公开(公告)号：US09017923B2

公开(公告)日：2015-04-28

申请号：US14089371

申请日：2013-11-25

申请人： Shin-Etsu Chemical Co., Ltd.

发明人： Jun Hatakeyama

IPC分类号： C08F30/04 ,  G03F7/40 ,  G03F7/038 ,  G03F7/20

CPC分类号： G03F7/0382 ,  G03F7/0043

摘要： The invention provides a negative resist composition including, as a base resin, a polymer that contains at least a repeating unit “a” having a cyclopentadienyl complex and is represented by the following general formula (1). There can be a negative resist composition, especially a chemically amplified negative resist composition that has a higher resolution than conventional hydroxystyrene-based and novolak-based negative resist compositions, a good pattern configuration after exposure, and further excellent etching resistance, and a patterning process using the same.

摘要翻译： 本发明提供一种负型抗蚀剂组合物，其包含作为基础树脂的至少含有具有环戊二烯基络合物的重复单元“a”的聚合物，并且由以下通式（1）表示。 可以存在负性抗蚀剂组合物，特别是具有比常规的基于羟基苯乙烯和酚醛清漆的负性抗蚀剂组合物更高的分辨率，曝光后的良好图案构造和更好的耐蚀刻性的化学放大的负性抗蚀剂组合物和图案化工艺 使用相同

公开(公告)号：US20140100300A1

公开(公告)日：2014-04-10

申请号：US14103192

申请日：2013-12-11

申请人： FINA TECHNOLOGY, INC.

发明人： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC分类号： C08F30/04

CPC分类号： C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

摘要： Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

摘要翻译： 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。

公开(公告)号：US08372929B2

公开(公告)日：2013-02-12

申请号：US13059151

申请日：2009-07-17

申请人： Bjoern Fechner ,  Carsten Schaefer ,  Alexander Woerndle

发明人： Bjoern Fechner ,  Carsten Schaefer ,  Alexander Woerndle

IPC分类号： C08F118/02 ,  C08F30/04 ,  C08F12/30 ,  C08F220/68 ,  C08F228/06 ,  C08F226/06

CPC分类号： C08F220/26 ,  C08F212/08 ,  C08F220/18 ,  C08F226/06 ,  C08F2220/185 ,  C08F2220/1858 ,  C08F2220/1883 ,  C08F2220/1891 ,  C09J133/066 ,  C08F2220/308 ,  C08F2220/307

摘要： The invention relates to copolymers that can be obtained by the polymerization of monomers (A), (B), (C) and (D), where (A) is a monomer of formula (I) wherein A is C2-C4 alkylene and B is a C2-C4 alkylene different from A, R is hydrogen or methyl, m is a number between 1 and 500, and n is a number between 1 and 500, the sum of m+n being equal to between 2 and 1000; (B) is a monomer of formula (II) wherein D is C3 alkylene, R is hydrogen or methyl, and o is a number between 2 and 500; (C) is an ethylenically unsaturated monomer containing an aromatic group; and (D) is an ethylenically unsaturated monomer containing an alkyl radical.

摘要翻译： 本发明涉及可通过单体（A），（B），（C）和（D）的聚合获得的共聚物，其中（A）是式（I）的单体，其中A是C 2 -C 4亚烷基， B是不同于A的C 2 -C 4亚烷基，R是氢或甲基，m是1至500之间的数，n是1至500之间的数，m + n之和等于2和1000; （B）是式（II）的单体，其中D是C3亚烷基，R是氢或甲基，o是2和500之间的数; （C）是含有芳基的烯属不饱和单体; 和（D）是含有烷基的烯属不饱和单体。

公开(公告)号：US20120065676A1

公开(公告)日：2012-03-15

申请号：US13300906

申请日：2011-11-21

申请人： Ahmad R. Hadba ,  Brian Cuevas ,  Frank R. Schiretz ,  Joshua B. Stopek

发明人： Ahmad R. Hadba ,  Brian Cuevas ,  Frank R. Schiretz ,  Joshua B. Stopek

IPC分类号： A61B17/064 ,  C08F20/58 ,  C08F28/02 ,  C08F30/04

CPC分类号： A61L24/043 ,  A61B17/06166 ,  A61B17/064 ,  A61B2017/00898 ,  A61L17/10 ,  A61L31/041 ,  A61L2400/04 ,  C08F220/06 ,  C08F220/38 ,  C08F220/58 ,  C08L33/14 ,  Y10T428/2964 ,  Y10T428/2967 ,  Y10T428/2969 ,  C08L33/04 ,  C08L2666/02

