公开(公告)号：US11772076B2

公开(公告)日：2023-10-03

申请号：US17074548

申请日：2020-10-19

申请人： ZHEJIANG UNIVERSITY

发明人： Yong Wang ,  Shanjun Mao ,  Zhe Wang

IPC分类号： B01J21/18 ,  B01J23/44 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/03 ,  B01J3/04 ,  C07C45/00 ,  C07C47/02

CPC分类号： B01J23/44 ,  B01J21/18 ,  B01J35/002 ,  B01J35/023 ,  C07C45/002 ,  C07C47/02 ,  C07C2521/18 ,  C07C2523/44

摘要： Disclosed are a nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst and a preparation method thereof. The preparation method includes preparing nitrogen-doped hierarchical-porous carbon, mixing the nitrogen-doped hierarchical-porous carbon with water, adjusting a pH value of the mixed solution to be alkaline, mixing the mixed solution with a Pd metal precursor aqueous solution, and then adding a reducing agent to obtain the nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst after reduction. The prepared nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst includes a nitrogen-doped porous carbon material carrier with hierarchical pores and Pd metal nanoparticles loaded in the hierarchical pores of the carrier. The Pd metal nanoparticles have a size of 2˜14 nm and a regular polyhedron shape. The nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst has excellent catalytic performance, especially has ultra-high conversion rate, selectivity and cycle stability in the selective hydrogenation reaction of unsaturated ketones, and is a key to open a new synthetic route of vitamin E.

公开(公告)号：US10913055B2

公开(公告)日：2021-02-09

申请号：US15765979

申请日：2017-07-04

申请人： LG CHEM, LTD.

发明人： Mi Young Kim ,  Sung Shik Eom ,  Dong Hyun Ko ,  Da Won Jung ,  Tae Yun Kim ,  Min Ji Choi

IPC分类号： C07C47/02 ,  B01J31/18 ,  C07C45/50 ,  C07C45/62 ,  B01J31/20

摘要： A hydroformylation catalyst having excellent catalytic activity and stability, a composition including the hydroformylation catalyst, and a method of preparing an aldehyde using the hydroformylation catalyst, wherein, when hydroformylation of an olefin compound is performed in the presence of the hydroformylation catalyst to prepare an aldehyde, the normal/iso (n/i) ratio of the prepared aldehyde is lowered, and synthesis gas yield is increased.

公开(公告)号：US10695715B2

公开(公告)日：2020-06-30

申请号：US15814823

申请日：2017-11-16

申请人： Industrial Technology Research Institute

发明人： Wen-An Xie ,  Hong-Ping Lin ,  Shou-Nan Li ,  Hui-Ya Shih

IPC分类号： C01B31/00 ,  B01D53/66 ,  C07B63/02 ,  C01B13/02 ,  C07G99/00 ,  B01J20/30 ,  B01J20/20 ,  C01B32/00 ,  C01B32/50 ,  C07C69/00 ,  C07C53/00 ,  C07C47/02 ,  C07B33/00

摘要： A carbonized material, a device for removing ozone, and a method for removing ozone are provided. The carbonized material has at least a carbonyl-containing group, alkylol group, and carbon having sp2 hybrid orbital. In particular, the at least one carbonyl-containing group has a carbon content from 10 atom % to 30 atom %, based on the total carbon atoms of the at least one carbonyl-containing group, the at least one alkylol group, and the at least one carbon having sp2 hybrid orbital.

公开(公告)号：US10654784B2

公开(公告)日：2020-05-19

申请号：US16574217

申请日：2019-09-18

申请人： Evonik Operations GmbH

发明人： Jennifer Haßelberg ,  Robert Franke ,  Frank Stenger ,  Peter Kreis ,  Corinna Hecht ,  Marc Oliver Kristen

IPC分类号： C07C45/50 ,  B01J31/00 ,  C07C47/02 ,  B01J31/02 ,  B01J27/22

摘要： The invention relates to a process for hydroformylating short-chain olefins, especially C2 to C5 olefins, in which the catalyst system is in heterogenized form on a support of a porous ceramic material, and to plants for performing this process.

