公开(公告)号：US20240262776A1

公开(公告)日：2024-08-08

申请号：US18277896

申请日：2022-02-23

申请人： S.H. KELKAR AND COMPANY LIMITED

发明人： Avdhoot D. Velankar ,  Kedar Ramesh Vaze ,  Popat D. Shinde

IPC分类号： C07C47/02 ,  C07C29/147 ,  C07C33/025 ,  C07C45/29 ,  C07C47/21 ,  C07C49/04 ,  C11B9/00

CPC分类号： C07C47/02 ,  C07C29/147 ,  C07C33/025 ,  C07C45/29 ,  C07C47/21 ,  C07C49/04 ,  C11B9/0015

摘要： The present invention relates to compounds of formula (I), wherein A represents —CH2OH or —CHO, —CH2OAc R1 is an alkyl or alkylidene group, R2 is an alkyl or alkylidene group, dotted line represents double bond or single bond. The present invention also relates to a method of preparation of the compounds and a composition comprising the compounds which is used in perfumed, flavored, deodorizing, masking composition.

公开(公告)号：US11753358B2

公开(公告)日：2023-09-12

申请号：US17867782

申请日：2022-07-19

申请人： Chevron Phillips Chemical Company LP

发明人： Carlos A. Cruz ,  Masud M. Monwar ,  Max P. McDaniel ,  Jared Barr ,  Kathy S. Clear ,  William C. Ellis

IPC分类号： B01J21/06 ,  B01J21/08 ,  B01J23/26 ,  B01J38/02 ,  B01J37/08 ,  B01J37/34 ,  C07C29/72 ,  C07C29/50 ,  C07C37/58 ,  C07C45/33 ,  C07C31/20 ,  C07C29/48 ,  C07C29/09 ,  C07C51/215 ,  C07C31/04 ,  B01J35/02 ,  B01J35/10 ,  C07C29/17 ,  C07C45/29

CPC分类号： C07C29/72 ,  B01J21/063 ,  B01J21/08 ,  B01J23/26 ,  B01J37/08 ,  B01J37/34 ,  B01J37/345 ,  B01J38/02 ,  C07C29/09 ,  C07C29/48 ,  C07C29/50 ,  C07C31/20 ,  C07C37/58 ,  C07C45/33 ,  C07C51/215 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  C07C29/17 ,  C07C31/04 ,  C07C45/292 ,  C07C29/48 ,  C07C31/202 ,  C07C29/48 ,  C07C31/20 ,  C07C45/292 ,  C07C49/04 ,  C07C45/292 ,  C07C47/02

摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.

公开(公告)号：US20190210940A1

公开(公告)日：2019-07-11

申请号：US16325676

申请日：2017-08-16

申请人： Organofuel Sweden AB

发明人： Armando Córdova ,  Samson Afewerki

IPC分类号： C07B35/02 ,  C07C45/29 ,  C07C45/30 ,  C07C45/62 ,  C07C45/72

CPC分类号： C07B35/02 ,  C07B31/00 ,  C07B33/00 ,  C07B35/04 ,  C07C45/29 ,  C07C45/294 ,  C07C45/30 ,  C07C45/62 ,  C07C45/72 ,  C07D319/06 ,  Y02P20/584 ,  C07C47/02 ,  C07C47/21 ,  C07C47/11

摘要： Embodiments herein concerns the eco-friendly conversion of simple alcohols to linear or branched functionalized alkanes, by integrated catalysis. The alcohols are firstlyoxidized either chemically or enzymatically to the corresponding aldehydes or ketones, followed by aldol condensations using a catalyst to give the corresponding enals or enones. The enals or enones are subsequently and selectively hydrogenated using a recyclable heterogeneous metal catalyst, organocatalyst or an enzyme to provide linear or branched functionalized alkanes with an aldehyde, keto- or alcohol functionality. The process is also iterative and can be further extended by repeating the above integrated catalysis for producing long-chain functionalized alkanes from simple alcohols.

公开(公告)号：US20180208538A1

公开(公告)日：2018-07-26

申请号：US15925401

申请日：2018-03-19

申请人： Evonik Degussa GmbH

发明人： Helene Reeker ,  Guido Stochniol ,  Dietrich Maschmeyer ,  Horst-Werner Zanthoff ,  Jörg Schallenberg ,  Frank Geilen ,  Katrin Marie Dyballa ,  Dirk Fridag ,  Stephan Peitz ,  Lena Altmann ,  Robert Franke

IPC分类号： C07C67/08 ,  C07C45/50 ,  C07C2/24 ,  C07C29/141

CPC分类号： C07C67/08 ,  C07C2/24 ,  C07C29/141 ,  C07C45/50 ,  C07C45/505 ,  C07C2521/12 ,  C07C2523/755 ,  Y02P20/52 ,  C07C47/02 ,  C07C31/125 ,  C07C69/80 ,  C07C11/02

