Selective 1-hexene/1-octene production with 1-decene

    公开(公告)号:US11498889B1

    公开(公告)日:2022-11-15

    申请号:US17471278

    申请日:2021-09-10

    摘要: A process to produce 1-octene and 1-decene includes (a) separating a composition containing an oligomer product—which contains from 15 to 80 mol % C6 olefins, from 20 to 80 mol % C8 olefins, and from 5 to 20 mol % C10+ olefins—into a first oligomer composition containing C6 alkanes and at least 85 mol % C6 olefins (e.g., 1-hexene), a second oligomer composition containing at least 85 mol % C8 olefins (e.g., 1-octene), and a heavies stream containing C10+ olefins, then (b) contacting a metathesis catalyst system with the first oligomer composition to form a first composition comprising C10 linear internal olefins, (c) contacting the C10 linear internal olefins with an isomerization hydrofunctionalization catalyst system to form a second composition containing a functionalized alkane, (d) retro-hydrofunctionalizing the functionalized alkane to form a third composition containing 1-decene, and (e) purifying the third composition to isolate a fourth composition containing at least 90 mol % 1-decene. Processes to produce 1-hexene and 1-decene also are described, as well as related manufacturing systems.

    PRODUCTION METHOD OF POLYOLEFIN, POLYOLEFIN AND 1-HEXENE FOR LINEAR LOW DENSITY POLYETHYLENE PRODUCTION RAW MATERIAL
    8.
    发明申请
    PRODUCTION METHOD OF POLYOLEFIN, POLYOLEFIN AND 1-HEXENE FOR LINEAR LOW DENSITY POLYETHYLENE PRODUCTION RAW MATERIAL 有权
    线性低密度聚乙烯生产原料的聚烯烃,聚烯烃和1-HEXENE的生产方法

    公开(公告)号:US20100331503A1

    公开(公告)日:2010-12-30

    申请号:US12521467

    申请日:2007-11-09

    摘要: The object of the present invention is to provide a production method for a polyolefin, in which catalyst activity is improved, and a polyolefin such as a linear low density polyethylene can advantageously be industrially produced. The present invention relates to a production method for a polyolefin, in which in producing a polyolefin by the polymerization reaction of an olefin using a catalyst, an organohalide is present in the reaction system in an amount of from 0.05 to 10 ppm by weight in terms of the halogen atom as a concentration in a raw material olefin, and 1-hexene for linear low density polyethylene production raw material, containing an organohalide in an amount of from 0.05 to 10 ppm by weight in terms of the halogen atom.

    摘要翻译: 本发明的目的是提供一种提高催化剂活性的聚烯烃的制造方法,可以有利地在工业上制造线性低密度聚乙烯等聚烯烃。 聚烯烃的制造方法技术领域本发明涉及聚烯烃的制造方法,其中通过使用催化剂的烯烃的聚合反应制造聚烯烃中,有机卤化物的含量相对于反应体系中的0.05〜10重量ppm 的卤素原子作为原料烯烃中的浓度,以及用于线性低密度聚乙烯生产原料的1-己烯,其含有以卤素原子计为0.05至10重量ppm的有机卤化物。