公开(公告)号：US20230340237A1

公开(公告)日：2023-10-26

申请号：US18245377

申请日：2021-09-16

Applicant: ZANNAN SCITECH CO., LTD.

Inventor： Zheng-Yun James ZHAN

IPC: C08L15/00 ,  C07F15/00 ,  C08C19/02 ,  C08C19/08 ,  C08K13/04 ,  B01J31/22

CPC classification number: C08L15/005 ,  C07F15/0046 ,  C08C19/02 ,  C08C19/08 ,  C08K13/04 ,  B01J31/2278 ,  B01J31/2217 ,  C08L2207/324 ,  C08L2201/08 ,  B01J2531/821 ,  B01J2231/645 ,  B01J2231/005 ,  C08K3/04

Abstract: Disclosed are a liquid hydrogenated nitrile-butadiene rubber, a preparation method therefor and the use thereof. In the liquid hydrogenated nitrile-butadiene rubber: the content of acrylonitrile is 15-50%; the hydrogenation saturation is 75-99.5%; the weight-average molecular weight (Mw) is 3,000-60,000; the molecular weight polydispersity index (PDI) is 2.0-8.0; and the glass transition temperature (Tg) is lower than −28° C. The liquid hydrogenated nitrile-butadiene rubber is low in molecular weight and wide in molecular weight polydispersity, simultaneously has an excellent fluidity during processing and excellent mechanical properties after curing and has a unique application value in the field of special rubbers; and the preparation method therefor is simple and feasible in terms of the process.

公开(公告)号：US11773049B2

公开(公告)日：2023-10-03

申请号：US17530629

申请日：2021-11-19

Applicant: EVONIK OPERATIONS GMBH

Inventor： Peter Kucmierczyk ,  Robert Franke ,  Matthias Beller ,  Ricarda Dühren ,  Ralf Jackstell

IPC: C07C67/04 ,  C07C67/36 ,  C07C67/38 ,  B01J31/22

CPC classification number: C07C67/04 ,  B01J31/2234 ,  C07C67/36 ,  C07C67/38 ,  B01J2231/321 ,  B01J2231/645 ,  B01J2531/821 ,  C07C67/36 ,  C07C69/14 ,  C07C67/38 ,  C07C69/14

Abstract: Ru-catalysed domino hydroformylation/hydrogenation/esterification using phosphine ligands.

公开(公告)号：US20180223005A1

公开(公告)日：2018-08-09

申请号：US15882145

申请日：2018-01-29

Applicant: ARLANXEO Deutschland GmbH

Inventor： Werner OBRECHT ,  Sarah DAVID ,  Qingchun LIU ,  Zhenli WEI

IPC: C08C19/02 ,  B01J31/22 ,  B01J31/18 ,  B01J31/24 ,  B01J31/02 ,  C08C19/00

CPC classification number: C08C19/02 ,  B01J31/0204 ,  B01J31/1805 ,  B01J31/181 ,  B01J31/183 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/2286 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/543 ,  B01J2231/641 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/825 ,  B01J2540/20 ,  B01J2540/40 ,  C08C2019/09

Abstract: Catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and specific co-catalysts are provided for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.

公开(公告)号：US10016749B2

公开(公告)日：2018-07-10

申请号：US14428622

申请日：2013-09-12

Applicant: Asahi Kasei Chemicals Corporation

Inventor： Yoshifumi Araki ,  Eiji Sasaya ,  Katsunori Nitta

IPC: C08C19/02 ,  B01J31/22 ,  B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  C07F7/28 ,  C08F299/02 ,  C07F17/00 ,  C08F8/04

CPC classification number: B01J31/2295 ,  B01J31/0204 ,  B01J31/0209 ,  B01J31/0237 ,  B01J31/122 ,  B01J31/143 ,  B01J31/22 ,  B01J2231/60 ,  B01J2231/64 ,  B01J2231/645 ,  B01J2531/46 ,  C07F7/28 ,  C07F17/00 ,  C08C19/02 ,  C08F8/04 ,  C08F299/02 ,  C08F297/04

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R5 and R6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R1 and R2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R1 and R2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms), (B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated compound having a molecular weight of 400 or less, and (D): a polar compound.