公开(公告)号：US10351503B2

公开(公告)日：2019-07-16

申请号：US15768397

申请日：2016-10-27

申请人： Dow Technology Investments LLC

发明人： Gerald L. Smith ,  Kathleen Simpson

IPC分类号： C07C45/50 ,  B01L3/14 ,  B01J31/02 ,  B01J31/40 ,  C07C47/02

摘要： The present invention relates generally to processes for producing aldehydes wherein an olefinic compound, carbon monoxide, and hydrogen are reacted in the presence of a solubilized rhodium-phosphorous complex. In one embodiment, the process comprises (a) receiving a vaporized aldehyde product stream downstream from a hydroformylation reactor, the vaporized aldehyde product stream comprising aldehydes, phosphorous ligand, and aldehyde condensation by-products; (b) contacting the vaporized aldehyde product stream with a partial condenser so as to condense the phosphorous ligand and the by-products, wherein up to 10 weight percent of the vaporized stream is condensed; (c) removing the condensed phosphorous ligand and the condensed by-products from the liquid condensation stream using a refining column; and (d) further processing the vaporized aldehydes from the separate refining column.

公开(公告)号：US10173960B2

公开(公告)日：2019-01-08

申请号：US15564927

申请日：2016-04-08

申请人： DAIKIN INDUSTRIES, LTD.

发明人： Tomohito Hamada ,  Makoto Matsuura ,  Asako Yoshiyama ,  Akihiro Gotou ,  Manaho Miyazaki ,  Yosuke Kishikawa

IPC分类号： C07C47/02 ,  C07C67/62 ,  C07C69/653

摘要： An object of the present invention is to provide a method for stabilizing an acrylic acid derivative, and a composition containing an acrylic acid derivative in which the acrylic acid derivative is stabilized. The present invention provides a composition comprising: (A) an acrylic acid derivative represented by Formula (I): (wherein Ra represents alkyl, fluoroalkyl, aryl that may have one or more substituents, or hydrogen; and X represents fluorine, alkyl, perfluoroalkyl, or hydrogen); and (B) aldehyde, wherein the content of acrylic acid derivative (A) is 30% (w/w) or more.

公开(公告)号：US20180305285A1

公开(公告)日：2018-10-25

申请号：US15768397

申请日：2016-10-27

申请人： Dow Technology Investments LLC

发明人： Gerald L. Smith ,  Kathleen Simpson

IPC分类号： C07C45/50 ,  C07C47/02 ,  B01J31/40 ,  B01J31/02 ,  B01D3/14

CPC分类号： C07C45/50 ,  B01D3/14 ,  B01J31/0267 ,  B01J31/4046 ,  B01J2531/822 ,  C07C47/02 ,  Y02P20/582

摘要： The present invention relates generally to processes for producing aldehydes wherein an olefinic compound, carbon monoxide, and hydrogen are reacted in the presence of a solubilized rhodium-phosphorous complex. In one embodiment, the process comprises (a) receiving a vaporized aldehyde product stream downstream from a hydroformylation reactor, the vaporized aldehyde product stream comprising aldehydes, phosphorous ligand, and aldehyde condensation by-products; (b) contacting the vaporized aldehyde product stream with a partial condenser so as to condense the phosphorous ligand and the by-products, wherein up to 10 weight percent of the vaporized stream is condensed; (c) removing the condensed phosphorous ligand and the condensed by-products from the liquid condensation stream using a refining column; and (d) further processing the vaporized aldehydes from the separate refining column.

公开(公告)号：US20180290132A1

公开(公告)日：2018-10-11

申请号：US15765979

申请日：2017-07-04

申请人： LG CHEM, LTD.

