公开(公告)号：US20170158970A1

公开(公告)日：2017-06-08

申请号：US15321287

申请日：2014-06-26

Applicant: S-OIL CORPORATION ,  KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Chan-Ju SONG ,  Sang Cheol PAIK ,  Sang-Goo LEE ,  Min Kee CHOI ,  Myoung Yeob KIM

IPC: C10G45/64 ,  C01B39/54 ,  B01J37/08 ,  B01J35/10 ,  B01J29/85 ,  B01J37/04

CPC classification number: C10G45/64 ,  B01J29/041 ,  B01J29/042 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/064 ,  B01J29/076 ,  B01J29/85 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1095 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/186 ,  C01B39/54 ,  C01P2006/14 ,  C01P2006/16 ,  C10G45/60 ,  C10G45/62

Abstract: The present disclosure relates to a method for preparing a multi-level pore zeolite, including: (A) a step of mixing a silicon precursor, an aluminum precursor, a phosphorus precursor, a structure directing agent and water; a step of (B) adding phenylphosphonic acid, carbon black or a mixture thereof to the mixture prepared in the step (A) and mixing the same; a step of (C) crystallizing the mixture prepared in the step (B) by heat-treating the same; and a step of (D) calcining the crystallization product, and utilization of the prepared multi-level pore zeolite as a catalyst for hydroisomerization of normal paraffins. The catalyst exhibits improved isoparaffin yield when it is used as a catalyst for hydroisomerization of normal paraffins such as diesel or lube base oil by supporting an active metal component because residence time of reactants and products in the zeolite crystals are decreased due to mesopores and the proportion of external acid sites to total acid sites is low. Also, cloud point and pour point are effectively improved and high hydroisomerization reactivity is achieved without product loss.

公开(公告)号：US09566567B2

公开(公告)日：2017-02-14

申请号：US14030070

申请日：2013-09-18

Applicant: Korea Institute of Energy Research

Inventor： Hee Yeon Kim ,  Seok Yong Hong ,  Hyun Uk Kim

IPC: B01J23/42 ,  B01J37/02 ,  B01J37/08 ,  B01J37/12 ,  B01J21/04 ,  B01J23/28 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/75 ,  B01J23/755 ,  B01J29/04 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J35/00 ,  C01B3/40

CPC classification number: B01J23/42 ,  B01J21/04 ,  B01J23/28 ,  B01J23/44 ,  B01J23/462 ,  B01J23/52 ,  B01J23/75 ,  B01J23/755 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J35/002 ,  B01J35/008 ,  B01J37/0217 ,  B01J37/0244 ,  B01J37/084 ,  B01J37/12 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52

Abstract: A metal-carbon composite supported catalyst for hydrogen production using co-evaporation and a method of preparing the same, wherein the catalyst is configured such that a metal-carbon composite having a core-shell structure resulting from co-evaporation is supported on the surface of an oxide-based support coated with carbon, thereby maintaining superior durability without agglomeration even in a catalytic reaction at a high temperature. Because part or all of the surface of metal is covered with the carbon shell, even when the catalyst is applied under severe reaction conditions including high temperatures, long periods of time, acidic or alkaline states, etc., the metal particles do not agglomerate or are not detached, and do not corrode, thus exhibiting high performance and high durability. Therefore, inactivation of the catalyst or the generation of side reactions can be prevented, so that the catalyst can be efficiently utilized in hydrogen production.

Abstract translation: 一种使用共蒸发的氢制造用金属 - 碳复合材料负载型催化剂及其制备方法，其特征在于，所述催化剂构成为具有由共蒸发得到的核 - 壳结构的金属 - 碳复合体被支撑在所述表面上 的涂覆有碳的氧化物基载体，从而即使在高温下的催化反应中也保持优异的耐久性而没有附聚。 由于金属表面的一部分或全部被碳壳覆盖，所以即使催化剂在包括高温，长时间，长时间，酸性或碱性状态等苛刻的反应条件下被使用，金属颗粒也不会聚集或 不分离，不腐蚀，因此表现出高性能和高耐久性。 因此，可以防止催化剂的失活或副反应的产生，从而可以有效地利用催化剂进行制氢。

公开(公告)号：US20140128246A1

公开(公告)日：2014-05-08

申请号：US14075661

申请日：2013-11-08

Applicant: Rive Technology, Inc.

Inventor： Javier Garcia-Martinez

IPC: B01J29/14 ,  B01J29/08

CPC classification number: B01J29/146 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J35/0013 ,  B01J35/002 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G2300/1059 ,  C10G2300/1074

Abstract: Compositions and methods for preparing a catalyst composition containing mesoporous materials are described herein. In particular, various embodiments described herein relate to the preparation of catalytic compositions containing a mesoporous zeolite and one or more catalytic nanoparticles dispersed therein. In various embodiments described herein, such catalyst compositions can be used in various catalytic conversion processes, such as hydrocracking.

