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    METHODS
    1.
    发明申请
    METHODS 有权

    公开(公告)号：US20250042836A1

    公开(公告)日：2025-02-06

    申请号：US18680516

    申请日：2024-05-31

    Applicant: MEXICHEM FLUOR S.A. DE C.V.

    Inventor： Andrew P. Sharratt ,  John Charles McCarthy

    IPC: C07C67/38 ,  C07C69/63 ,  C07C69/675 ,  C07C69/708 ,  C09K5/08 ,  C10M105/54 ,  H01M10/0569

    Abstract: A method for preparing a partially fluorinated ester comprising acyl and alkoxy groups wherein the acyl group comprises a branched or linear fluorine containing C3-C8 group with one of the structures: wherein X and Y are independently selected from: —H, —CH3, —F, —CI, —CH2F, —CF3, —OCF3, —OCH2CF3, OCH2CF2CHF2 and —CH2CF3 (wherein both X and Y cannot be H) comprising reacting an unsaturated halocarbon: wherein A and B are independently selected from the group comprising —H, —CH3, —F, —CI, —CH2F, —CF3, —OCF3, —OCH2CF3, OCH2CF2CHF2 and —CH2CF3 (wherein both A and B cannot be H) with carbon monoxide and an alcohol, in the presence of a catalyst.

    BUTYL-BRIDGED DIPHOSPHINE LIGANDS FOR ALKOXYCARBONYLATION
    6.
    发明申请
    BUTYL-BRIDGED DIPHOSPHINE LIGANDS FOR ALKOXYCARBONYLATION 有权

    公开(公告)号：US20210276939A1

    公开(公告)日：2021-09-09

    申请号：US17326738

    申请日：2021-05-21

    Applicant: EVONIK OPERATIONS GMBH

    Inventor： Kaiwu DONG ,  Xiangjie FANG ,  Helfried NEUMANN ,  Ralf JACKSTELL ,  Matthias BELLER ,  Robert FRANKE ,  Dieter HESS ,  Katrin Marie DYBALLA ,  Dirk FRIDAG ,  Frank GEILEN

    IPC: C07C67/38 ,  C07F9/58 ,  C07F9/572 ,  C07F9/6506 ,  C07F15/00 ,  B01J31/24 ,  B01J31/22 ,  C07F9/655 ,  C07F9/6553 ,  C07F17/02

    Abstract: The invention relates to compounds of formula (I) where R1, R2, R3, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; at least one of the R1, R2, R3, R4 radicals is a —(C3-C20)-heteroaryl radical; and R1, R2, R3, R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl or —(C3-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen; and to the use thereof as ligands in alkoxycarbonylation.

    PROCESS FOR THE ALKOXYCARBONYLATION OF ALCOHOLS
    8.
    发明申请
    PROCESS FOR THE ALKOXYCARBONYLATION OF ALCOHOLS 审中-公开

    公开(公告)号：US20180022765A1

    公开(公告)日：2018-01-25

    申请号：US15649770

    申请日：2017-07-14

    Applicant: EVONIK DEGUSSA GMBH

    Inventor： Kaiwu DONG ,  Ralf JACKSTELL ,  Helfried NEUMANN ,  Matthias BELLER ,  Dirk FRIDAG ,  Dieter HESS ,  Katrin Marie DYBALLA ,  Frank GEILEN ,  Robert FRANKE

    IPC: C07F9/50 ,  C07F15/00 ,  C07D471/00 ,  C07C67/38

    CPC classification number: C07F9/5045 ,  C07C67/36 ,  C07C67/38 ,  C07D471/00 ,  C07F15/0066 ,  C07C69/24 ,  C07C69/612

    Abstract: The invention relates to a process comprising the following process steps: a) introducing a first alcohol, the first alcohol having 2 to 30 carbon atoms; b) adding a phosphine ligand and a compound which comprises Pd, or adding a complex comprising Pd and a phosphine ligand; c) adding a second alcohol; d) supplying CO; e) heating the reaction mixture, the first alcohol reacting with CO and the second alcohol to form an ester; where the phosphine ligand is a compound of formula (I) where m and n are each independently 0 or 1; R1, R2, R3, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; at least one of the R1, R2, R3, R4 radicals is a —(C3-C20)-heteroaryl radical; and R1, R2, R3, R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl or —(C3-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-alkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COON, —OH, —SO3H, —NH2, halogen.

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