公开(公告)号：US11708437B2

公开(公告)日：2023-07-25

申请号：US17219622

申请日：2021-03-31

申请人： NOVA CHEMICALS (INTERNATIONAL) S.A.

发明人： Niousha Kazemi ,  Monika Kleczek ,  Vinod Konaganti ,  Bronwyn Gillon ,  Shivendra Goyal ,  Fazle Sibtain ,  Sepideh Kasiri ,  Stephen Salomons ,  Kenneth Taylor ,  Mehdi Keshtkar

IPC分类号： C08F210/16 ,  C08F4/6592 ,  C08L23/08 ,  B32B27/32 ,  C08J5/18 ,  C08F4/659

CPC分类号： C08F210/16 ,  B32B27/32 ,  C08J5/18 ,  C08L23/0815 ,  B32B2323/04 ,  C08F4/65908 ,  C08F4/65912 ,  C08J2323/08 ,  C08J2423/04 ,  C08J2423/10 ,  C08F210/16 ,  C08F2/001 ,  C08F210/16 ,  C08F2/06 ,  C08F210/16 ,  C08F4/65927 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/05 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/19 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/19 ,  C08F2500/26 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/09 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10 ,  C08F210/16 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/07 ,  C08F2500/10 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/10 ,  C08F2500/12 ,  C08L23/0815 ,  C08L23/10

摘要： This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless Long Chain Branching Factor, LCBF, greater than or equal to 0.001; a residual catalytic metal of from ≥0.03 to ≤5 ppm of hafnium, and; a dimensionless unsaturation ratio, UR, of from ≥−0.40 to ≤0.06, wherein UR is defined by the following relationship; UR=(SCU−TU)/TU, where SCU is the amount of a side chain unsaturation per 100 carbons and TU is amount of a terminal unsaturation per 100 carbons, in said ethylene interpolymer product. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity (Mw/Mn) from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.

公开(公告)号：US10995166B2

公开(公告)日：2021-05-04

申请号：US15805268

申请日：2017-11-07

申请人： NOVA Chemicals (International) S.A.

发明人： Niousha Kazemi ,  Monika Kleczek ,  Vinod Konaganti ,  Bronwyn Gillon ,  Shivendra Kumar Goyal ,  Fazle Sibtain ,  Sepideh Kasiri ,  Stephen Salomons ,  Kenneth Edward Taylor ,  Mehdi Keshtkar

IPC分类号： C08F210/16 ,  C08F4/6592 ,  C08L23/08 ,  C08J5/18 ,  B32B27/32 ,  C08F4/659

摘要： This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless Long Chain Branching Factor, LCBF, greater than or equal to 0.001; a residual catalytic metal of from ≥0.03 to ≤5 ppm of hafnium, and; a dimensionless unsaturation ratio, UR, of from ≥−0.40 to ≤0.06, wherein UR is defined by the following relationship; UR=(SCU−TU)/TU, where SCU is the amount of a side chain unsaturation per 100 carbons and TU is amount of a terminal unsaturation per 100 carbons, in said ethylene interpolymer product. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity (Mw/Mn) from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.

公开(公告)号：US20200325317A1

公开(公告)日：2020-10-15

申请号：US16910141

申请日：2020-06-24

申请人： NOVA Chemicals (International) S.A.

发明人： Zengrong Zhang ,  Niousha Kazemi ,  Stephen Salomons ,  Monika Kleczek ,  Mehdi Keshtkar ,  Brian Molloy ,  Qinyan Wang ,  Peter Zoricak ,  Charles Carter ,  XiaoChuan Wang ,  Christopher Dobbin ,  Fazle Sibtain ,  Kenneth Taylor ,  Lawrence VanAsseldonk ,  Hamidreza Khakdaman

IPC分类号： C08L23/08 ,  C08F210/16 ,  C08J5/18

摘要： A continuous solution polymerization process is disclosed wherein at least two catalyst formulations are employed. A first homogeneous catalyst formulation is employed in a first reactor to produce a first ethylene interpolymer and a first heterogeneous catalyst formulation is employed in a second reactor to produce a second ethylene interpolymer. Optionally a third ethylene interpolymer is formed in a third reactor. The resulting ethylene interpolymer products possess desirable properties in a variety of end use applications, for example in film applications. A means for increasing the molecular weight of the first ethylene interpolymer is disclosed and/or a means for increasing the temperature of the first reactor, relative to a third homogeneous catalyst formulation. A means for reducing the (α-olefin/ethylene) weight ratio in the first reactor is disclosed and/or reducing the density of the first ethylene interpolymer, relative to a third homogeneous catalyst formulation.

