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    CATALYST COMPOUNDS
    8.
    发明申请
    CATALYST COMPOUNDS 审中-公开
    催化剂化合物

    公开(公告)号：US20150073165A1

    公开(公告)日：2015-03-12

    申请号：US14394246

    申请日：2013-04-15

    申请人： THE UNIVERSITY OF LIVERPOOL

    发明人： Barbara Villa Marcos ,  Weijun Tang ,  Dinesh Talwar ,  Chao Wang ,  Jianjun Wu ,  Jianliang Xiao

    IPC分类号： C07F15/00 ,  B01J31/22

    CPC分类号： C07F15/0033 ,  B01J31/18 ,  B01J31/2295 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2531/827 ,  C07B31/00 ,  C07F17/02

    摘要： The present invention relates to an iridium-based catalyst compound for hydrogenating reducible moieties, especially imines and iminiums, the catalyst compounds being defined by the formula: (Formula (I)) where ring B is a conjugated ring system with one or more substituents. The catalysts of the invention are particularly effective in reductive amination procedures which involve the in situ generation of the imine or iminium under reductive hydrogenative conditions.

    摘要翻译： 本发明涉及用于氢化可还原部分，特别是亚胺和亚胺的铱基催化剂化合物，催化剂化合物由式（I（I））定义，其中环B是具有一个或多个取代基的共轭环系。 本发明的催化剂在还原胺化方法中特别有效，其涉及在还原氢化条件下原位产生亚胺或亚胺。

    ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS
    9.
    发明申请
    ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS 审中-公开
    含有N-杂环碳酸酯配位体的亚甲基二胺的复合物; 用作高活性选择性催化剂，用于烯烃METATHESIS

    公开(公告)号：US20150038723A1

    公开(公告)日：2015-02-05

    申请号：US14193785

    申请日：2014-02-28

    申请人： Evonik Degussa GmbH

    发明人： Wolfgang Anton Herrmann ,  Wolfgang Schattenmann ,  Thomas Weskamp

    IPC分类号： C07F15/00

    CPC分类号： C07F15/0046 ,  B01J31/18 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2404 ,  B01J31/26 ,  B01J2231/14 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/0263 ,  B01J2531/821 ,  C07C2/32 ,  C07C6/04 ,  C07C67/313 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C08G61/08 ,  C07C69/593 ,  C07C13/20 ,  C07C11/02

    摘要： Akylidene complexes of ruthenium containing N-heterocyclic carbene ligands and their use as highly active, selective catalysts for olefin metathesisThe invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.

    摘要翻译： 含有N-杂环卡宾配体的钌的亚胺络合物及其作为烯烃复分解的高活性选择性催化剂的用途本发明涉及结构式I的钌络合物，其中X1和X2相同或不同并且各自为阴离子配体 R 1和R 2相同或不同，也可以含有环，R 1和R 2各自为氢或/或烃基，配位体L1为N-杂环卡宾，配位体L2为不带电子的电子给体，特别是 N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R1，R2，R3和R4是氢或/ 。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R'1，R'2，R'3和R'4是氢或/和烃基。