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公开(公告)号:US10413893B2
公开(公告)日:2019-09-17
申请号:US15517758
申请日:2016-02-02
Applicant: LG CHEM, LTD.
Inventor: Eun Ji Shin , Yong Ho Lee , Seul Ki Im , Ki Soo Lee , Jin Young Park , Seok Pil Sa
IPC: C07C2/02 , C07C2/04 , C07C2/24 , C07C2/26 , B01J31/24 , B01J31/02 , B01J31/04 , B01J31/14 , C07C2/32 , C08F210/16 , C08F2/40 , C08F4/69 , C08F10/00 , C08K5/05 , B01J31/18 , C07F9/50 , C08K5/00 , C08K5/17 , B01J35/00 , B01J37/04 , C08F10/02
Abstract: The method for oligomerizing olefin according to the present disclosure is a method for oligomerizing olefin using an oligomerization catalyst system and includes deteriorating the activity of the oligomerization catalyst system by injecting a deactivator in a latter part of a multimerization reaction of olefin. The deactivator may include an additive for polymer containing at least one functional group selected from the group consisting of a hydroxyl group, an amine group and an amide group. According to the oligomerizing method, the isomer of 1-hexene and/or 1-octene and alpha-olefins with C10 to C40 may be decreased via the restraint of the additional side reaction of a product. Since the deactivator is an additive for enhancing the physical properties of a polymer, a separating process thereof is not required, thereby improving economic feasibility and productivity.
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公开(公告)号:US10189920B2
公开(公告)日:2019-01-29
申请号:US15552136
申请日:2016-01-27
Applicant: LG CHEM, LTD.
Inventor: Seung Mi Lee , Yong Ho Lee , Jin Young Park , Ki Soo Lee , Eun Ji Shin , Seok Pil Sa
IPC: C08F110/02 , C08F4/02 , C08F4/69 , C08F10/00 , C08F210/16 , C08F4/659 , C08F4/6592 , C08F210/00 , C07C2/30
Abstract: Provided are a hybrid supported catalyst system and a method of preparing a polyolefin using the same. The hybrid supported catalyst system according to the present invention may be used to perform oligomerization and copolymerization of olefin monomers in a single reactor at the same time with high efficiency without a separate process of preparing alpha-olefin. Therefore, costs for preparing or purchasing comonomers which are expensive raw materials may be reduced, thereby reducing the production cost of a final product.
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公开(公告)号:US10179752B2
公开(公告)日:2019-01-15
申请号:US15941708
申请日:2018-03-30
Applicant: LG CHEM, LTD.
Inventor: Yong Ho Lee , Seok Pil Sa , Eun Ji Shin , Ki Soo Lee , Jin Young Park , Seul Ki Im , Yoon Ki Hong
Abstract: The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.
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公开(公告)号:US09994653B2
公开(公告)日:2018-06-12
申请号:US15317038
申请日:2015-01-28
Applicant: LG CHEM, LTD.
Inventor: Yong Ho Lee , Kyung Jin Cho , Jin Young Park , Ki Soo Lee , Min Seok Cho , Se Young Kim , Sung Min Lee , Chang Woan Han
IPC: C08F4/6592 , C08F10/00 , C07F17/00 , C08F10/02 , C08F4/659
CPC classification number: C08F10/02 , C07F7/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927
Abstract: Provided are a novel metallocene compound, a catalyst composition including the same, and a method of preparing an olefin-based polymer using the same. The metallocene compound according to the present invention or the catalyst composition including the same may be used for the preparation of an olefin-based polymer, may have excellent polymerization ability, and may produce an olefin-based polymer having a high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefin-based polymer having a high molecular weight may be polymerized because the metallocene compound shows high polymerization activity even when it is supported on a support and maintains high activity even in the presence of hydrogen because of its low hydrogen reactivity.
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公开(公告)号:US09963527B2
公开(公告)日:2018-05-08
申请号:US15314303
申请日:2015-06-05
Applicant: LG CHEM, LTD.
Inventor: Bog Ki Hong , Yong Ho Lee , Chang Woan Han , Yi Young Choi , Ki Soo Lee
IPC: C07F17/00 , C08F4/6592 , C08F210/16 , C07F7/08 , C08F4/659
CPC classification number: C08F210/16 , B01J31/00 , C07F7/0803 , C07F7/081 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/14 , C08F2500/03
Abstract: The present invention relates to a novel transition metal compound, a catalyst composition comprising the transition metal compound, and a method of preparing polyolefin using the catalyst composition.
