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    SUPERDEGAS- A PROCESS OF INTEGRATING SULFUR COLLECTION AND DEGASSING FOR ZERO EMISSION
    2.
    发明申请
    SUPERDEGAS- A PROCESS OF INTEGRATING SULFUR COLLECTION AND DEGASSING FOR ZERO EMISSION 审中-公开

    公开(公告)号：US20170088421A1

    公开(公告)日：2017-03-30

    申请号：US14870017

    申请日：2015-09-30

    Applicant: MAHIN RAMESHNI ,  STEPHEN L. SANTO

    Inventor： MAHIN RAMESHNI ,  STEPHEN L. SANTO

    IPC: C01B17/04 ,  B01J31/02 ,  B01D19/00

    CPC classification number: C01B17/0447 ,  B01D19/0042 ,  B01D19/0073 ,  B01J31/0271 ,  B01J2231/62 ,  B01J2531/002 ,  C01B17/0426

    Abstract: SuperDegas process refers to innovative process of the liquid sulfur collection and degassing which takes place in the underground container in a concrete pit or a carbon steel vessel located in the concrete pit. SuperDegas process consists of at least three compartments: (1) sulfur collection to agitate and create turbulent, higher velocity, and higher pressure in the liquid sulfur for more effective degassing by using vertical pumps; (2) consists of the proprietary air spargers and Morpholine catalyst for degassing. Morpholine catalyst degas the liquid sulfur 30 times faster than Quinoline or any other solvent with sparging air and within 1 hour residence time from 16-30 hours and to meet less than 10 ppmw of H2S in liquid sulfur. (3) The last compartment receives the degassed sulfur by overflow and transport through a pump or pumps to other facilities. An eductor will sweep vapor phase containing H2S, vaporized Morpholine with air where the pit vent can be sent to incineration or the reaction furnace. The tail gas stream from SRU can sweep the pit and the discharge shall be recycled to the tail gas unit, which ultimately zero emission can be achieved.

    Catalyst for desulfurization and deodorization of gasoline and method for preparation of the same and use thereof
    6.
    发明授权
    Catalyst for desulfurization and deodorization of gasoline and method for preparation of the same and use thereof 有权
    用于汽油脱硫除臭的催化剂及其制备方法及其应用

    公开(公告)号：US08501657B2

    公开(公告)日：2013-08-06

    申请号：US12933313

    申请日：2008-11-20

    Applicant: Can Li ,  Zongxuan Jiang ,  Yongna Zhang ,  Hongying Lv ,  Boyu Zhang

    Inventor： Can Li ,  Zongxuan Jiang ,  Yongna Zhang ,  Hongying Lv ,  Boyu Zhang

    IPC: B01J31/18 ,  C10L1/04 ,  C10G45/00 ,  C10G29/00 ,  C10G29/08

    CPC classification number: B01J31/1805 ,  B01J27/188 ,  B01J31/0239 ,  B01J2231/62 ,  C10G25/003 ,  C10G27/12

    Abstract: A catalyst for the desulfurization and deodorization of gasoline, which is expressed by the formula: QlBmHn[AxMyOz](1+m+n)−, where: Q denotes a quaternary ammonium cation consisting of R1R2R3R4N+, in which R1, R2, R3, and R4 each denotes independently a C1 to C20 saturated alkyl group, respectively, provided that at least one of R1, R2, R3, and R4 denotes a C4 to C20 saturated alkyl group; B denotes a metal cation of Na+ or/and K+; H denotes a hydrogen atom; A denotes a central atom of B, P, As, Si or Al; M denotes a coordinated atom of W or Mo; O denotes an oxygen atom; 1≦l≦10, 0≦m≦3, 0≦n≦3, l+m+n≦14, x=1 or 2, 9≦y≦18, 34≦z≦62, and l, m, n, y and z all are integers. A method of the desulfurization and deodorization of gasoline by using the catalyst comprises the steps of: mixing the catalyst and an aqueous solution of hydrogen peroxide, and then adding the gasoline to react them with stirring under conditions of 25 to 90° C. and 0.1 to 1 MPa for 10 to 180 min. An odorless gasoline can be obtained through settlement or centrifugation, and the catalyst is recovered.

    Abstract translation: 一种用于汽油脱硫除臭的催化剂，其由下式表示：QlBmHn [AxMyOz]（1 + m + n） - ，其中：Q表示由R1R2R3R4N +组成的季铵阳离子，其中R1，R2，R3， 并且R 4各自独立地表示C1〜C20饱和烷基，条件是R 1，R 2，R 3和R 4中的至少一个表示C 4至C 20饱和烷基; B表示Na +或/和K +的金属阳离子; H表示氢原子; A表示B，P，As，Si或Al的中心原子; M表示W或Mo的配位原子; O表示氧原子; 1 @ l @ 10，0 @ m @ 3，0 @ n @ 3，l + m + n @ 14，x = 1或2，9 @ y @ 18,34 @ z @ 62和l，m，n ，y和z都是整数。 通过使用催化剂对汽油进行脱硫除臭的方法包括以下步骤：将催化剂和过氧化氢水溶液混合，然后加入汽油使其在25〜90℃，0.1〜 至1MPa 10至180分钟。 可以通过沉降或离心获得无臭汽油，回收催化剂。

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