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    Oxidative coupling of aromatic methyl groups
    1.
    发明授权
    Oxidative coupling of aromatic methyl groups 失效
    芳香族甲基的氧化偶联

    公开(公告)号：US4400567A

    公开(公告)日：1983-08-23

    申请号：US419751

    申请日：1982-09-20

    申请人： Theodorus M. Wortel ,  Jan H. Schutten

    发明人： Theodorus M. Wortel ,  Jan H. Schutten

    IPC分类号： C07C2/84 ,  B01J31/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/82 ,  C07C15/18 ,  C07C67/00 ,  C07C3/14 ,  C07C3/12

    CPC分类号： C07C2/82

    摘要： Highly selective oxidative coupling of aromatic methyl groups, such as coupling toluene to DPE, is effected under mild, liquid phase conditions with a peroxodisulfate without expensive metal ion catalysts, in presence of substantial amounts, preferably equimolar, of methyl, ethyl or benzyl substituted quaternary ammonium salts. A continuous process is possible by electrolytic regeneration of the spent oxidant.

    摘要翻译： 芳香族甲基的高度选择性氧化偶联，例如将甲苯偶联至DPE，在温和的液相条件下与无需贵金属离子催化剂的过二硫酸盐在大量（优选等摩尔）甲基，乙基或苄基取代的季铵盐存在下进行 铵盐。 通过废氧化剂的电解再生可以进行连续的处理。

    Maintaining effective molar ratio of HF to metal pentafluoride in a hydrocarbon conversion process
    2.
    发明授权
    Maintaining effective molar ratio of HF to metal pentafluoride in a hydrocarbon conversion process 失效
    在烃转化过程中维持HF与金属五氟化物的有效摩尔比

    公开(公告)号：US4065381A

    公开(公告)日：1977-12-27

    申请号：US758053

    申请日：1976-12-29

    申请人： Geoffrey R. Say ,  William C. Baird, Jr. ,  Paul W. Kamienski

    发明人： Geoffrey R. Say ,  William C. Baird, Jr. ,  Paul W. Kamienski

    IPC分类号： B01J27/12 ,  C07C5/22 ,  C07C7/10 ,  C07C5/28 ,  C07C3/12 ,  C07C9/00 ,  C10G35/06

    CPC分类号： C07C7/10 ,  B01J27/12 ,  C07C5/2253 ,  C07C2527/1206 ,  C07C2527/135

    摘要： A hydrocarbon phase separated from a hydrocarbon conversion process is solvent extracted with anhydrous liquid HF to separate metal pentafluoride which is carried over into the hydrocarbon phase. The extract of HF and metal fluoride is then combined with the catalyst phase (HF and metal pentafluoride) and stripped with hydrogen to reduce the molar ratio of HF to metal pentafluoride to the level that HF + metal pentafluoride catalyst is utilized in the hydrocarbon conversion process. The metal pentafluoride is TaF.sub.5 and/or NbF.sub.5 and the hydrocarbon conversion may involve isomerization, alkylation with olefins and reactions of a paraffin with another paraffin.

    摘要翻译： 从烃转化方法分离的烃相用无水液体HF溶剂萃取以分离携带到烃相中的五氟化金。 然后将HF和金属氟化物的提取物与催化剂相（HF和五金属金属）合并，并用氢气汽提，以将HF与五氟化金的摩尔比降低至在烃转化过程中使用HF +五金属五氟化物催化剂的水平 。 五氟化金属是TaF 5和/或NbF 5，并且烃转化可以涉及异构化，用烯烃烷基化和石蜡与另一种石蜡的反应。

    Detergent alkylation reactor
    3.
    发明授权
    Detergent alkylation reactor 失效
    洗涤剂烷基化反应器

    公开(公告)号：US4134734A

    公开(公告)日：1979-01-16

    申请号：US858040

    申请日：1977-12-06

    申请人： George R. Winter, III

    发明人： George R. Winter, III

    IPC分类号： B01J4/00 ,  B01J14/00 ,  B01J8/00 ,  B01J1/00 ,  C07C3/12

    CPC分类号： B01J14/00 ,  B01J4/001 ,  Y10S585/922 ,  Y10S585/926

    摘要： A unitary reactor system for the alkylation of benzene with olefins. The hydrocarbon reactants are sprayed horizontally from a plurality of openings in a number of vertical conduits which extend upward into a lower portion of the vessel. The conduits are surrounded by a vertical reaction tube having a circular catalyst inlet at its bottom end and which contains a mixing means located above the conduits. A hydrocarbon phase is retained in the upper portion of the vessel and an acid phase surrounds the reaction tube, with the interface of the two liquid phases being maintained above the open upper end of the reaction tube.

