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    Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins
    5.
    发明申请
    Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins 有权
    用于二烯化，共二聚和低聚烯烃的催化组合物

    公开(公告)号：US20030109766A1

    公开(公告)日：2003-06-12

    申请号：US09775556

    申请日：2001-02-05

    发明人： Dominique Commereuc ,  Dominique Le Pennec ,  Helene Olivier-Bourbigou

    IPC分类号： B01J027/186 ,  B01J031/00 ,  C07C005/25

    CPC分类号： C07C2/32 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/14 ,  B01J31/143 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2/26 ,  C07C2527/128 ,  C07C2531/22

    摘要： A catalytic composition comprising at least one nickel compound mixed or complexed with at least one tertiary phosphine or a phosphite carrying a functional group, at least partly dissolved in a non-aqueous medium with an ionic nature resulting from bringing at least one aluminum halide into contact with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide is useful for dimerizing, co-dimerizing and oligomerizing olefins. Functional group include, but are not limited to, an amine, a cyclic amine, a nitrogen-containing heterocycle, an ester, an acid, an alcohol, a quaternary ammonium, a quaternary phosphonium, a sulfonium, a sulfonate or a phosphonate group.

    摘要翻译： 一种催化组合物，其包含与至少一种叔膦或携带官能团的亚磷酸酯混合或络合的至少一种镍化合物，至少部分地溶解在具有离子性质的非水介质中，所述非水介质使至少一种卤化铝接触 与至少一种季铵卤化物和/或至少一种季卤化鏻可用于二烯化，共二聚和低聚烯烃。 官能团包括但不限于胺，环胺，含氮杂环，酯，酸，醇，季铵，季鏻，锍，磺酸盐或膦酸酯基。

    Composition of catalyst and solvent and catalysis processes using this composition
    6.
    发明申请
    Composition of catalyst and solvent and catalysis processes using this composition 有权
    使用该组合物的催化剂和溶剂的组成和催化方法

    公开(公告)号：US20030060359A1

    公开(公告)日：2003-03-27

    申请号：US10232837

    申请日：2002-09-03

    申请人： Institut Francais du Petrole

    发明人： Helene Olivier-Bourbigou ,  Dominique Commereuc ,  Olivia Martin ,  Lionel Magna ,  Emmanuel Pellier

    IPC分类号： B01J031/00

    CPC分类号： B01J31/0281 ,  B01J31/0225 ,  B01J31/0288 ,  B01J31/0289 ,  B01J2231/20 ,  B01J2231/323 ,  B01J2231/52 ,  C07C2/26 ,  C07C2/58 ,  C07C2531/025

    摘要： A composition defined: either as comprising at least one Broensted acid, designated HB, dissolved in a liquid medium with an ionic nature of general formula QnullAnull, in which Qnull represents an organic cation and Anull represents an anion that is different from B, or as resulting from dissolving at least one Broensted acid, designated HB, in a non-aqueous liquid medium with an ionic nature of general formula QnullAnull, in which Qnull represents an organic cation and Anull represents an anion that is identical to the anion B, can be used as a catalyst and solvent in acid catalysis processes, in particular in the alkylation of aromatic hydrocarbons, the oligomerization of olefins, the dimerization of isobutene, the alkylation of olefins by isoparaffins, the isomerization of n-paraffins into isoparaffins, the isomerization of n-olefins into iso-olefins, the isomerization of the double bond of an olefin and the purification of an olefin mixture that contains branched alpha olefins as impurities.