公开(公告)号：US20200325258A1

公开(公告)日：2020-10-15

申请号：US16866730

申请日：2020-05-05

申请人： NOVA Chemicals (International) S.A.

发明人： Niousha Kazemi ,  Monika Kleczek ,  Vinod Konaganti ,  Bronwyn Gillon ,  Shivendra Goyal ,  Fazle Sibtain ,  Sepideh Kasiri ,  Stephen Salomons ,  Kenneth Taylor ,  Mehdi Keshtkar

IPC分类号： C08F210/16 ,  C08J5/18

摘要： This disclosure relates to an improved continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a first reactor to form a first ethylene interpolymer. Optionally, process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in a third reactor, wherein a homogeneous catalyst formulation or a heterogeneous catalyst formulation is employed. In solution, the first, optional second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is optionally passivated and following a phase separation process an ethylene interpolymer product is recovered.

公开(公告)号：US20200056025A1

公开(公告)日：2020-02-20

申请号：US16557153

申请日：2019-08-30

申请人： NOVA Chemicals (International) S.A.

发明人： Zengrong Zhang ,  Niousha Kazemi ,  Stephen Salomons ,  Monika Kleczek ,  Mehdi Keshtkar ,  Brian Molloy ,  Qinyan Wang ,  Peter Zoricak ,  Charles Carter ,  XiaoChuan Wang ,  Christopher Dobbin ,  Fazle Sibtain ,  Kenneth Taylor ,  Lawrence VanAsseldonk ,  Hamidreza Khakdaman

IPC分类号： C08L23/08 ,  C08J5/18 ,  C08F210/16

摘要： A continuous solution polymerization process is disclosed wherein at least two catalyst formulations are employed. A first homogeneous catalyst formulation is employed in a first reactor to produce a first ethylene interpolymer and a first heterogeneous catalyst formulation is employed in a second reactor to produce a second ethylene interpolymer. Optionally a third ethylene interpolymer is formed in a third reactor. The resulting ethylene interpolymer products possess desirable properties in a variety of end use applications, for example in film applications. A means for increasing the molecular weight of the first ethylene interpolymer is disclosed and/or a means for increasing the temperature of the first reactor, relative to a third homogeneous catalyst formulation. A means for reducing the (α-olefin/ethylene) weight ratio in the first reactor is disclosed and/or reducing the density of the first ethylene interpolymer, relative to a third homogeneous catalyst formulation.

公开(公告)号：US20190241724A1

公开(公告)日：2019-08-08

申请号：US16385211

申请日：2019-04-16

申请人： NOVA Chemicals (International) S.A.

发明人： Brian Molloy ,  Shivendra Goyal ,  Stephen Salomons ,  Fazle Sibtain

IPC分类号： C08L23/08 ,  C08J5/18 ,  B32B27/34 ,  C08J5/00 ,  C08F2/00 ,  C08L23/20 ,  B32B3/26 ,  B32B27/32 ,  B29C41/22 ,  C08L23/14 ,  C08F2/06 ,  C08F4/6592 ,  C08F210/16 ,  B32B7/12 ,  B32B27/08 ,  B29C41/04

摘要： This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal ≥3.0 ppm; ≥0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US20180230298A1

公开(公告)日：2018-08-16

申请号：US15434089

申请日：2017-02-16

申请人： NOVA Chemicals (International) S.A.

