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    INTEGRATED CARBOXYLIC ACID PRODUCTION FROM SYNTHESIS GAS
    1.
    发明公开
    INTEGRATED CARBOXYLIC ACID PRODUCTION FROM SYNTHESIS GAS 审中-公开

    公开(公告)号：US20240010596A1

    公开(公告)日：2024-01-11

    申请号：US18253605

    申请日：2021-11-17

    申请人： Rohm and Haas Company

    发明人： Joseph F. Dewilde ,  Kirk W. Limbach ,  Reetam Chakrabarti

    IPC分类号： C07C51/225 ,  C07C51/64

    CPC分类号： C07C51/225 ,  C07C51/64 ,  C07C2521/06 ,  C07C2523/08 ,  C07C2529/85

    摘要： A process for preparing C2 to C4 carboxylic acids from synthesis gas includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas comprising carbon monoxide into a reaction zone of a first reactor, converting the feed stream into an intermediate stream comprising C2 to C4 hydrocarbons in the reaction zone in the presence of a first catalyst, wherein the intermediate stream further comprises carbon dioxide and wherein the first catalyst is a composite catalyst comprising a metal oxide catalyst component and a microporous catalyst component, and converting the intermediate stream into a product stream comprising C2 to C4 carboxylic acids in the presence of a second catalyst in a second reactor. The second reactor can be configured for olefin oxidation or paraffin oxidation.

    PRODUCTION OF PRODUCTS FROM NATURAL RESOURCES
    5.
    发明申请
    PRODUCTION OF PRODUCTS FROM NATURAL RESOURCES 审中-公开
    从自然资源生产产品

    公开(公告)号：US20160096796A1

    公开(公告)日：2016-04-07

    申请号：US14786010

    申请日：2014-04-22

    申请人： SAUDI BASIC INDUSTRIES CORPORATION

    发明人： Khalid Karim ,  Labeeb Chaudhary Ahmed

    IPC分类号： C07C51/225 ,  B01J27/057 ,  B01J27/187 ,  B01J23/889 ,  C07C51/215 ,  C07C1/04

    CPC分类号： C07C51/225 ,  B01J23/8892 ,  B01J27/0515 ,  B01J27/0576 ,  B01J27/187 ,  B01J37/035 ,  C07C1/0435 ,  C07C1/0485 ,  C07C51/215 ,  C07C51/252 ,  C07C2523/889 ,  C07C2527/187 ,  C07C57/04 ,  C07C53/08

    摘要： The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C2-C3 olefins and/or C2-C3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.

    摘要翻译： 本文公开的方法涉及将合成气转化为乙酸，丙烯酸和/或丙烯的两阶段催化方法。 更具体地，本文所述和要求保护的方法涉及产生丙烯酸和乙酸的方法，包括以下步骤：a）提供包含合成气的原料流; b）使进料流与第一催化剂接触以产生包含C 2 -C 3烯烃和/或C 2 -C 3链烷烃的第一产物流; 和c）使第一产物流与氧气和第二催化剂接触，从而产生包含丙烯酸和乙酸的第二产物流，其中在第一产物流接触之前不存在分离第一产物流的组分的步骤 与第二催化剂。

    Preparation of aliphatic carboxylic acids in the presence of heteropolyacid catalysts
    6.
    发明授权
    Preparation of aliphatic carboxylic acids in the presence of heteropolyacid catalysts 失效
    在杂多酸催化剂存在下制备脂肪族羧酸

    公开(公告)号：US6114274A

    公开(公告)日：2000-09-05

    申请号：US443450

    申请日：1995-05-18

    申请人： Elisabeth Bordes ,  Michel Gubelmann ,  Laurent Tessier

    发明人： Elisabeth Bordes ,  Michel Gubelmann ,  Laurent Tessier

    IPC分类号： B01J27/18 ,  B01J27/199 ,  C07C51/215 ,  C07C51/225 ,  B01J27/198 ,  C07C51/31

    CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J27/199 ,  B01J2523/00

    摘要： The aliphatic carboxylic acids, e.g., acetic acid, are selectively prepared, even on an industrial scale, by controlledly oxidizing the corresponding alkanes, e.g., ethane, with a source of oxygen, in the presence of a catalytically effective amount of an advantageously supported heteropolyacid catalyst having the formula (I):[A.sub.a B.sub.b ].sub.f [C.sub.c D.sub.d E.sub.e O.sub.x ].sup.f-(I)in which A is at least one monovalent cation selected from among hydrogen, an alkali metal, or the ammonium ion; B is VO.sup.2 +, VO.sup.3 +, an alkaline earth metal ion, or an ion of a metal of Groups VII A, VIII, I B, IV B and V B of the Periodic Table; C is Mo and/or W; D is phosphorus, arsenic, antimony, silicon, germanium and/or boron; E is vanadium, optionally in combination with at least one metal of Groups V A, VII A and VIII of the Periodic Table or chromium; f=a+.alpha.b wherein .alpha. depends on the charge of the ion B, which is equal to 2, 3 or 4; c is a number ranging from 5 to 20-e; d is a number ranging from 1 to 5; and e is a number ranging from 1 to 9.

    摘要翻译： 通过在催化有效量的有利负载的杂多酸的存在下，通过有选择地制备脂肪族羧酸，例如乙酸，即使在工业规模上，通过可控地氧化相应的烷烃，例如乙烷与氧源 具有式（I）的催化剂：[AaBb] f [CcDdEex] f-（I）其中A是选自氢，碱金属或铵离子中的至少一种一价阳离子; B是VO2 +，VO3 +，碱土金属离子或元素周期表第VIIA，VIII，IB，IVB和VB族金属的离子; C是Mo和/或W; D是磷，砷，锑，硅，锗和/或硼; E是钒，任选地与元素周期表第ⅤA，ⅦA和Ⅷ族的至少一种金属或铬组合; f = a +αb其中α取决于离子B的电荷，其等于2,3或4; c为5〜20-e的数字; d为1〜5的数字; e是从1到9的数字。