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公开(公告)号:US09850326B2
公开(公告)日:2017-12-26
申请号:US15026119
申请日:2015-08-21
Applicant: LG CHEM, LTD.
Inventor: Bog Ki Hong , Yong Ho Lee , Chang Woan Han , Yi Young Choi , Ki Soo Lee
IPC: C07F17/00 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , C07F7/08 , C08F4/659
CPC classification number: C08F10/02 , C07F7/0812 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2420/06 , C08F210/14 , C08F2500/03 , C08F2500/01
Abstract: The present invention relates to a novel ligand compound, a metallocene compound, and a method for preparing an olefin-based polymer using the same. The metallocene compound according to the present invention and a catalyst composition comprising the same have excellent polymerization activity, and yet, have excellent comonomer insertion capability, and thus, can be used to prepare olefin-based polymer having wide molecular weight distribution and the resulting excellent processability.
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公开(公告)号:US09637508B2
公开(公告)日:2017-05-02
申请号:US14894132
申请日:2014-11-18
Applicant: LG CHEM, LTD.
Inventor: Yong Ho Lee , Eun Ji Shin , Seok Pil Sa , Ki Soo Lee
IPC: C07F9/46 , C07C2/36 , C07C211/54 , C08F4/00 , B01J31/14 , B01J31/18 , C07C2/32 , C07C11/107 , C08F110/02
CPC classification number: C07F9/46 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C211/54 , C07C2531/14 , C07C2531/22 , C08F4/00 , C07C11/107 , C08F110/02 , C08F2500/02 , C08F4/69267
Abstract: Provided are ligand compounds containing two or more diphosphinoamine functional groups, where the two or more diphosphinoamine functional groups are linked by 4 carbon atoms, a catalyst system including the ligand compounds for olefin oligomerization, and a method for olefin oligomerization using the same. The catalyst system for olefin oligomerization according to the present invention has excellent catalytic activity, and yet, exhibits high selectivity to 1-hexene and 1-octene, thus enabling efficient preparation of alpha-olefin.
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公开(公告)号:US10947256B2
公开(公告)日:2021-03-16
申请号:US16916877
申请日:2020-06-30
Applicant: LG Chem, Ltd.
Inventor: Seul Ki Im , Yong Ho Lee , Ki Soo Lee , Eun Ji Shin , Jin Young Park , Seok Pil Sa , Yoon Ki Hong
IPC: C07F9/50 , C07C11/107 , C07F9/02 , C07F9/70 , C07F11/00 , C07F9/90 , C08F4/69 , C08F10/00 , B01J31/18 , B01J31/34 , C08F10/02
Abstract: The present invention relates to a ligand compound, a catalyst system for olefin oligomerization and a method for oligomerizing an olefin using same. The catalyst system for olefin oligomerization according to the present invention exhibits high selectivity to 1-hexene or 1-octene while having excellent catalytic activity, thus enabling more efficient preparation of alpha-olefins.
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公开(公告)号:US10035738B2
公开(公告)日:2018-07-31
申请号:US15023632
申请日:2015-06-12
Applicant: LG CHEM, LTD.
Inventor: Eun Ji Shin , Yong Ho Lee , Seok Pil Sa , Ki Soo Lee , Jin Young Park
Abstract: The present invention relates to a process for preparing an olefin oligomer including a step of contacting an olefin monomer with a composite catalyst in the presence of a halogenated organic solvent, wherein the composite catalyst includes: a transition metal compound; a cocatalyst; and an organic ligand including a diphosphonoamine compound in which two or more diphosphonoamines are combined via a polyvalent functional group.
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公开(公告)号:US09975969B2
公开(公告)日:2018-05-22
申请号:US15021238
申请日:2014-11-21
Applicant: LG CHEM, LTD.
Inventor: Kyung Jin Cho , Yong Ho Lee , Ki Soo Lee , Min Seok Cho , Se Young Kim , Sung Min Lee , Jin Young Park
CPC classification number: C08F10/02 , C08F2/001 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F2410/01 , C08F2410/03 , C08F2420/06 , C08F2/38 , C08F210/16 , C08F210/14 , C08F2500/01 , C08F2500/05 , C08F2500/12 , C08F4/65925 , C08F4/65927
Abstract: A method of preparing a polyolefin, wherein the method is used to more effectively prepare a polyolefin which has a high molecular weight and multimodal molecular weight distribution, thereby being preferably used for blow-molding or the like, and a polyolefin prepared thereby, are provided.
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