发明人： Xiaochuan Wang ,  Tieqi Li ,  Fazle Sibtain ,  Christopher Dobbin ,  Kenneth Taylor ,  Hamidreza Khakdaman ,  Brian Molloy

IPC分类号： C08L23/08 ,  B29C43/00 ,  B29C43/02 ,  B29C45/00 ,  B65D41/00

CPC分类号： C08L23/0815 ,  B29C43/003 ,  B29K2023/04 ,  B29L2031/56 ,  B65D41/00 ,  C08F4/76 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2314/02 ,  C08L2314/06

摘要： This disclosure relates to caps and closures manufactured from an ethylene interpolymer product, or a blend containing an ethylene interpolymer product.

公开(公告)号：US10035906B2

公开(公告)日：2018-07-31

申请号：US15332202

申请日：2016-10-24

申请人： NOVA Chemicals (International) S.A.

发明人： Tieqi Li ,  XiaoChuan Wang ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC分类号： C08F210/16 ,  C08L23/08 ,  C08J5/00 ,  C08F2/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/20 ,  B29C41/04 ,  B32B7/12 ,  B32B27/08 ,  B32B27/34 ,  B29K23/00 ,  B29K105/00 ,  C08F4/659 ,  C08F4/6592

CPC分类号： C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06 ,  C08F2/42 ,  C08F2500/07

摘要： This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal ≥3.0 ppm; ≥0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US10023706B2

公开(公告)日：2018-07-17

申请号：US15609051

申请日：2017-05-31

申请人： NOVA Chemicals (International) S.A.

发明人： Celine Bellehumeur ,  Brian Molloy ,  Hamidreza Khakdaman ,  XiaoChuan Wang ,  Tieqi Li ,  Christopher Dobbin ,  Fazle Sibtain ,  Kenneth Taylor

IPC分类号： C08J5/18 ,  C08L23/20 ,  C08F4/655 ,  B32B3/26 ,  B32B27/32 ,  C08L23/08 ,  C08J5/00 ,  B32B7/12 ,  B32B27/08 ,  B32B27/34 ,  C08F210/16 ,  C08F4/659 ,  C08F4/658 ,  C08F4/6592 ,  C08F2/06 ,  B29C41/04 ,  C08F2/00 ,  B29C41/22 ,  C08L23/14 ,  C08F210/14 ,  B29K23/00 ,  B29K105/00

摘要： This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Yd) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

公开(公告)号：US09695309B2

公开(公告)日：2017-07-04

申请号：US15091810

申请日：2016-04-06

申请人： NOVA Chemicals (International) S.A.

发明人： Celine Bellehumeur ,  XiaoChuan Wang ,  Tieqi Li ,  Christopher John Brooke Dobbin ,  Fazle Sibtain ,  Kenneth Edward Taylor ,  Hamidreza Khakdaman

IPC分类号： C08L23/20 ,  C08J5/00 ,  B32B3/26 ,  B32B27/32 ,  C08J5/18 ,  C08L23/08 ,  B29C41/04 ,  C08F210/16 ,  B29K23/00 ,  B29K105/00

CPC分类号： C08L23/0815 ,  B29C41/04 ,  B29C41/22 ,  B29K2023/08 ,  B29K2105/0058 ,  B29K2105/0085 ,  B29K2105/0094 ,  B29K2905/02 ,  B29K2995/0063 ,  B29K2995/0088 ,  B32B3/266 ,  B32B7/12 ,  B32B27/08 ,  B32B27/327 ,  B32B27/34 ,  B32B2307/7265 ,  B32B2439/40 ,  C08F2/001 ,  C08F2/06 ,  C08F4/6555 ,  C08F4/6583 ,  C08F4/6585 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16 ,  C08F2420/01 ,  C08F2420/04 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/26 ,  C08J5/00 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2323/20 ,  C08J2323/24 ,  C08J2423/08 ,  C08J2423/20 ,  C08J2423/24 ,  C08L23/08 ,  C08L23/14 ,  C08L23/20 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2314/02 ,  C08L2314/06

摘要： This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than −1.0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms. The ethylene interpolymer products have a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.