摘要： The present disclosure relates to compositions comprising a copolymer that includes a first monomer and a second monomer that is different from the first monomer, wherein both the first and second monomer are selected from the group consisting of 3-sulfopropyl acrylate potassium salt, sodium acrylate, N-(tris(hydroxyl methyl)methyl)acrylamide, and 2-acrylamideo-2-methyl-1-propane sulfonic acid. The present disclosure further relates to methods for preparing the copolymer compositions and shaped articles comprising the copolymers.

摘要翻译： 本公开涉及包含共聚物的组合物，所述共聚物包括不同于第一单体的第一单体和第二单体，其中第一和第二单体都选自丙烯酸3-磺丙酯钾盐，丙烯酸钠， N-（三（羟基甲基）甲基）丙烯酰胺，和2-丙烯酸异丙基-2-甲基-1-丙磺酸。 本公开还涉及制备包含共聚物的共聚物组合物和成型制品的方法。

公开(公告)号：US20100184932A1

公开(公告)日：2010-07-22

申请号：US12750424

申请日：2010-03-30

申请人： Gerard Bidan ,  Bruno Jousselme ,  Rémi De Bettignies

发明人： Gerard Bidan ,  Bruno Jousselme ,  Rémi De Bettignies

IPC分类号： C08F30/04 ,  C07C245/20 ,  C25D5/48 ,  C25D7/12 ,  H01L29/12

CPC分类号： C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0085 ,  H01L51/0086 ,  Y02E10/549

摘要： Polymerizable diazonium salts having redox properties and absorption in the visible range, a process for preparing them and uses thereof are disclosed. The salts have the general formula: [XX+LnDdEm(N2+)p][(B−)p+x] in which: X is chosen from transition metals, preferably X is chosen from ruthenium (Ru), osmium (Os), iron (Fe), cobalt (Co) and iridium (Ir), x is an integer ranging from 1 to 5 inclusive, L is a ligand chosen from pyridine, bipyridine, terpyridine, phenanthroline and phenylpyridine groups, and mixtures thereof, n is an integer ranging from 1 to 5 inclusive, D is a saturated or unsaturated, C1-C5 alkyl spacer compound, d=0 or 1, E is an aromatic or polyaromatic spacer compound that can contain one or more heteroatoms, m is an integer ranging from 0 to 5 inclusive, p is an integer, and B is a counterion.

摘要翻译： 公开了具有氧化还原性和可见光吸收的可聚合重氮盐，其制备方法和用途。 该盐具有以下通式：[XX + LnDdEm（N2 +）p] [（B-）p + x]其中：X选自过渡金属，优选X选自钌（Ru），锇（Os） 铁（Fe），钴（Co）和铱（Ir），x是从1到5的整数，包括1和5，L是选自吡啶，联吡啶，三联吡啶，菲咯啉和苯基吡啶基团的配体，以及它们的混合物，n是 D为饱和或不饱和的C1-C5烷基间隔化合物，d = 0或1，E为可含有一个或多个杂原子的芳族或多芳族间隔体化合物，m为范围从 0〜5，p为整数，B为抗衡离子。

公开(公告)号：US07629424B2

公开(公告)日：2009-12-08

申请号：US11792739

申请日：2006-06-12

申请人： Mangala Malik ,  Joseph J Schwab

发明人： Mangala Malik ,  Joseph J Schwab

IPC分类号： C08F30/04

CPC分类号： C08J3/28 ,  C08F230/04

摘要： The present invention relates to metal-containing compositions with refractive indices of at least 1.5 comprising a metal-containing precursor unit (MU), a prepolymer unit (PU), and a catalyst or an initiator capable of inducing a combining reaction of ethylenically unsaturated functional groups of the metal-containing precursor unit and reactive functional groups of the prepolymer unit. In another embodiment, the composition comprises MU and a catalyst or initiator capable of inducing a combining reaction of the metal-containing precursor units. Both MU and PU contain additional functional groups, which may be selected to impart compatibility with each other and to produce optically clear films. The metal-containing compositions can be used to produce films or articles having a transmittance of at least 90% and index of refraction in the range of 1.5 to 1.8 in the 400-700 nm range of light and 1.5 to 2.4 in the 150-400 nm range of light.

