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公开(公告)号:US12064754B2
公开(公告)日:2024-08-20
申请号:US17741029
申请日:2022-05-10
申请人: NATIONAL TSING HUA UNIVERSITY , Chang Chun Plastics Co., Ltd. , Chang Chun Petrochemical Co., LTD. , DAIREN CHEMICAL CORP.
发明人: Yi-Chou Tsai , John Di Yi Ou , Chuan-Sheng Huang , Yung-Sheng Lin
IPC分类号: C07F7/28 , B01J31/22 , B01J31/38 , C08G63/672 , C08K5/00
CPC分类号: B01J31/38 , B01J31/2213 , C08G63/672 , C08K5/005
摘要: A titanium catalyst and a synthesizing method of polyester resins are provided in the present disclosure. The titanium catalyst has a chemical structure represented by Formula (I), Formula (II) or Formula (III).
The symbols shown in the Formula (I), the Formula (II) or the Formula (III) are defined in the description. The synthesizing method of polyester resins includes providing the titanium catalyst, performing a feeding step, performing a heating and pressurizing step and performing a heating and vacuuming step. The titanium catalyst and a heat stabilizer are added into an autoclave before the feeding step or before the heating and vacuuming step.-
公开(公告)号:US11970510B2
公开(公告)日:2024-04-30
申请号:US17286776
申请日:2019-10-15
申请人: CHINA PETROLEUM & CHEMICAL CORPORATION , BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
发明人: Jin Zhao , Xianzhi Xia , Yuexiang Liu , Yang Tan , Chunhong Ren , Weili Li , Long Chen , Futang Gao , Yongtai Ling , Tao Liu
IPC分类号: C08F10/00 , C07F7/28 , C08F110/00 , C08F110/06
CPC分类号: C07F7/28 , C08F110/06
摘要: Disclosed are a catalyst component and a catalyst for olefin polymerization, and an olefin polymerization method. The catalyst component comprises magnesium, titanium, a halogen and an internal electron donor, wherein the internal electron donor comprises a monocarboxylic acid ester compound and a diether compound, and the molar ratio of the monocarboxylic acid ester compound to the diether compound is (0.0035-0.7):1. By using the catalyst, a polymer having both a high isotactic index and a high melt flow index can be prepared.
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公开(公告)号:US20240018171A1
公开(公告)日:2024-01-18
申请号:US18221917
申请日:2023-07-14
发明人: Nilesh Rajesh Mote , Monikangkana Talukdar , Yogesh Popatrao Patil , Bennet Chelliahn , Ramachandrarao Bojja
IPC分类号: C07F7/28 , C08F110/14
CPC分类号: C07F7/28 , C08F110/14
摘要: The present disclosure pertains to the technical field of a catalyst. The present disclosure relates to a complexing agent for preparing titanium complexes for alpha olefin polymerization. In particular, the present disclosure provides titanium complexes for alpha olefin polymerization and methods of preparation thereof.
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公开(公告)号:US20230357509A1
公开(公告)日:2023-11-09
申请号:US18002470
申请日:2021-06-23
发明人: Yuya NAKAGAWA , Kazunori NAMBA , Haruka YOSHIYAMA , Yuji IMADA , Nanae KIKUI
IPC分类号: C08G77/08 , C07F7/28 , C07C211/63
CPC分类号: C08G77/08 , C07F7/28 , C07C211/63
摘要: Provided is a curing catalyst having a high safety and a practical curing rate.
According to the present invention, provided is a curing catalyst [B] used for curing a polymer [A] having a reactive hydrolyzable silicon-containing group, wherein
the curing catalyst [B] contains a complex of a titanium compound [B1] and an ammonium hydroxide [B2], and an amino group-containing compound [B3] containing a primary amino group and/or a secondary amino group,
the titanium compound [B1] is represented by Chemical Formula (1), and
the ammonium hydroxide [B2] is represented by Chemical Formula (2).-
公开(公告)号:US20230339988A1
公开(公告)日:2023-10-26
申请号:US17787435
申请日:2020-12-16
摘要: Metal complexes of macrocycles and/or isoprenoids and/or linear tetrapyrroles by mechanochemistry (grinding or milling), preparation method thereof, sunscreen/concealer/UV absorber thereof, self-assembled coating material thereof, superamphiphilic material or surfaces thereof, hair dyeing thereof and other uses thereof. Converting biomass, including products from its own process-line wastes, into high value products such as biofuel, bioplastics and biochemicals in an attempt to replace oil consumption has become nowadays a challenge for innovation. In one embodiment of the present invention, a novel product obtained from the solvent-free mechanochemical reaction (grinding and milling) of biomass and a metal alkoxide is produced. In one embodiment of the present invention, Spirulina biomass, comprising macrocycles (chlorophyll) and isoprenoids (P-carotene) and linear tetrapyrroles (phycobilins attached to proteins), is ground or milled together with a metal alkoxide to produce a stable colored material.