    摘要翻译： 用烯烃烷基化苯的单一反应器系统。 烃反应物从多个垂直管道中的多个开口水平喷射，其向上延伸到容器的下部。 导管被垂直反应管围绕，该反应管在其底端具有圆形催化剂入口，并且包含位于导管上方的混合装置。 烃相保留在容器的上部，并且酸相包围反应管，两个液相的界面保持在反应管的敞开的上端上方。

    Means for controlling a cascade system
    4.
    发明授权
    Means for controlling a cascade system 失效
    控制系统的手段

    公开(公告)号：US3843327A

    公开(公告)日：1974-10-22

    申请号：US26380272

    申请日：1972-06-19

    申请人： TEXACO INC

    发明人： HOPKINS W ,  EDWARDS R

    IPC分类号： B01J19/00 ,  C07C2/62 ,  C07C3/12

    CPC分类号： C07C2/62 ,  B01J19/0006 ,  Y10T137/0324 ,  Y10T137/7303 ,  Y10T137/86163 ,  Y10T137/86196

    摘要： 1. APPARATUS FOR CONTROLLING THE LEVELS OF A LIQUID IN A PLURALITY OF VESSELS IN A SYSTEM RECEIVING AND DISCHARGING THE LIQUID, SAID VESSELS BEING CONNECTED IN SERIES BY MEANS FOR CONVEYING THE LIQUID FROM VESSEL TO VESSEL, COMPRISING A PAIR OF CONTROL DEVICES, ONE CONTROL DEVICE IS CONNECTED TO A FIRST VESSEL OF THE PLURALITY OF VESSELS AND IS RESPONSIVE TO A FIRST CONTROL SIGNAL TO CONTROL THE FLOW RATE OF THE LIQUID BEING RECEIVED BY SYSTEM AND ENTERING THE FIRST VESSEL, THE OTHER CONTROL DEVICE IS CONNECTED TO A LAST VESSEL OF THE PLURALITY OF VESSELS AND IS RESPONSIVE TO A SECOND CONTROL SIGNAL TO CONTROL THE LIQUID LEAVING THE LAST VESSEL AND BEING DISCHARGED FROM THE SYSTEM, MEANS CONNECTED TO EACH VESSEL FOR SENSING THE LIQUID LEVEL IN THE VESSEL AND PROVIDING A LIQUID SIGNAL CORRESPONDING THERETO, MEANS CONNECTED TO THE ONE CONTROL DEVICE TO AFFECT THE FLOW RATE OF THE LIQUID, BEING RECEIVED BY THE SYSTEM AND ENTERING THE FIRST VESSEL, MEANS CONNECTED TO EACH CONVEYING MEANS FOR SENSING THE FLOW RATES OF THE LIQUID MOVING BETWEEN VESSELS AND PROVIDING FLOW RATE SIGNALS CORRESPONDING THERETO, MEANS CONNECTED TO EACH CONVEYING MEANS AND TO THE FLOW RATE SENSING MEANS FOR AFFECTING THE FLOW RATES OF THE LIQUID BETWEEN VESSELS IN ACCORDANCE
    WITH COMMAND SIGNALS AND THE FLOW RATE SIGNALS, AND CIRCUIT MEANS CONNECTED TO THE FIRST CONTROL SIGNAL MEANS, TO THE LIQUID LEVEL SENSING MEANS, TO THE OTHER CONTROL DEVICE AND TO THE FLOW RATE AFFECTING MEANS FOR PROVIDING THE SECOND CONTROL SIGNAL TO THE OTHER CONTROL DEVICE IN ACCORDANCE WITH THE FIRST CONTROL SIGNAL AND AT LAEST ONE LIQUID LEVEL SIGNAL AND FOR PROVIDING THE COMMAND SIGNALS TO THE FLOW RATE AFFECTING MEANS IN ACCORDANCE WITH THE FIRST CONTROL SIGNAL AND AT LEAST ONE LIQUID LEVEL SIGNAL SO AS TO CONTROL THE LIQUID LEVELS IN THE PLURALITY OF VESSELS.

