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    Catalytic method for the production of carbonyl compounds
    5.
    发明授权
    Catalytic method for the production of carbonyl compounds 有权
    用于生产羰基化合物的催化方法

    公开(公告)号：US07273954B2

    公开(公告)日：2007-09-25

    申请号：US10534878

    申请日：2003-11-14

    Applicant: Franco Antognoli ,  Paul Rys

    Inventor： Franco Antognoli ,  Paul Rys

    IPC: C07C45/28

    CPC classification number: B01J31/0218 ,  B01J31/0215 ,  B01J31/28 ,  B01J2231/70 ,  C07C45/28

    Abstract: The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1=H, alkyl or aryl, X=H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of Eo>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.

    Abstract translation: 本发明涉及一种生产具有至少一种醛或酮官能团的脂族和芳族羰基化合物的催化方法，其中所述化合物还可以包含至少一种醛和酮官能团。 包含至少一种式（I）的脂族 - 和/或芳基键合官能团的起始材料，其中R 1 = H，烷基或芳基，X = H或可以是 在催化反应期间由亚砜的亚磺酰基取代，n = 1至8的整数，在亚砜和/或硫化物的存在下被氧化，并且铁/铜的铁盐或氧化还原对的存在或 银/铜盐，通过氧化还原电位与NHE的氧化还原电位相反，由此亚砜或硫化物具有催化功能。 该方法允许以高选择性生产羰基化合物，特别是（多）醛和（聚）酮，由此将醇和羧酸，二聚产物和其它副产物的形成降低到最小或基本上被预防。 获得的最终产品可用作重要的中间体和最终产品。

    Process for sulfiding an additive-containing catalyst
    8.
    发明申请
    Process for sulfiding an additive-containing catalyst 有权
    用于硫化含添加剂的催化剂的方法

    公开(公告)号：US20020013223A1

    公开(公告)日：2002-01-31

    申请号：US09829638

    申请日：2001-04-10

    Inventor： Sonja Eijsbouts ,  Frans Lodewijk Plantenga ,  Pierre Dufresne ,  Franck Labruyere

    IPC: C10G045/00 ,  C10G045/04 ,  B01J027/043 ,  B01J027/04 ,  B01J027/047 ,  B01J027/049 ,  B01J027/051

    CPC classification number: B01J31/0254 ,  B01J23/85 ,  B01J27/188 ,  B01J31/0202 ,  B01J31/0205 ,  B01J31/0218 ,  B01J31/0237 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/705

    Abstract: The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40%, preferably less than about 35%, more preferably less than about 25%, most preferably less than about 15%, of the sulfur present in the sulfided catalyst is added with the organic liquid. The process of the present invention makes it possible to use additive-containing catalysts without loss of activity in units which cannot effect gas phase start-up or are required to carry out a pressure test. The organic liquid may be a hydrocarbon with a boiling range of about 150-500null C., preferably gasoline, white spirit, diesel, gas oil, mineral lube oil, or white oil. The step of contacting the catalyst with hydrogen and a sulfur-containing compound may take place in one step at a temperature of about 150-450null C. It may also take place in two steps, with the first step being performed at a temperature which is lower than that of the second step, with the first step being carried out at a temperature of about 100-250null C. and the second step at a temperature of about 150-450null C.

    Abstract translation: 本发明涉及一种硫化催化剂组合物的方法，该催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族氢化金属组分和一种有机添加剂，其中催化剂组合物首先与有机液体接触， 催化剂在气相中与氢气和含硫化合物接触，其中少于约40％，优选小于约35％，更优选小于约25％，最优选小于约15％的硫 存在于硫化催化剂中的有机液体中加入。 本发明的方法使得可以在不能实现气相启动或需要进行压力试验的单位中使用不含活性的添加剂的催化剂。 有机液体可以是沸点为约150-500℃的烃，优选汽油，白酒，柴油，瓦斯油，矿物润滑油或白油。 使催化剂与氢气和含硫化合物接触的步骤可以在约150-450℃的温度下在一个步骤中进行。它也可以在两个步骤中进行，第一步是在 低于第二步骤，第一步骤在约100-250℃的温度下进行，第二步在约150-450℃的温度下进行。

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