公开(公告)号：US09963651B1

公开(公告)日：2018-05-08

申请号：US15291615

申请日：2016-10-12

Applicant: The United States of America as Represented by the Secretary of the Navy

Inventor： Benjamin G Harvey

IPC: C07C2/52 ,  C10L1/04 ,  C07C6/04 ,  C07C5/03 ,  C07C5/27

CPC classification number: C10L1/04 ,  B01J31/10 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/821 ,  C07C1/20 ,  C07C2/50 ,  C07C2/52 ,  C07C4/10 ,  C07C5/03 ,  C07C5/22 ,  C07C5/2253 ,  C07C5/2506 ,  C07C5/27 ,  C07C5/29 ,  C07C5/31 ,  C07C6/04 ,  C07C29/00 ,  C07C2521/16 ,  C07C2523/16 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2527/053 ,  C07C2527/11 ,  C07C2527/126 ,  C07C2527/167 ,  C07C2531/04 ,  C07C2531/10 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2601/10 ,  C07C2602/28 ,  C07C2602/32 ,  C07C2602/42 ,  C07C2602/50 ,  C07C2603/12 ,  C07C2603/30 ,  C07C2603/66 ,  C07C2603/68 ,  C07C2603/80 ,  C10G45/00 ,  C10G50/00 ,  C10G65/043 ,  C10G69/126 ,  C10G2300/1011 ,  C10G2300/1092 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/44 ,  C10G2300/703 ,  C10G2400/04 ,  C10G2400/22 ,  C10L1/08 ,  C10L2200/0469 ,  Y02P30/20 ,  C07C13/15 ,  C07C13/61 ,  C07C13/43 ,  C07C9/16 ,  C07C13/40 ,  C07C35/06 ,  C07C11/09 ,  C07C13/605 ,  C07C13/547 ,  C07C13/54 ,  C07C13/32 ,  C07C13/50 ,  C07C13/72

Abstract: A method to generate cyclic hydrocarbons from farnesene to increase both the density and net heat of combustion of the product fuels.

公开(公告)号：US09884316B2

公开(公告)日：2018-02-06

申请号：US15124773

申请日：2015-03-03

Applicant: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION ,  SHIN-ETSU CHEMICAL CO., LTD.

Inventor： Hideo Nagashima ,  Yusuke Sunada ,  Hajime Ogushi ,  Koji Sakuta

IPC: C07C69/38 ,  B01J31/16 ,  C07C209/50 ,  C07F15/00 ,  C07F19/00 ,  C07C5/03 ,  C07C67/303 ,  C07C67/283 ,  C07C209/62 ,  C07F7/08

CPC classification number: B01J31/1608 ,  B01J2231/323 ,  B01J2231/645 ,  B01J2531/821 ,  C07C5/03 ,  C07C67/283 ,  C07C67/303 ,  C07C209/50 ,  C07C209/62 ,  C07C2531/16 ,  C07C2531/18 ,  C07C2601/14 ,  C07C2602/08 ,  C07F7/0829 ,  C07F7/0879 ,  C07F15/0046 ,  C07F15/0053 ,  C07F19/00 ,  C07C211/04 ,  C07C13/18 ,  C07C13/465 ,  C07C15/18 ,  C07C15/073 ,  C07C9/15 ,  C07C9/16 ,  C07C69/24 ,  C07C69/38 ,  C07C69/612

Abstract: A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. (In the formula, R1-R6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R1-R3 and any of R4-R6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)

公开(公告)号：US09782762B2

公开(公告)日：2017-10-10

申请号：US14771765

申请日：2014-02-26

Applicant: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION ,  SHIN-ETSU CHEMICAL CO., LTD.

