公开(公告)号：US20190106516A1

公开(公告)日：2019-04-11

申请号：US16088610

申请日：2017-10-11

Applicant: LG Chem, Ltd.

Inventor： Jong Woo Park ,  Hye Kyung Lee ,  Byung Seok Kim ,  Sang Jin Jeon ,  Jae Youp Cheong ,  Hee Kwang Park

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F2/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2420/01 ,  C08F4/65927 ,  C08F2500/12

Abstract: The present invention relates to a metallocene supported catalyst including a novel single metallocene compound having excellent polymerization activity, and a process for producing a polypropylene having excellent processability and broad molecular eight distribution using the same.

公开(公告)号：US10035906B2

公开(公告)日：2018-07-31

申请号：US15332202

申请日：2016-10-24

Applicant: NOVA Chemicals (International) S.A.

Inventor： Tieqi Li ,  XiaoChuan Wang ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC: C08F210/16 ,  C08L23/08 ,  C08J5/00 ,  C08F2/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/20 ,  B29C41/04 ,  B32B7/12 ,  B32B27/08 ,  B32B27/34 ,  B29K23/00 ,  B29K105/00 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06 ,  C08F2/42 ,  C08F2500/07

Abstract: This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal ≥3.0 ppm; ≥0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US20180155470A1

公开(公告)日：2018-06-07

申请号：US15368139

申请日：2016-12-02

Applicant: Lion Copolymer Geismar, LLC

Inventor： Willie Burton ,  Thomas Toups

IPC: C08F110/14

CPC classification number: C08F110/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F2420/01 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2230/02 ,  C08F10/02 ,  C08F4/65927 ,  C08F2500/17

Abstract: Herein discussed is a method of producing a polyolefin blend, comprising providing a catalyst system comprising a first catalyst, a second catalyst, a first co-catalyst, a second co-catalyst, and a third co-catalyst; polymerizing at least one monomer in a single step; obtaining the polyolefin blend having a Kinematic viscosity (Kv) of 6 to 1000 cSt at 100 degrees C., wherein the Kv is adjusted by varying the ratio of the first catalyst to the second catalyst without mixing separately-synthesized polymers.

公开(公告)号：US09879106B2

公开(公告)日：2018-01-30

申请号：US15117816

申请日：2015-02-10

Applicant: Univation Technologies, LLC

Inventor： Francis C. Rix ,  Ching-Tai Lue ,  Timothy M. Boller ,  Garth R. Giesbrecht ,  C. Jeff Harlan

IPC: C08F210/16 ,  C08F4/64 ,  C07F17/00 ,  C08F210/02 ,  C08F4/76 ,  C08F4/659 ,  C08J5/18 ,  C08F2/34 ,  C08L23/08 ,  C08F210/14 ,  C08F210/08 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F2/00 ,  C08F2/34 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F2410/02 ,  C08F2420/00 ,  C08F2420/01 ,  C08F2500/01 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/03

Abstract: Catalyst systems and methods for making and using the same are described. A method includes selecting a catalyst blend using a blend polydispersity index (bPDI) map. The polydispersity map is generated by generating a number of polymers for at least two catalysts. Each polymer is generated at a different hydrogen to ethylene ratio. At least one catalyst generates a higher molecular weight polymer and another catalyst generates a lower molecular weight polymer. A molecular weight for each polymer is measured. The relationship between the molecular weight of the polymers generated by each of the catalysts and the ratio of hydrogen to ethylene is determined. A family of bPDI curves for polymers that would be made using a number of ratios of a blend of the at least two catalysts for each of a number of ratios of hydrogen to ethylene. A ratio for the catalyst blend of the catalysts that generates a polymer having a bPDI that matches a polymer fabrication process is selected, and the product specific polyolefin is made using the catalyst blend.

公开(公告)号：US09809667B2

公开(公告)日：2017-11-07

申请号：US15116696

申请日：2015-02-10

Applicant: Univation Technologies, LLC

Inventor： Ching-Tai Lue ,  Francis C. Rix ,  C. Jeff Harlan ,  Laughlin G. McCullough

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C07F17/00 ,  C08F210/02 ,  C08F4/76

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F2/00 ,  C08F2/34 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F2410/02 ,  C08F2420/00 ,  C08F2420/01 ,  C08F2500/01 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/03

Abstract: Catalyst systems and methods for making and using the same. A method of polymerizing olefins to produce a polyolefin polymer with a multimodal composition distribution, includes contacting ethylene and a comonomer with a catalyst system. The catalyst system includes a first catalyst compound and a second catalyst compound that are co-supported to form a commonly supported catalyst system. The first catalyst compound includes a compound with the general formula (C5HaR1b)(C5HcR2d)HfX2. The second catalyst compound includes at least one of the following general formulas: In both catalyst systems, the R groups can be independently selected from any number of substituents, including, for example, H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group, among others.

