摘要:
The present disclosure relates to molybdenum and/or tungsten complexes, catalyst systems including molybdenum and/or tungsten complexes, and polymerization processes to produce polyalkenamers such as polypentenamers and polycyclooctenamers.
摘要:
The solid titanium catalyst component (I) of the present invention contains titanium, magnesium, halogen, and a cyclic multiple-ester-group-containing compound (a) represented by the following formula (1).
摘要:
To provide a solid catalyst component for olefin polymerization having a small amount of fine powder. A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an internal electron donor. The solid catalyst component has an absolute difference in binding energy of 73.50 to 75.35 eV between a peak (1) with the binding energy of 457.00 to 459.00 eV and a peak (2) with the binding energy of 532.50 to 534.50 eV. The peak (1) and the peak (2) are within peak components measured by X-ray photoelectron spectroscopy, the peak (1) is obtained by waveform separation of peaks assigned to the 2p orbitals of the titanium atom, and the peak (2) is obtained by waveform separation of peaks assigned to the is orbital of an oxygen atom.
摘要:
A modified Ziegler-Natta procatalyst that is a product mixture of modifying an initial Ziegler-Natta procatalyst with a molecular (pro)catalyst, and optionally an activator, the modifying occurring before activating the modified Ziegler-Natta procatalyst with an activator and before contacting the modified Ziegler-Natta procatalyst with a polymerizable olefin. Also, a modified catalyst system prepared therefrom, methods of preparing the modified Ziegler-Natta procatalyst and the modified catalyst system, a method of polymerizing an olefin using the modified catalyst system, and a polyolefin product made thereby.
摘要:
The instant invention provides a polyolefin composition suitable for sealant applications, sealant compositions, method of producing the same, and films and multilayer structures made therefrom. The polyolefin composition suitable for sealant applications according to the present invention comprises: an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 110, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.0; a density in the range of from 0.908 to 0.922 g/cm3, a melt index (I2 at 190° C./2.16 kg) in the range of from 0.5 to 5.0 g/10 minutes, a molecular weight distribution (defined as the weight average molecular weight divided by the number average molecular weight, Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second, determined at 190° C., in the range of from 5 to 50.
摘要:
The instant invention provides an ethylene/alpha-olefin interpolymer composition suitable for blown film applications, and blown films made therefrom. The ethylene/alpha-olefin interpolymer composition suitable for blown film applications according to the present invention comprises greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.910 to 0.918 g/cm3, a melt index I2 in the range of from 0.5 to 1.1 g/10 minutes, a melt flow ratio I10/I2 in the range of from 8 to 10, a melt strength in the range of from 3 to 6 cN, a highest temperature fraction in the range of from 11 to 14 percent determined by CEF, a highest peak temperature fraction by CEF in range of from 96 to 100° C., and a lowest temperature fraction from CEF in the range of from 2 to 5 percent, and a DSC heat curve having three melting peaks with a highest temperature melting peak in the range of from 120 to 124° C., a crystallinity in the range of from 40 to 50 percent.
摘要:
A multiblock copolymer, obtainable by copolymerization of a conjugated diene compound and a non-conjugated olefin, wherein: a structure of the multiblock copolymer includes A-(B-A)x and/or B-(A-B)x, wherein “A” represents a block portion constituted of monomer units of a non-conjugated olefin, “B” represents a block portion constituted of monomer units of a conjugated diene compound, and “x” represents an integer ≧1; content of the non-conjugated olefin portion is ≦30 mass %; and storage modulus G′ at 130° C., measured by rubber process analysis using a rubber process analyzer, i.e. RPA, according to ASTM D6204, is ≧20 kPa. It is possible to obtain vulcanized rubber and thus a tire having high fracture resistance and high weather resistance from the multiblock copolymer and a rubber composition derived therefrom.
摘要:
The present invention relates to a carriered hybrid vanadium-chromium-based catalyst, characterized in the catalyst is carriered on a porous inorganic carrier and a V active site and an organic Cr active site are present on the porous inorganic carrier at the same time. The present invention further relates to a process for producing a carriered hybrid vanadium-chromium-based catalyst. The catalyst of the present invention can be used for producing ethylene homopolymers and ethylene/α-olefin copolymers. The hybrid vanadium-chromium-based catalyst can have high activity and produce polyethylene polymers having the properties of broad molecular weight distribution (Part of the products are bimodal distribution) and excellent α-olefin copolymerization characteristic.
摘要:
Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.
摘要:
In a first aspect, the present invention concerns a kit for a polymerisable composition comprising a portion A constituted by a composition comprising at least one monomer (a1) that is reactive towards a cationic species (b) or a Lewis or Brönsted acid species, and at least one co-initiator, and a portion B comprising at least one cationic salt (e) selected from the salts with formula S1, S3, and S4 shown and defined in claim 1. In a second aspect, the present invention concerns a method of producing a coating or a composite material starting from polymerisable composition comprising at least one salt (e) selected from the salts with formula S1, S2, S3, and S4 shown and defined in claim 10, said composition being polymerised without adding external heat thereto.