摘要： The invention relates to a process for preparing an ester mixture, in which an n-butene-containing feed mixture having a composition which changes over time is first oligomerized and then converted by hydroformylation, hydrogenation and esterification to an ester mixture. In this process, an approximation of the actual viscosity of the ester mixture is determined. The problem that it addresses is that of specifying a comparatively simple process which enables conversion of an n-butene with a variable composition over time to an ester mixture having a viscosity which can be kept very substantially constant over a long period even when an inconstant C4 source which delivers fluctuating qualities over this period is utilized. This is achieved through controlled use of a second raw material, namely ethene. It has been found that the viscosity of n-butene-based ester mixtures can be influenced by controlled use of ethene in the preparation of the ester precursors. Specifically, the invention proposes two measures by which the ethene can be used: either directly as C2 olefin or as C8 olefin after prior separate oligomerization.

公开(公告)号：US09988274B2

公开(公告)日：2018-06-05

申请号：US13766876

申请日：2013-02-14

申请人： SAMSUNG ELECTRONICS CO., LTD.

发明人： Won Mook Choi ,  Byung Hee Hong ,  Jaeyoung Choi

IPC分类号： B32B9/00 ,  C01B31/04 ,  B82Y30/00 ,  B82Y40/00 ,  C07C31/125 ,  C07C31/20 ,  C07C47/02 ,  C07C49/12 ,  C07C53/128 ,  C07C69/22 ,  C01B32/23 ,  C01B32/186 ,  C01B32/194

CPC分类号： C01B32/194 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/186 ,  C01B32/23 ,  C01B2204/04 ,  C01B2204/32 ,  C07C31/125 ,  C07C31/20 ,  C07C47/02 ,  C07C49/12 ,  C07C53/128 ,  C07C69/22 ,  Y10T428/24479 ,  Y10T428/24802 ,  Y10T428/30

摘要： A method for chemical modification of graphene includes dry etching graphene to provide an etched graphene; and introducing a functional group at an edge of the etched graphene. Also disclosed is graphene, including an etched edge portion, the etched portion including a functional group.

公开(公告)号：US09982001B2

公开(公告)日：2018-05-29

申请号：US14958143

申请日：2015-12-03

申请人： Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Armin Börner ,  Detlef Selent

发明人： Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Armin Börner ,  Detlef Selent

IPC分类号： C07F9/6574 ,  C07C45/50 ,  C07F15/00 ,  C07F15/06

CPC分类号： C07F9/65744 ,  C07C45/50 ,  C07F9/65746 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/0073 ,  C07F15/06 ,  C07C47/02

摘要： Bisphosphites having an unsymmetric central biaryl unit.

公开(公告)号：US20180105477A1

公开(公告)日：2018-04-19

申请号：US15565133

申请日：2016-11-29

申请人： ZHEJIANG NHU COMPANY LTD. ,  SHANDONG NHU PHARMACEUTICAL CO., LTD. ,  ZHEJIANG UNIVERSITY

发明人： YOUGUI ZHOU ,  MING YU ,  JINTAO YUAN ,  LEI ZHAO ,  XIANDONG ZHU ,  GUANGXIONG YU ,  WEIWEI SU ,  WEIKANG SHAO ,  XINGXING SHI ,  YIN ZHANG ,  MING FENG ,  ZHIRONG CHEN ,  HAORAN LI ,  YUHONG ZHANG

IPC分类号： C07B53/00 ,  B01J31/02 ,  B01J23/46 ,  C07C45/62 ,  C07C47/21 ,  C07C47/225 ,  C07C47/232 ,  C07C49/21 ,  C07C49/217 ,  C07D307/46 ,  C07D333/22

CPC分类号： C07B53/00 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J31/02 ,  B01J31/0237 ,  C07C45/62 ,  C07C47/21 ,  C07C47/225 ,  C07C47/232 ,  C07C49/21 ,  C07C49/217 ,  C07C67/303 ,  C07C201/12 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2602/10 ,  C07D307/46 ,  C07D333/22 ,  Y02P20/584 ,  C07C205/44 ,  C07C47/02 ,  C07C47/19 ,  C07C47/198 ,  C07C47/23 ,  C07C69/716 ,  C07C47/24 ,  C07C49/403 ,  C07C47/277 ,  C07C49/175 ,  C07C49/213 ,  C07C49/215 ,  C07C49/427

摘要： The present invention discloses a method for preparing optically active carbonyl compound, comprising the following steps: under the catalysis of chiral amine salt and transition metal catalysts, with hydrogen and catalytic amount of dihydropyridine compound as hydrogen source, use α, β-unsaturated aldehydes or α, β-unsaturated troponoid compounds to conduct asymmetric catalytic reaction to obtain the optically active carbonyl compound. This method comes in moderate reaction condition, simple operation, and catalytic amount of dihydropyridine compounds usage, the target product is easy to be separated and purified from the reaction system, and the metal catalyst can be recycled, it is economical.

