23/26 ,  B01J21/06 ,  B01J21/08 ,  B01J38/02 ,  C07C29/50 ,  C07C37/58 ,  C07C51/215 ,  C07C31/20 ,  B01J37/08 ,  C07C29/48 ,  C07C29/09 ,  B01J37/34 ,  C07C31/04 ,  B01J35/02 ,  B01J35/10 ,  C07C29/17 ,  C07C45/29

CPC分类号： C07C29/72 ,  B01J21/063 ,  B01J21/08 ,  B01J23/26 ,  B01J37/08 ,  B01J37/34 ,  B01J37/345 ,  B01J38/02 ,  C07C29/09 ,  C07C29/48 ,  C07C29/50 ,  C07C31/20 ,  C07C37/58 ,  C07C45/33 ,  C07C51/215 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  C07C29/17 ,  C07C31/04 ,  C07C45/292 ,  C07C29/48 ,  C07C31/202 ,  C07C29/48 ,  C07C31/20 ,  C07C45/292 ,  C07C49/04 ,  C07C45/292 ,  C07C47/02

摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.

公开(公告)号：US11708316B2

公开(公告)日：2023-07-25

申请号：US17623642

申请日：2020-06-24

申请人： BASF SE

发明人： Mathias Schelwies ,  Jonas Schwaben ,  Rocco Paciello

IPC分类号： C07C41/26 ,  C07C29/149 ,  C07C29/156

CPC分类号： C07C41/26 ,  C07C29/149 ,  C07C29/156 ,  C07C2602/28 ,  C07C29/149 ,  C07C33/26 ,  C07C29/149 ,  C07C31/278 ,  C07C29/149 ,  C07C33/02 ,  C07C29/149 ,  C07C33/22 ,  C07C29/149 ,  C07C31/08 ,  C07C29/149 ,  C07C31/125 ,  C07C29/149 ,  C07C33/20 ,  C07C41/26 ,  C07C43/23 ,  C07C29/149 ,  C07C31/20

摘要： Method for hydrogenating an ester with molecular hydrogen to the corresponding alcohols in the presence of a ruthenium complex (I), wherein said complex comprises a tridentate ligand L of the general formula (II)




n and m are each independently 0 or 1, and the solid-dashed double lines represent a single or double bond, with the proviso that in the case of n=1 both solid-dashed double lines represent a single bond and m is 1, and in the case of n=0 one solid-dashed double line represents a single bond and the other solid-dashed double line represents a double bond, wherein in the case of a double bond on the side facing the phenyl ring m=1, in the case of a double bond on the side facing the pyridyl ring m=0, or both solid-dashed double lines represent a single bond and m is 1.

公开(公告)号：US20190134618A1

公开(公告)日：2019-05-09

申请号：US16201519

申请日：2018-11-27

申请人： HEINISCH-WESTFÄLISCHE TECHNISCHE HOCHSCHULE (RWTH) AACHEN

发明人： Jürgen KLANKERMAYER ,  Walter Leitner ,  Markus Meuresch

IPC分类号： B01J31/24 ,  C07D307/33 ,  C07C67/303 ,  C07C29/17 ,  C07D307/06

CPC分类号： B01J31/2409 ,  B01J2231/645 ,  B01J2531/821 ,  C07C29/177 ,  C07C67/303 ,  C07D307/06 ,  C07D307/33 ,  C07C69/34 ,  C07C31/20

摘要： A method for the reduction organic molecules comprising a Ruthenium-Triphosphine complex with aromatic ligands at the phosphors which are ortho or meta substituted.

公开(公告)号：US20180223213A1

公开(公告)日：2018-08-09

申请号：US15562339

申请日：2016-03-31

申请人： FUNDACIÓN CIDETEC

发明人： Ignacio GARCÍA ALONSO ,  Sarah MONTES PÉREZ ,  Ibon ODRIOZOLA ,  Germán CABAÑERO ,  Hans-Jürgen GRANDE ,  Ramón TENA ZAERA

IPC分类号： C10M125/22 ,  C07C43/13 ,  C07C41/18 ,  C07C31/20 ,  C07C29/00 ,  C07C215/14 ,  C07C213/08 ,  C08G65/326 ,  C07C215/08 ,  C07C321/04 ,  C07C319/12 ,  C08K7/14 ,  C08K9/04 ,  C08K9/08 ,  C08K3/30 ,  C10M159/18 ,  C01G39/06

CPC分类号： C10M125/22 ,  C01B19/007 ,  C01G39/06 ,  C01G41/00 ,  C01P2002/82 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/10 ,  C01P2004/13 ,  C01P2004/16 ,  C01P2004/24 ,  C01P2004/32 ,  C01P2004/62 ,  C01P2004/64 ,  C07C29/00 ,  C07C31/20 ,  C07C31/205 ,  C07C41/18 ,  C07C43/132 ,  C07C213/08 ,  C07C215/08 ,  C07C215/14 ,  C07C319/12 ,  C07C321/04 ,  C08G65/326 ,  C08K3/30 ,  C08K7/14 ,  C08K9/04 ,  C08K9/08 ,  C08K2003/3009 ,  C08K2201/011 ,  C10M159/18 ,  C10M2201/065 ,  C10M2201/066 ,  C10M2227/066 ,  C10M2227/09 ,  C10N2210/06 ,  C10N2220/082 ,  C10N2230/06