公开(公告)号：US09695309B2

公开(公告)日：2017-07-04

申请号：US15091810

申请日：2016-04-06

Applicant: NOVA Chemicals (International) S.A.

Inventor： Celine Bellehumeur ,  XiaoChuan Wang ,  Tieqi Li ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC: C08L23/20 ,  C08J5/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/08 ,  B29C41/04 ,  C08F210/16 ,  B29K23/00 ,  B29K105/00

CPC classification number: C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06

Abstract: This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than −1.0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms. The ethylene interpolymer products have a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US20170183433A1

公开(公告)日：2017-06-29

申请号：US15118307

申请日：2015-02-10

Applicant: UNIVATION TECHNOLOGIES ,LLC

Inventor： Francis C. RIX ,  Alexander D. TODD ,  C. Jeff HARLAN

IPC: C08F210/16 ,  C07F17/00

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F2/00 ,  C08F2/34 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F2410/02 ,  C08F2420/00 ,  C08F2420/01 ,  C08F2500/01 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/03

Abstract: Catalyst systems and methods for making and using the same. A method of methylating a catalyst composition while substantially normalizing the entiomeric distribution is provided. The method includes slurrying the organometallic compound in dimethoxyethane (DME), and adding a solution of RMgBr in DME, wherein R is a methyl group or a benzyl group, and wherein the RMgBr is greater than about 2.3 equivalents relative to the organometallic compound. After the addition of the RMgBr, the slurry is mixed for at least about four hours. An alkylated organometallic is isolated, wherein the methylated species has a meso/rac ratio that is between about 0.9 and about 1.2.

公开(公告)号：US09518159B2

公开(公告)日：2016-12-13

申请号：US14919051

申请日：2015-10-21

Applicant: NOVA Chemicals (International) S.A.

Inventor： Daniel Ward ,  Michael Li ,  Xiaochuan Wang ,  Tieqi Li ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC: C08J5/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/08 ,  C08L23/20

CPC classification number: C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06

Abstract: This disclosure relates to multilayer films having improved caulkability. These multilayer films have at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Abstract translation: 本公开涉及具有改善的可渗透性的多层膜。 这些多层膜具有至少一层含有乙烯互聚体产物或含有乙烯互聚物产物的共混物，其中乙烯互聚物产物具有：稀释指数（Yd）大于0; 总催化金属≥3.0ppm; ≧0.03个末端乙烯基不饱和/ 100个碳原子， 任选的大于0的无量纲模量（Xd）。乙烯互聚物产物的熔体指数为约0.4至约100dg /分钟，密度为约0.950至约0.970g / cm 3，多分散性（Mw / Mn）为约 2至约25，CDBI50为约55％至约97％。 此外，乙烯互聚物产物是至少两种乙烯互聚物的共混物; 其中一个乙烯互聚物用单中心催化剂制剂生产，并且用非均相催化剂制剂生产至少一种乙烯互聚物。

公开(公告)号：US20160222141A1

公开(公告)日：2016-08-04

申请号：US15097355

申请日：2016-04-13

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Qing Yang ,  Randy S. Muninger ,  Elizabeth A. Benham ,  Kathy S. Clear

IPC: C08F110/02

CPC classification number: C08F210/16 ,  B01J27/00 ,  B01J27/053 ,  B01J27/10 ,  B01J27/12 ,  B01J27/16 ,  B01J31/143 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/1805 ,  B01J31/2226 ,  B01J31/2295 ,  B01J35/0006 ,  B01J2531/0225 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/06 ,  C08F210/08 ,  C08F2420/01 ,  Y02P20/52 ,  C08F4/025 ,  C08F4/65916 ,  C08F210/14

Abstract: Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.

Abstract translation: 公开了二氧化硅涂覆的氧化铝活化剂 - 载体和含有这些活化剂 - 载体的催化剂组合物。 提供了用于制备二氧化硅涂覆的氧化铝活化剂 - 载体，用于制备催化剂组合物和使用催化剂组合物聚合烯烃的方法。

公开(公告)号：US20160024236A1

公开(公告)日：2016-01-28

申请号：US14876890

申请日：2015-10-07

Applicant: Chevron Phillips Chemical Company LP

Inventor： Ashish M. Sukhadia ,  Max P. McDaniel ,  Errun Ding ,  Guylaine St. Jean ,  Qing Yang ,  Daniel G. Hert ,  Chung Ching Tso

IPC: C08F210/14 ,  C08F210/08

CPC classification number: C08F10/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08F2410/02 ,  C08F2420/01 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/26

Abstract: Disclosed herein are ethylene-based polymers produced using dual metallocene catalyst systems. These polymers have low densities, high molecular weights, and broad molecular weight distributions, as well as having the majority of the long chain branches in the lower molecular weight component of the polymer, and the majority of the short chain branches in the higher molecular weight component of the polymer. Films produced from these polymers have improved impact and puncture resistance.