摘要:
The invention relates to the field of olefin oligomerization to obtain liner α-olefins, particularly to a method of separating olefin oligomerization products using an evaporator. The invention includes two embodiments of the method of separating the oligomerization reaction product streams. In accordance with the first embodiment of the invention, the oligomerization reaction product stream after the step of isolating an initial olefin is fed into an evaporator to the step of separating the oligomerization reaction product steam. In accordance with the second embodiment of the invention, the oligomerization reaction product stream after the step of isolating the initial olefin is separated into two streams, the first part of which is fed into the separation column, and the second part is fed into the evaporator. The invention allows to minimize a quantity of technological equipment contaminated by the by-product polymer.
摘要:
A process to produce 1-octene and 1-decene includes (a) separating a composition containing an oligomer product—which contains from 15 to 80 mol % C6 olefins, from 20 to 80 mol % C8 olefins, and from 5 to 20 mol % C10+ olefins—into a first oligomer composition containing C6 alkanes and at least 85 mol % C6 olefins (e.g., 1-hexene), a second oligomer composition containing at least 85 mol % C8 olefins (e.g., 1-octene), and a heavies stream containing C10+ olefins, then (b) contacting a metathesis catalyst system with the first oligomer composition to form a first composition comprising C10 linear internal olefins, (c) contacting the C10 linear internal olefins with an isomerization hydrofunctionalization catalyst system to form a second composition containing a functionalized alkane, (d) retro-hydrofunctionalizing the functionalized alkane to form a third composition containing 1-decene, and (e) purifying the third composition to isolate a fourth composition containing at least 90 mol % 1-decene. Processes to produce 1-hexene and 1-decene also are described, as well as related manufacturing systems.
摘要:
The present invention relates to a ligand compound, a catalyst system for olefin oligomerization and a method for oligomerizing an olefin using same. The catalyst system for olefin oligomerization according to the present invention exhibits high selectivity to 1-hexene or 1-octene while having excellent catalytic activity, thus enabling more efficient preparation of alpha-olefins.
摘要:
The present disclosure relates to a ligand compound, a catalyst system for oligomerization, and a method for olefin oligomerization using the same. The catalyst system for oligomerization using the ligand compound according to the present disclosure has excellent catalytic activity, exhibits high selectivity to 1-hexene and 1-octene, and greatly reduces the production of the by-products, thereby enabling efficient preparation of alpha-olefin.
摘要:
The present invention relates to a ligand compound, a catalyst system for olefin oligomerization, and a method for oligomerizing olefins using the same. The ligand compound according to the present invention has a structure in which a substituent is substituted in the trans form, and thereby when used for olefin oligomerization, the activity of the catalyst used and the selectivity of 1-hexene and 1-octene can be increased.
摘要:
The present invention relates to a ligand compound, a catalyst system for olefin oligomerization and a method for oligomerizing an olefin using same. The catalyst system for olefin oligomerization according to the present invention exhibits high selectivity to 1-hexene or 1-octene while having excellent catalytic activity, thus enabling more efficient preparation of alpha-olefins.
摘要:
An object of the present invention is to provide a method for efficiently producing an α-olefin low polymer at a high α-olefin low polymer selectivity and a high α-olefin low polymer yield with suppressing the deterioration of catalytic activity with time, and the invention relates to a method for producing an α-olefin low polymer, which comprises performing a low polymerization reaction of an α-olefin in the presence of a catalyst containing a chlorine atom-containing compound (d) and a reaction solvent, wherein the chlorine atom-containing compound (d) that are at least two compounds having specific chlorine atom elimination rate is supplied in predetermined ratio.
摘要:
The object of the present invention is to provide a production method for a polyolefin, in which catalyst activity is improved, and a polyolefin such as a linear low density polyethylene can advantageously be industrially produced. The present invention relates to a production method for a polyolefin, in which in producing a polyolefin by the polymerization reaction of an olefin using a catalyst, an organohalide is present in the reaction system in an amount of from 0.05 to 10 ppm by weight in terms of the halogen atom as a concentration in a raw material olefin, and 1-hexene for linear low density polyethylene production raw material, containing an organohalide in an amount of from 0.05 to 10 ppm by weight in terms of the halogen atom.
摘要:
Processes for the production of alpha-olefins, including dimerization and isomerization of olefins using a cobalt catalyst complex are provided herein. The olefins so produced are useful as monomers in further polymerization reactions and are useful as chemical intermediates.
摘要:
A process for the trimerisation of olefins is disclosed, comprising contacting a monomeric olefin or mixture of olefins under trimerisation conditions with a catalyst which comprises (a) a source of chromium, molybdenum or tungsten (b) a ligand containing at least one phosphorus, arsenic or antimony atom bound to at least one hydrocarbyl or heterohydrocarbyl group having a polar substituent, but excluding the case where all such polar substituents are phosphane, arsane or stibana groups; and optionally (c) an activator.