摘要： The present invention provides a Molybdenum or Tungsten chalcogenide nanoobject having: (a) an object size comprised from 0.1 to 500 nm, and (b) from 1 to 99% by weight of molecules of formula (I) with respect to the total weight of the nanoobject, wherein: A is —OH; X is selected from: (C1-C20)alkyl optionally substituted with one or more radicals; a 2 to 20-member heteroalkyl optionally substituted with one or more radicals; and a homopolymer or copolymer comprising a polymeric chain; B is selected from: H, —OH, —NH2, (C1-C4)alkyl, halogen, phenyl substituted with one or more halogen radicals, benzyl substituted with one or more halogen radicals, —C(═O)R3, —C(═O)(R7), —OC(═O)(O)R3, —C(═O)(O−), —C(═O)(O)R3, —OR3, —CH(OR3)(OR4), —C(OR3)(OR4)(R5), —C(OR3)(OR4)(OR5), —C(OR3)(OR4)(OR5)(OR6), —NR1R2, —N+R1R2R3, —C(═NR1)(R2), —C(═O)(NR1R2), —N(C(═O)(R1)) (C(═O)(R2))(R3), —O(CN), —NC(═O), —ONO2, —CN, —NC, —ON(═O), —NO2, —NO, —C5H4N, —SR1, —SSR1, —S(═O)(R1), — S(═O)(═O)(R1), —S(═O)(OH), —S(═O)(═O)(OH), —SCN, —NCS, —C(═S)(R1), —PR1R2, —P(═O)(OH)2, —OP(═O)(OH)2, —OP(═O)(OR1)(OR2), —B(OH), —B(OR1)(OR2), and —B(OR1)(R2); provided that when B is —H or (C1-C4) alkyl, then X is a homopolymer, a copolymer, or a 2 to 20-member heteroalkyl optionally substituted with one or more radicals as defined above.The present invention also provides processes for the preparation of the nanoobjects, their use as additive for reducing the friction coefficient of a material, and compositions comprising thereof. A-X-B  (I)

公开(公告)号：US09944581B2

公开(公告)日：2018-04-17

申请号：US15490187

申请日：2017-04-18

申请人： Virent, Inc.

发明人： Andrew Held ,  Elizabeth Woods ,  Randy Cortright ,  Matthew Gray

IPC分类号： C07C45/60 ,  C07C29/60 ,  C07C1/24 ,  C12P19/02 ,  C12P19/14 ,  C10L1/02 ,  C10G3/00

CPC分类号： C07C45/60 ,  C07C1/24 ,  C07C27/04 ,  C07C29/132 ,  C07C29/60 ,  C07C41/09 ,  C07C45/59 ,  C07C51/377 ,  C10G3/42 ,  C10G3/47 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/22 ,  C10G2400/30 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  C10L2200/0469 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C12P19/02 ,  C12P19/14 ,  Y02P30/20 ,  C07C31/12 ,  C07C31/125 ,  C07C31/20

摘要： The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C4+ compounds useful as fuels and chemicals.

公开(公告)号：US09926252B2

公开(公告)日：2018-03-27

申请号：US15304790

申请日：2015-05-12

申请人： VIRDIA, INC.

发明人： Robert Jansen ,  Noa Lapidot ,  James Alan Lawson ,  Michael Zviely ,  Neta Matis ,  Lee Madsen ,  Bassem Hallac ,  Philip Travisano

IPC分类号： C07C45/00 ,  C01B3/00 ,  C07C5/03 ,  C01B3/22 ,  C07C29/17

CPC分类号： C07C45/002 ,  C01B3/22 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1211 ,  C01B2203/1217 ,  C07C5/03 ,  C07C29/172 ,  C07C29/175 ,  C07C2523/44 ,  C07C2523/72 ,  C07C2523/86 ,  C07D307/08 ,  C07C49/10 ,  C07C9/15 ,  C07C31/20

摘要： The present disclosure relates to methods, processes, and systems for utilizing the dehydrogenation of 2-butanol for hydrogen consuming reactions of biomass or biomass-derived molecules. The present invention relates to methods, processes, and systems for utilizing the dehydrogenation of 2-butanol for hydrogen consuming hydrogenation, hydrogenolysis, or hydrodeoxygenation reactions of biomass or biomass-derived molecules.

公开(公告)号：US20170298036A1

公开(公告)日：2017-10-19

申请号：US15417110

申请日：2017-01-26

申请人： Rennovia Inc.

发明人： Valery SOKOLOVSKII ,  Mayya LAVRENKO ,  Alfred HAGEMEYER ,  Eric L. DIAS ,  James A. W. SHOEMAKER ,  Vincent J. MURPHY

IPC分类号： C07D307/28 ,  C07D307/12 ,  C07C29/60 ,  C07C29/132 ,  B01J8/04 ,  C07C29/10 ,  C07C29/09 ,  C07D307/42 ,  C07C29/17

CPC分类号： C07D307/28 ,  B01J8/04 ,  B01J2208/027 ,  C07C29/09 ,  C07C29/103 ,  C07C29/132 ,  C07C29/172 ,  C07C29/60 ,  C07D307/12 ,  C07D307/42 ,  C07C31/22 ,  C07C31/20

摘要： Industrial scale conversions of 5-hydroxymethylfurfural to commodity chemicals such as 1,2,6-hexanetriol and 1,6-hexanediol by chemocatalytic conversions using hydrogen and a heterogeneous reduction catalyst are provided. The reactions are suitable for use in continuous flow reactors. Methods of carrying out the conversions are provided, as are product and catalyst compositions.