    摘要翻译： 一种组合物，其定义为：包含至少一种Broensted酸，称为HB，溶解在具有通式Q + A-的离子性质的液体介质中，其中Q +表示有机阳离子，A-表示不同于 B或由至少一种名为HB的Broensted酸溶解在具有通式Q + A-的离子性质的非水性液体介质中，其中Q +表示有机阳离子，A-表示阴离子， 与阴离子B相同，可用作酸催化方法中的催化剂和溶剂，特别是芳烃的烷基化，烯烃的低聚，异丁烯的二聚，异链烷烃的烯烃的烷基化， 链烷烃变成异链烷烃，正烯烃异构化成异烯烃，烯烃双键异构化和含有支链α-烯烃作为杂质的烯烃混合物的纯化。

    Process for linear alpha-olefin production: eliminating wax precipitation
    7.
    发明授权
    Process for linear alpha-olefin production: eliminating wax precipitation 失效
    线性α-烯烃生产方法：消除蜡沉淀

    公开(公告)号：US5523508A

    公开(公告)日：1996-06-04

    申请号：US366153

    申请日：1994-12-29

    申请人： Mark A. Krawczyk ,  Richard E. Marinangeli ,  R. Joe Lawson

    发明人： Mark A. Krawczyk ,  Richard E. Marinangeli ,  R. Joe Lawson

    IPC分类号： C07C2/08 ,  C07C2/26 ,  C07C2/24

    CPC分类号： C07C2/26 ,  C07C2/08 ,  C07C2531/02

    摘要： Linear alpha-olefin formation via oligomerization of ethylene using transition metal catalysis leads to a Schultz-Flory distribution of oligomers. At modest temperatures formation of heavy oligomers which are waxy solids only partly soluble in the LAO product mix causes reactor plugging and curtailing the time of continuous runs. Recycling a portion of a lighter oligomeric fraction obviates this problem and permits runs uninterrupted by solids formation.

    摘要翻译： 使用过渡金属催化通过乙烯低聚形成线性α-烯烃导致低聚物的Schultz-Flory分布。 在适度的温度下，仅仅部分溶解在LAO产物混合物中的蜡状固体的重低聚物的形成导致反应器堵塞并且缩短连续运行的时间。 回收较轻的低聚部分的一部分消除了这个问题，并允许不间断地通过固体形成运行。

    Polymerization process
    10.
    发明授权
    Polymerization process 失效
    聚合工艺

    公开(公告)号：US3842134A

    公开(公告)日：1974-10-15

    申请号：US26151472

    申请日：1972-06-09

    申请人： BRAY OIL CO

    发明人： PRATT R

    IPC分类号： C07C2/26 ,  C07C3/18

    CPC分类号： C07C2/26 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2531/02 ,  C07C2531/26

    摘要： 1. A PROCESS FOR THE CNTROLLED POLYMERIZATION OF LINEAR ALPHA OLEFINES CONTAINING FROM 6 TO 12 CARBON ATOMS INTO POLYMER OILS CONTAINING HIGH PERCENTAGES OF TRIMERIC ANC TETRAMERIC PRODUCTS POSSESSING LOW POUR POINTS, LOW VISCOSITIES, HIGH VISCOSITY INDEXES, AND HIGH FLASH POINTS, SAID PRODUCTS BEING SUITABLE FOR THE FORMULATION OF LIGHT LUBRICATING OILS AND HYDRAULIC FLUIDS, SAID PROCESS COMPRISING THE FOLLOWING STEPS: (A) REACTING A LINEAR ALPHA OLEFIN OF 6 TO 12 CARBON ATOMS AT A TEMPERATURE BETWEEN 180* AND 250*F., WITH A CATALYST COMPRISING A MIXTURE OF ANHYDROUS ALUMINUM CHLORIDE WITH A MONONITROALKANE HAVING ONE TO THREE CARBON ATOMS IN A RATIO OF 1 YO 6 MOLS OF MONONITROALKANE TO EACH MOL OF ALUMINUM CHLORIDE, AND (B) REMOVING CATALYST FROM THE POLYMER OIL PRODUCT AND FRACTIONATING THE OIL TO RECOVER THEREFROM AN OIL FRACTION COMPOSED OF THE DESIRED POLYMERS OF THE ALPHA OLEFINE STARTING MATERIAL.