Inventor： Hideo Nagashima ,  Yusuke Sunada ,  Hironori Tsutsumi ,  Toru Hashimoto ,  Koji Sakuta

IPC: C22C5/04 ,  B01J31/16 ,  B01J31/22 ,  C07C209/50 ,  C07C5/03 ,  C07C9/16 ,  C07C13/10 ,  C07C13/18 ,  C07F7/08 ,  C07C15/073 ,  C07C15/18 ,  C07F15/00 ,  C07C29/14 ,  C07C213/00 ,  C07D223/04

CPC classification number: B01J31/1608 ,  B01J31/22 ,  B01J2231/323 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2531/821 ,  C07C5/03 ,  C07C9/16 ,  C07C13/10 ,  C07C13/18 ,  C07C15/073 ,  C07C15/18 ,  C07C29/14 ,  C07C209/50 ,  C07C213/00 ,  C07C2531/16 ,  C07C2531/22 ,  C07C2531/28 ,  C07C2601/08 ,  C07C2601/14 ,  C07D223/04 ,  C07F7/08 ,  C07F15/0046 ,  C07C217/58 ,  C07C211/29 ,  C07C211/27 ,  C07C9/18

Abstract: Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R1-R6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R1-R3 and one of R4-R6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.

公开(公告)号：US09732166B2

公开(公告)日：2017-08-15

申请号：US14408409

申请日：2013-06-21

Applicant: UNIVERSITY OF WATERLOO

Inventor： Garry L. Rempel ,  Qinmin Pan ,  Yin Liu ,  Jialong Wu

IPC: C08C19/02 ,  C08C19/00

CPC classification number: C08C19/02 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/825 ,  C08C19/08 ,  C08C2019/09

Abstract: The present invention provides a novel process for subjecting a diene-based-polymer to a metathesis reaction in a first step and a selective hydrogenation of the carbon-carbon double bonds present in such diene-based polymers in a second step using a ruthenium or osmium based complex catalyst, wherein the diene-based polymer is present in latex form, this means as a suspension of diene-based polymer particles in an aqueous medium.

公开(公告)号：US09725395B2

公开(公告)日：2017-08-08

申请号：US14650537

申请日：2013-12-06

Applicant: University of Central Florida Research Foundation, Inc.

Inventor： Richard G. Blair

IPC: C07C51/36 ,  C07C5/03 ,  C01B21/064 ,  B01J27/24 ,  B01J37/00 ,  B01J35/02 ,  C07C45/62 ,  C07C231/00 ,  C07C253/00 ,  B01J37/34

CPC classification number: C07C51/36 ,  B01J27/24 ,  B01J35/02 ,  B01J37/00 ,  B01J37/0036 ,  B01J37/343 ,  B01J2231/643 ,  B01J2231/645 ,  C01B21/0648 ,  C01P2002/85 ,  C01P2004/03 ,  C07C5/03 ,  C07C45/62 ,  C07C231/00 ,  C07C253/00 ,  C07C2527/24 ,  C07C9/08 ,  C07C9/22 ,  C07C15/18 ,  C07C15/16 ,  C07C255/03 ,  C07C255/07 ,  C07C233/11 ,  C07C57/30 ,  C07C49/784

Abstract: The inventive concepts disclosed and/or claimed herein relate generally to catalysts and, more particularly, but not by way of limitation, to a heterogeneous, metal-free hydrogenation catalyst containing frustrated Lewis pairs. In one non-limiting embodiment, the heterogeneous, metal-free catalyst comprises hexagonal boron nitride (h-BN) having frustrated Lewis pairs therein.

公开(公告)号：US20170218002A1

公开(公告)日：2017-08-03

申请号：US15514977

申请日：2015-09-18

Applicant: KURARAY CO., LTD.

Inventor： Shinji HATAE ,  Syuichi SUNAGA ,  Tomoaki TSUJI

IPC: C07F17/00 ,  B01J31/22

CPC classification number: C07F17/00 ,  B01J31/2295 ,  B01J2231/645 ,  B01J2531/0208 ,  B01J2531/31 ,  B01J2531/46 ,  C07F5/06 ,  C07F7/28 ,  C07F19/00

Abstract: The present invention relates to a method for producing a Tebbe complex having high purity and high activity and having excellent storage stability in a high yield, the method including allowing bis(cyclopentadienyl)titanium dichloride and trimethylaluminum to react with each other in the presence of a solvent such that a solubility of the Tebbe complex in 1 g of the solvent at 25° C. is 0.5 mmol/g or less.