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公开(公告)号:US20230312614A1
公开(公告)日:2023-10-05
申请号:US18025017
申请日:2021-09-06
发明人: Hyun-Kee KIM , Cheol-Wan PARK , Ki-Yeung MUN , Ee-Seul SHIN , Eun-Jeong CHO , Jang-Hyeon SEOK , Jung-Woo PARK
IPC分类号: C07F7/00 , C07F7/28 , C23C16/455 , C23C16/40 , C23C16/44
CPC分类号: C07F7/00 , C07F7/28 , C23C16/45553 , C23C16/405 , C23C16/40 , C23C16/44
摘要: The present disclosure relates to a novel Group 4 metal element-containing compound having excellent thermal stability, a precursor composition including the compound, and a method for manufacturing a thin film using the precursor composition. The novel Group 4 metal element-containing compound according to the present disclosure and the vapor deposition precursor composition including the compound can have excellent thermal stability, realize thin film deposition in a wide temperature range, and reduce residues caused by heat loss, thereby preventing side reactions in a process. Additionally, the vapor deposition precursor composition according to the present disclosure can realize uniform thin film deposition, thereby securing excellent physical properties of the thin film.
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公开(公告)号:US20230303597A1
公开(公告)日:2023-09-28
申请号:US18041016
申请日:2021-12-13
发明人: Dongcheol Shin , Miji Kim , Minji Kim
IPC分类号: C07F7/28 , C08F4/64 , C08F210/16
CPC分类号: C07F7/28 , C08F4/64193 , C08F210/16
摘要: Provided are a metal-ligand complex having both a strong electron donor group and an electron withdrawing group by introducing a specific functional group, difluoromethylene group, into an oxygen-oxygen bridge, a catalyst composition for ethylene-based polymerization containing the same, and a preparation method of an ethylene-based polymer using the same. The metal-ligand complex according to the present invention and the catalyst composition containing the same may be very usefully used in the preparation of an ethylene-based polymer having excellent physical properties.
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公开(公告)号:US20230234976A1
公开(公告)日:2023-07-27
申请号:US18002463
申请日:2021-06-23
发明人: Yuya Nakagawa , Kazunori Namba , Haruka Yoshiyama , Yuji Imada , Nanae Kikui
摘要: Provided is a curing catalyst having a high safety and a practical curing rate.
According to the present invention, provided is a curing catalyst [B] used for curing a polymer [A] having a reactive hydrolyzable silicon-containing group, wherein
the curing catalyst [B] contains a complex of a titanium compound [B1] and an ammonium hydroxide [B2], and an amine compound [B3],
the titanium compound [B1] is represented by Chemical Formula (1),
the ammonium hydroxide [B2] is represented by Chemical Formula (2), and
the amine compound [B3] is represented by Chemical Formula (3), Chemical Formula (4), or Chemical Formula (5).-
公开(公告)号:US11649256B2
公开(公告)日:2023-05-16
申请号:US17067256
申请日:2020-10-09
发明人: Gursu Culcu , Catherine A. Faler , Crisita Carmen H. Atienza , David A. Cano , John R. Hagadorn
IPC分类号: C08F4/64 , C08F4/76 , C08F10/02 , C08F210/16 , C07F7/28 , C08F210/02
CPC分类号: C07F7/28 , C08F4/64158 , C08F10/02 , C08F210/02 , C08F210/16 , C08F2500/01 , C08F2500/03 , C08F2500/34 , C08F2500/38
摘要: The present disclosure provides catalyst compounds represented by Formula (I):
where Q is OR13, SR13, NR13R14, PR13R14, or a heterocyclic ring; each R1-14 is independently hydrogen, C1-C40 hydrocarbyl, substituted C1-C40 hydrocarbyl, a heteroatom, or a heteroatom-containing group, or multiple R1-14 are joined together to form a C4-C62 cyclic, heterocyclic, or polycyclic ring structure, or combination(s) thereof; each X1 and X2 is independently C1-C20 hydrocarbyl, substituted C1-C20 hydrocarbyl, a heteroatom, or a heteroatom-containing group, or X1 and X2 join together to form a C4-C62 cyclic, heterocyclic, or polycyclic ring structure; and Y is a hydrocarbyl. The present disclosure also provides catalyst systems including an activator, a support, and a catalyst of the present disclosure. The present disclosure also provides polymerization processes including introducing olefin monomers to a catalyst system. Additionally, the present disclosure provides a polyolefin formed by a catalyst system or method of the present disclosure.-
公开(公告)号:US11560394B2
公开(公告)日:2023-01-24
申请号:US17048042
申请日:2019-04-15
发明人: Georgy Pavlovich Goryunov , Oleg Vladimirovich Samsonov , Dmitry Vadimovich Uborsky , Alexander Zel'Manovich Voskoboynikov , Alexandra Berthoud , Maxence Valla
IPC分类号: C07F17/00 , C08F4/6592 , C08F210/16 , C08F210/18 , C07F7/28
摘要: A metal complex of the formula (1) InCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is number of 1 to 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R1 independently is a C1-C4-alkyl, m is a number of 0 to 4, R2 is a C1-C10-alkyl, C5-C10-cycloalkyl, or a C6-C10-aryl unsubstituted or substituted with C1-C10-alkyl or C1-C4-dialkyl amino, R3, R4 and R5 each is independently selected from hydrogen, C1-C4-alkyl, C6-C10-aryl unsubstituted or substituted with C1-C4-alkyl, halide, or both of C1-C4-alkyl and halide and, L is an amidinate ligand of the formula (3a) wherein the amidine-containing ligand (3a) is bonded to the metal M via the imine nitrogen atom N2, wherein R7 is independently selected from C1-C4-alkyl and halide and q is a number of 0 to 4, Sub4 is a cyclic or linear aliphatic or aromatic substituent.
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