摘要翻译： 本发明涉及具有至少1.5的折射率的含金属组合物，其包含含金属的前体单元（MU），预聚物单元（PU），以及能够诱导烯属不饱和官能团的组合反应的催化剂或引发剂 含金属的前体单元的基团和预聚物单元的反应性官能团。 在另一个实施方案中，组合物包含MU和能够诱导含金属的前体单元的组合反应的催化剂或引发剂。 MU和PU都包含另外的官能团，其可以被选择以赋予彼此的相容性并产生光学透明的膜。 含金属的组合物可用于生产具有至少90％的透光率和在400-700nm光范围内的1.5至1.8范围内的折射率和在150-400中的1.5至2.4的膜或制品 nm范围的光。

公开(公告)号：US20080241559A1

公开(公告)日：2008-10-02

申请号：US11898979

申请日：2007-09-18

申请人： Won Jae Joo ,  Chulhee Kim ,  Kwang Hee Lee ,  Tae Lim Choi

发明人： Won Jae Joo ,  Chulhee Kim ,  Kwang Hee Lee ,  Tae Lim Choi

IPC分类号： B32B15/08 ,  B05D1/02 ,  B05D1/04 ,  C08F30/04 ,  B32B27/28 ,  B05D1/40

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  C07F17/02 ,  C08G83/003 ,  G11C13/0009 ,  G11C13/0016 ,  H01L51/0083 ,  H01L51/0095 ,  H01L51/0591 ,  Y10T428/31663 ,  Y10T428/31678 ,  Y10T428/31688 ,  Y10T428/31855

摘要： Disclosed herein is a dendrimer, in which metallocene, which is an oxidation-reduction material, is located at a core, and a conjugated dendron is connected to the metallocene core by a linker compound, an organic active layer having the dendrimer, an organic memory device having the organic active layer and a method of manufacturing the organic active layer and the organic memory device. The organic memory device manufactured using a dendrimer having a metallocene core of example embodiments may have a shorter switching time, decreased operation voltage, decreased manufacturing cost and increased reliability, thereby realizing a highly-integrated large-capacity memory device.

摘要翻译： 本文公开了一种树枝状大分子，其中作为氧化还原材料的茂金属位于核心，并且共轭树突通过连接体化合物连接到茂金属核，具有树枝状聚合物的有机活性层，有机记忆 具有有机活性层的器件和制造有机活性层的方法和有机存储器件。 使用具有示例性实施方案的茂金属核的树枝状聚合物制造的有机存储器件可以具有更短的开关时间，降低的操作电压，降低的制造成本和增加的可靠性，从而实现高度集成的大容量存储器件。

公开(公告)号：US20080103273A1

公开(公告)日：2008-05-01

申请号：US11896675

申请日：2007-09-05

申请人： Benzhong Tang ,  Anjun Qin ,  Matthias Haeussler

发明人： Benzhong Tang ,  Anjun Qin ,  Matthias Haeussler

IPC分类号： C08F38/00 ,  C08F24/00 ,  C08F26/06 ,  C08F30/04

CPC分类号： C08F24/00 ,  C08F26/06 ,  C08F30/04

摘要： A process of synthesizing hyperbranched polytriazoles, linear and hyperbranched poly(aroyltriazoles) by Huisgen 1,3-dipolar cycloaddition. The polytriazoles were prepared by A2+B3 method to avoid self-polymerization during monomer preparation and storage. The polymers are light emissive and can be crosslinked to generate well-resolution photopatterns upon UV irradiation. White light emission patterns were observed with fluorescence microscopy. The high molecular weight poly(aroyltriazoles) (up to 26000 Da) are prepared in high yields (up to 92.0%) and with high regioselectivity (the ratio of 1,4- and 1,5-disubstituted 1,2,3-triazole is equal or larger than 9:1). The polycyclomerization is not moisture or oxygen sensitive and therefore, no special precautions are necessary before and during the reaction. All the polymers are processible, easily film-forming, and curable into thermosets by heat or irradiation. The hyperbranched polymers can act as fluorescent adhesive materials with large tensile strength.