    Purification of hf catalyst in alkylation process
    5.
    发明授权
    Purification of hf catalyst in alkylation process 失效

    公开(公告)号：US3749753A

    公开(公告)日：1973-07-31

    申请号：US3749753D

    申请日：1971-04-15

    申请人： PHILLIPS PETROLEUM CO

    发明人： SKRABA F

    IPC分类号： C07C2/62 ,  C07C3/12 ,  C07C3/54

    CPC分类号： C07C2/62 ,  C07C2527/1206

    摘要： OLEFINS AND ISOPARAFFINS ARE ALKYLATED IN THE PRESENCE OF AN HF CATALYST. THE REACTOR EFFLUENT IS PASSED TO A SETTLING ZONE. THE HYDROCARBON PHASE IS FRACTIONATED TO RECOVER AN ALKYLATE PRODUCT. THE ACID PHASE IS RECYCLED TO THE REACTOR. A PORTION OF THE RECYCLED ACID IS PASSED TO A PURIFICATION COLUMN FOR REMOVAL OF ACID SOLUBLE OIL. STRIPPING VAPOR IS INTRODUCED INTO THE PURIFICATION COLUMN BOTH ABOVE AND BELOW THE SURFACE OF SAID SOLUBLE OIL ACCUMULATED THEREIN.

    Alkylation apparatus
    10.
    发明授权
    Alkylation apparatus 失效
    碱性装置

    公开(公告)号：US3867103A

    公开(公告)日：1975-02-18

    申请号：US37354473

    申请日：1973-06-25

    申请人： UNIVERSAL OIL PROD CO

    发明人： BONEY WILLIAM G ,  KUCHAR PAUL J

    IPC分类号： B01J14/00 ,  B01J19/24 ,  C07C2/62 ,  B01J1/00 ,  C07C3/12 ,  C07C3/54

    CPC分类号： B01J14/00 ,  B01J19/24 ,  B01J2219/00058 ,  B01J2219/0011 ,  B01J2219/00162 ,  B01J2219/00164 ,  B01J2219/00182 ,  C07C2/62

    摘要： An apparatus for the catalytic conversion of a hydrocarbon stream with a mineral acid catalyst comprising a vessel divided into an upper and lower chamber by an imperforate plate. The imperforate plate has a plurality of standpipe means connected thereto whereby hydrocarbon can pass into the upper chamber from hydrocarbon inlet means located in the lower chamber. A perforated plate is located in the upper chamber above the imperforate plate having flow guide conduits axially aligned above each of the standpipe means. A catalyst inlet means is located intermediate the imperforate and perforate plates and an emulsion outlet is located in the upper chamber. The flow guide conduits serve to promote eduction of acid-catalyst into the flow guide conduits by a high velocity hydrocarbon stream emitted from openings in said standpipe means, and to contain and confine the hydrocarbon stream and prevent contact of a resulting acidhydrocarbon emulsion with previously formed emulsion until the hydrocarbons and acid are thoroughly mixed and the hydrocarbons at least partially reacted.

    摘要翻译： 一种用无机酸催化剂催化转化烃流的装置，其包括通过无孔板分成上室和下室的容器。 无孔板具有连接到其上的多个立管装置，由此烃可以从位于下室中的烃入口装置进入上室。 多孔板位于无孔板上方的上室中，其具有在每个竖管装置上轴向对准的流动引导导管。 催化剂入口装置位于无孔和穿孔板的中间，并且乳液出口位于上室中。 流动引导管道用于通过从所述立管装置中的开口排出的高速烃流促进酸催化剂进入流动导管，并且包含并限制烃流并防止所得酸 - 烃乳液与 预先形成的乳液，直到烃和酸被充分混合并且烃至少部分地反应。