发明人： Mi Young KIM ,  Sung Shik EOM ,  Dong Hyun KO ,  Da Won JUNG ,  Tae Yun KIM ,  MIn Ji CHOI

IPC分类号： B01J31/18 ,  C07C47/02

摘要： A hydroformylation catalyst having excellent catalytic activity and stability, a composition including the hydroformylation catalyst, and a method of preparing an aldehyde using the hydroformylation catalyst, wherein, when hydroformylation of an olefin compound is performed in the presence of the hydroformylation catalyst to prepare an aldehyde, the normal/iso (n/i) ratio of the prepared aldehyde is lowered, and synthesis gas yield is increased.

公开(公告)号：US09777302B2

公开(公告)日：2017-10-03

申请号：US14741259

申请日：2015-06-16

申请人： INVISTA North America S.á r.l.

发明人： Alex Van Eck Conradie ,  Adriana Leonora Botes ,  Ramdane Haddouche

IPC分类号： C07C47/02 ,  C12P13/00 ,  C12P7/64 ,  C12N9/10 ,  C12N9/02 ,  C12P7/24 ,  C07C59/01 ,  C08G63/06 ,  C12P7/40 ,  C12P7/42 ,  C07C47/12 ,  C07C59/325 ,  C07C223/02 ,  C12P7/44 ,  C12P7/62

CPC分类号： C12P13/001 ,  C07C47/02 ,  C07C47/12 ,  C07C59/01 ,  C07C59/325 ,  C07C223/02 ,  C08G63/06 ,  C12N9/0008 ,  C12N9/0077 ,  C12N9/1007 ,  C12N9/1096 ,  C12P7/24 ,  C12P7/40 ,  C12P7/42 ,  C12P7/44 ,  C12P7/62 ,  C12P7/6409 ,  C12P7/6436 ,  C12Y102/99006 ,  C12Y114/15001 ,  C12Y114/15003 ,  C12Y206/01018 ,  C12Y206/01019 ,  C12Y206/01029 ,  C12Y206/01048 ,  C12Y206/01082

摘要： This document describes biochemical pathways for producing 5-hydroxypentanoate methyl ester and pentanoic acid pentyl ester using one or more of a fatty acid O-methyltransferase, an alcohol O-acetyltransferase, and a monooxygenase, as well as recombinant hosts expressing one or more of such exogenous enzymes. 5-hydroxypentanoate methyl esters and pentanoic acid pentyl esters can be enzymatically converted to glutaric acid, 5-aminopentanoate, 5-hydroxypentanoate, cadaverine, or 1,5-pentanediol.

公开(公告)号：US08921607B2

公开(公告)日：2014-12-30

申请号：US13439231

申请日：2012-04-04

申请人： Raphael F. Caers ,  Eddy Theophile Van Driessche ,  Hubertus J. Beckers ,  Luc Roger Marc Martens ,  Georges Marie Mathys ,  John Richard Shutt

发明人： Raphael F. Caers ,  Eddy Theophile Van Driessche ,  Hubertus J. Beckers ,  Luc Roger Marc Martens ,  Georges Marie Mathys ,  John Richard Shutt

IPC分类号： C07C45/00 ,  C07C29/141 ,  C07C31/125 ,  C07C69/80 ,  C07C29/17 ,  C07C47/02 ,  C07C69/22 ,  C07C69/003 ,  C07C45/50 ,  C07C53/126

CPC分类号： C07C29/141 ,  C07C29/175 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C07C53/126 ,  C07C69/003 ,  C07C69/22 ,  C07C69/80

摘要： Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes. Higher temperatures and/or longer residence times and/or higher partial pressure of carbon monoxide than in conventional processes are used to ensure hydroformylation of all the monomers.

摘要翻译： 在加氢甲酰化所有单体以产生戊醛混合物的条件下，将含有丁烯-1和异丁烯和任选的丁烯-2的混合丁烯流加氢甲酰化。 使用比常规方法更高的温度和/或更长的停留时间和/或更高的一氧化碳分压来确保所有单体的加氢甲酰化。