公开(公告)号：US20180057437A1

公开(公告)日：2018-03-01

申请号：US15536524

申请日：2015-12-18

申请人： BASF SE

发明人： Mathias SCHELWIES ,  Rocco PACIELLO ,  Gunnar HEYDRICH ,  Günter WEGNER ,  Gerd TEBBEN ,  Martin HAUBNER ,  Andreas KELLER ,  Oliver BEY ,  Stephanie RENZ ,  Georg SEEBER

IPC分类号： C07C45/62 ,  C07C29/56 ,  C07C29/17

CPC分类号： C07C45/62 ,  C07B2200/07 ,  C07C29/172 ,  C07C29/56 ,  C07C2601/14 ,  C07C47/21 ,  C07C47/02 ,  C07C35/12 ,  C07C35/17

摘要： The present invention relates to a process for the preparation of an optically active carbonyl compound by asymmetric hydrogenation of a prochiral α,β-unsaturated carbonyl compound with hydrogen in the presence of at least one optically active transition metal catalyst that is soluble in the reaction mixture and which has rhodium as catalytically active transition metal and a chiral, bidentate bisphosphine ligand, wherein the reaction mixture during the hydrogenation of the prochiral α,β-unsaturated carbonyl compound additionally comprises at least one compound of the general formula (I): in which R1, R2: are identical or different and are C6- to C10-aryl which is unsubstituted or carries one or more, e.g. 1, 2, 3, 4 or 5, substituents which are selected from C1- to C6-alkyl, C3- to C6-cycloalkyl, C6- to C10-aryl, C1- to C6-alkoxy and amino; Z is a group CHR3R4 or aryl which is unsubstituted or carries one or more, e.g. 1, 2, 3, 4 or 5, substituents which are selected from C1- to C6-alkyl, C3- to C6-cycloalkyl, C6- to C10-aryl, C1- to C6-alkoxy and amino, wherein R3 and R4 are as defined in the claims and the description.

公开(公告)号：US20180022676A1

公开(公告)日：2018-01-25

申请号：US15719658

申请日：2017-09-29

申请人： Eastman Chemical Company

发明人： Venkata Bharat Boppana ,  Kenneth Wayne Hampton, JR. ,  Zhufang Liu ,  Charles Edwan Sumner, JR. ,  Gerald Charles Tustin ,  Guy Ralph Steinmetz ,  Melissa Page Steffey

IPC分类号： C07C45/72 ,  B01J37/18 ,  B01J37/16 ,  B01J23/44 ,  B01J37/02 ,  B01J21/06 ,  B01J35/00

CPC分类号： C07C45/72 ,  B01J21/063 ,  B01J23/44 ,  B01J23/96 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/008 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/16 ,  B01J37/18 ,  B01J38/02 ,  B01J38/12 ,  C07C45/73 ,  Y02P20/584 ,  C07C47/02

摘要： Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

公开(公告)号：US09856282B2

公开(公告)日：2018-01-02

申请号：US15183490

申请日：2016-06-15

申请人： Kanto Kagaku Kabushiki Kaisha

发明人： Ryohei Yamaguchi ,  Ken-ichi Fujita

IPC分类号： C07F17/02 ,  C07C45/00 ,  C07C201/12 ,  B01J7/02 ,  C07C51/16 ,  B01J31/22 ,  C01B3/06 ,  C01B3/32 ,  C01B3/00 ,  C01B3/22 ,  C07B41/06 ,  C07B41/08 ,  C07J13/00

CPC分类号： C07F17/02 ,  B01J7/02 ,  B01J31/2295 ,  B01J2231/763 ,  B01J2231/766 ,  B01J2531/827 ,  C01B3/0015 ,  C01B3/06 ,  C01B3/22 ,  C01B3/326 ,  C01B2203/02 ,  C01B2203/0227 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/1205 ,  C01B2203/1211 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C07B41/06 ,  C07B41/08 ,  C07C45/002 ,  C07C51/16 ,  C07C201/12 ,  C07C2601/08 ,  C07C2601/14 ,  C07J13/007 ,  Y02E60/328 ,  Y02E60/36 ,  Y02P20/132 ,  C07C47/02 ,  C07C47/06 ,  C07C47/32 ,  C07C47/52 ,  C07C49/04 ,  C07C49/213 ,  C07C49/395 ,  C07C49/403

摘要： Objects of the present invention are to provide a novel dehydrogenation reaction catalyst, to provide a method that can produce a ketone, an aldehyde, and a carboxylic acid with high efficiency from an alcohol, and to provide a method for efficiently producing hydrogen from an alcohol, formic acid, or a formate, and they are accomplished by a catalyst containing an organometallic compound of Formula (1).