PREPARATION OF SURFACTANTS VIA CROSS-METATHESIS
    7.
    发明申请
    PREPARATION OF SURFACTANTS VIA CROSS-METATHESIS 有权
    通过跨METASESES制备表面活性剂

    公开(公告)号:US20160145204A1

    公开(公告)日:2016-05-26

    申请号:US14782935

    申请日:2014-04-09

    申请人: MATERIA, INC.

    摘要: The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein.

    摘要翻译: 本发明涉及包含烯烃苯或烯烃苯磺酸盐或烷基苯或烷基苯磺酸盐的组合物; 制备烯烃苯或烯烃苯磺酸盐或烷基苯或烷基苯磺酸盐的方法; 其中苯环任选被一个或多个指定为R *的基团取代,其中R *在本文中定义。 更具体地说,本发明涉及包含2-苯基线性烯烃苯或2-苯基直链烯烃苯磺酸盐或2-苯基直链烷基苯或2-苯基直链烷基苯磺酸盐的组合物; 制备2-苯基烯烃苯酚或2-苯基烯烃苯磺酸盐或2-苯基烷基苯或2-苯基烷基苯磺酸盐的方法; 其中苯环任选被一个或多个指定为R *的基团取代,其中R *在本文中定义。

    OLIGOMERISATION OF ETHYLENE TO MIXTURES OF 1-HEXENE AND 1-OCTENE
    8.
    发明申请
    OLIGOMERISATION OF ETHYLENE TO MIXTURES OF 1-HEXENE AND 1-OCTENE 有权
    乙烯的低聚与1-HEXENE和1-OCTENE的混合物

    公开(公告)号:US20160083312A1

    公开(公告)日:2016-03-24

    申请号:US14888717

    申请日:2014-05-06

    IPC分类号: C07C2/32

    摘要: A process for the oligomerisation, preferably the tetramerisation, of ethylene to predominantly 1-hexene or 1-octene or mixtures of 1-hexene and 1-octene includes contacting ethylene with a catalyst under ethylene oiigomerisation conditions. The catalyst comprises a source of chromium, a diphosphine ligating compound, and optionally an activator. The diphosphine ligating compound includes at least one substituted aromatic ring bonded to a phosphorous atom. The substituted aromatic ring is substituted at a ring atom adjacent to the ring atom bonded to the respective phosphorous atom with a group Y, where Y is of the form —AREWG, A being O, S or NR5, where R5 is a hydrocarbyl, heterohydrocarbyl or organoheteryl group, and REWG is an electron withdrawing group.

    摘要翻译: 乙烯至主要1-己烯或1-辛烯或1-己烯和1-辛烯的混合物的低聚,优选四聚的方法包括在乙烯异构化条件下使乙烯与催化剂接触。 催化剂包含铬源,二膦连接化合物和任选的活化剂。 二膦连接化合物包括至少一个与磷原子键合的取代芳环。 取代的芳环在与Y基团连接的各个磷原子的环原子相邻的环原子上被取代,其中Y为-AREWG,A为O,S或NR5,其中R5为烃基,杂烃基 或有机基酰基,REWG是吸电子基团。

    OLIGOMERISATION OF ETHYLENE TO MIXTURES OF 1-HEXENE AND 1-OCTENE
    9.
    发明申请
    OLIGOMERISATION OF ETHYLENE TO MIXTURES OF 1-HEXENE AND 1-OCTENE 有权
    乙烯的低聚与1-HEXENE和1-OCTENE的混合物

    公开(公告)号:US20160083311A1

    公开(公告)日:2016-03-24

    申请号:US14888520

    申请日:2014-05-06

    IPC分类号: C07C2/32

    摘要: A process for the oligomerisation of ethylene to predominantly 1-hexene or 1-octene or mixtures of 1-hexene and 1-octene includes contacting ethylene with a catalyst under ethylene oligomerisation conditions. The catalyst comprises a source of chromium, a diphosphine ligating compound, and optionally an activator. The diphosphine ligating compound includes at least one optionally substituted fused cyclic structure including at least two rings, the optionally substituted fused cyclic structure including a 5- to 7-membered aromatic first ring bonded to a phosphorus atom, the aromatic first ring being fused to a 4- to 8-membered heterocyclic second ring, the heterocyclic second ring including a heteroatom which is separated by two ring atoms along the shortest connecting path from the phosphorous atom that is bonded to the first aromatic ring.

    摘要翻译: 将乙烯低聚至主要1-己烯或1-辛烯或1-己烯和1-辛烯的混合物的方法包括在乙烯齐聚条件下使乙烯与催化剂接触。 催化剂包含铬源,二膦连接化合物和任选的活化剂。 二膦连接化合物包括至少一个包含至少两个环的任选取代的稠合环状结构,任选取代的稠合环状结构包括与磷原子键合的5-至7-元芳族第一环,芳族第一环与 4-至8-元杂环第二环,杂环第二环包括由键合到第一芳香环上的磷原子的最短连接路径被两个环原子分开的杂原子。