摘要翻译： 通过Huisgen 1,3-偶极环加成合成超支化聚三唑，线性和超支化聚（芳酰基三唑）的方法。 聚三唑通过A 2 N + B 3 N 3方法制备，以避免单体制备和储存期间的自聚合。 聚合物是发光的并且可以交联以在UV照射时产生良好分辨率的光图案。 用荧光显微镜观察白光发射模式。 高分子量聚（芳基三唑）（高达26000Da）以高产率（高达92.0％）和高分辨率选择性（1,4和1,5-二取代的1,2,3-三唑的比例 等于或大于9：1）。 多重环化不是水分或氧气敏感的，因此在反应之前和期间都不需要特别的预防措施。 所有的聚合物都是可加工的，易成膜的，并且通过热或照射可固化成热固性材料。 超支化聚合物可以作为具有大拉伸强度的荧光粘合剂材料。

公开(公告)号：US07101942B2

公开(公告)日：2006-09-05

申请号：US10053460

申请日：2002-01-18

申请人： Norbert Moszner ,  Thomas Völkel ,  Volker Rheinberger ,  Ulrich Schubert

发明人： Norbert Moszner ,  Thomas Völkel ,  Volker Rheinberger ,  Ulrich Schubert

IPC分类号： C08F30/04

CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

摘要： Dental material containing a cluster according to the general formula [(M1)a(M2)bOc(OH)d(OR)e(L-Sp-Z)f] (I) in which M1, M2, independently of each other, stand in each case for a metal atom of the IIIrd or Vth main groups or the Ist to VIIIth sub-groups of the periodic table; R is an alkyl group with 1 to 6 carbon atoms; L is a co-ordinating group with 2 to 6 complexing centres; Sp is a spacer group or is absent; Z is a polymerizable group; c is a number from 1 to 30; d, e, independently of each other, are in each case a number from 1 to 30; f is a number from 2 to 30, any charge of the cluster (I) present being equalized by counterions.

摘要翻译： 含有根据通式[（M 1））的簇的牙科材料[（M 2））B O （OH）n（OR）e（L-Sp-Z）F（ⅰ）在（ⅰ）中 其中M 1，M 2，2彼此独立地代表IIIrd或Vth主族或第I至VIII族的金属原子 周期表; R是具有1至6个碳原子的烷基; L是一个有2到6个络心中心的协调小组; Sp是间隔基团或不存在; Z是可聚合基团; c是从1到30的数字; d，e彼此独立地在每种情况下为1至30的数; f是从2到30的数字，存在的群集（I）的任何费用由抵抗衡平衡。

公开(公告)号：US20050282949A1

公开(公告)日：2005-12-22

申请号：US11150300

申请日：2005-06-13

申请人： Romano Lima ,  Augusto Fabbri

发明人： Romano Lima ,  Augusto Fabbri

IPC分类号： C08F257/02 ,  C08F30/04

CPC分类号： C08F257/02 ,  C08F236/18

摘要： A process is described for the preparation of latices based on polychloroprene, comprising the polymerization of chloroprene in the presence of a first latex essentially consisting of polymeric particles produced in a first polymerization of a composition of monomers comprising (a) alpha-, beta-unsaturated carboxylic acids and/or derivatives thereof, (b) vinyl aromatic compounds, (c) conjugated dienes; said first latex having a content of alpha-, beta-unsaturated carboxylic acids, expressed as parts of alpha-, beta-unsaturated carboxylic acids per 100 grams of polymeric particles, ranging from 1 to 15%, thus obtaining a final latex, the solid particles of said final latex having an quantity of chloroprene ranging from 50 to 95% by weight, preferably from 80 to 95% by weight.

摘要翻译： 描述了一种用于制备基于聚氯丁二烯的胶乳的方法，包括在第一胶乳存在下聚合氯丁二烯，所述第一胶乳基本上由在单体组合物的第一次聚合中产生的聚合物颗粒组成，所述组合物包含（a）α-不饱和 羧酸和/或其衍生物，（b）乙烯基芳族化合物，（c）共轭二烯; 所述第一胶乳含有α-，β-不饱和羧酸，每100克聚合物颗粒表示为α-不饱和羧酸的一部分，范围为1至15％，从而获得最终胶乳，固体 所述最终胶乳的颗粒具有50至95重量％，优选80至95重量％的氯丁二烯。