Abstract translation: 本文描述了制备含介孔材料的催化剂组合物的组合物和方法。 特别地，本文描述的各种实施方案涉及含有介孔沸石和分散在其中的一种或多种催化纳米颗粒的催化组合物的制备。 在本文所述的各种实施方案中，这种催化剂组合物可用于各种催化转化方法，例如加氢裂化。

公开(公告)号：US20140005031A1

公开(公告)日：2014-01-02

申请号：US13995508

申请日：2011-12-15

Applicant: Alexandra Chaumonnot ,  Clement Sanchez ,  Cedric Boissiere ,  Frederic Colbeau-Justin ,  Karin Marchand ,  Elodie Devers ,  Audrey Bonduelle ,  Denis Uzio ,  Antoine Daudin ,  Bertrand Guichard ,  Denis Uzio ,  Antoine Daudin

Inventor： Alexandra Chaumonnot ,  Clement Sanchez ,  Cedric Boissiere ,  Frederic Colbeau-Justin ,  Karin Marchand ,  Elodie Devers ,  Audrey Bonduelle ,  Denis Uzio ,  Antoine Daudin ,  Bertrand Guichard ,  Denis Uzio ,  Antoine Daudin

IPC: B01J27/199 ,  B01J27/19 ,  B01J27/188 ,  B01J23/882

CPC classification number: B01J27/199 ,  B01J23/882 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  C01B37/00 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/06 ,  C10G3/45 ,  C10G3/46 ,  C10G3/48 ,  C10G3/49 ,  C10G3/50 ,  C10G45/06 ,  C10G47/12 ,  C10G2300/1011 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  Y02P30/10 ,  Y02P30/20

Abstract: Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q−, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.

Abstract translation: 具有至少两个基本球形颗粒的无机材料，每个所述球形金属颗粒：具有式（XxMmOyHh）q-的多金属氧酸盐，其中H是氢，O是氧，X是磷，硅，硼，镍或钴，M是 一种或多种钒，铌，钽，钼，钨，铁，铜，锌，钴和镍，x为0,1,2或4，m为5,6,7,8,9,10,11,12 或18，y为17〜72，h为0〜12，q为1〜20。

公开(公告)号：US20060049083A1

公开(公告)日：2006-03-09

申请号：US11189666

申请日：2005-07-26

Applicant: Chuansheng Bai ,  Gary McVicker ,  Stuart Shih ,  Michael Kerby ,  Edward Lemon

Inventor： Chuansheng Bai ,  Gary McVicker ,  Stuart Shih ,  Michael Kerby ,  Edward Lemon

IPC: C10G45/04

CPC classification number: B01J29/045 ,  B01J23/85 ,  B01J23/882 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/044 ,  B01J35/002 ,  B01J37/0009 ,  B01J2229/42 ,  C10G2400/02

Abstract: This invention relates to a process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.

Abstract translation: 本发明涉及使用包含至少一种负载在低酸性有序介孔载体材料上的加氢脱硫金属的催化剂来选择性加氢脱硫石脑油原料流的方法。

公开(公告)号：US20050201920A1

公开(公告)日：2005-09-15

申请号：US11101858

申请日：2005-04-08

Applicant: Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

Inventor： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

IPC: B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/10 ,  C01B13/36 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C27/00 ,  C07C27/06 ,  C10G11/02 ,  C10G15/00

CPC classification number: C10G2/332 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2θ. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

公开(公告)号：US20020052289A1

公开(公告)日：2002-05-02

申请号：US09990812

申请日：2001-11-16

Inventor： Leo E. Manzer ,  Stephan Schwarz

IPC: B01J023/00 ,  B01J029/06

CPC classification number: B01J29/0325 ,  B01J29/0333 ,  B01J29/043 ,  B01J29/044 ,  B01J35/0013 ,  B01J37/0236 ,  C07C1/0435 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C10G2/334

Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 nullngstrom units.

Abstract translation: 本发明提供一种生产烃的方法。 该方法包括使包含氢气和一氧化碳的进料流与催化剂接触，所述反应区保持在有效产生包含烃的流出物流的转化促进条件下，并且使用催化剂，所述催化剂包括（a）至少一种催化金属用于费 - 托反应（例如铁，钴，镍和/或钌）和（b）在煅烧后显示出具有至少一个d-间距大于18埃的峰的非层状介孔载体 单位。

公开(公告)号：US20240326027A1

公开(公告)日：2024-10-03

申请号：US18738339

申请日：2024-06-10

Applicant: SK Innovation Co., Ltd. ,  SK Geo Centric Co., Ltd.

Inventor： Jae Suk Choi ,  Ka Young Kim ,  Hee Soo Kim ,  Ju Hwan Im ,  Dae Hyun Choo ,  Ho Won Lee ,  Je Mi Lim

IPC: B01J29/04 ,  B01J29/035 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J37/08 ,  B01J37/30 ,  C07C2/12

CPC classification number: B01J29/044 ,  B01J29/0356 ,  B01J35/615 ,  B01J35/617 ,  B01J35/618 ,  B01J35/633 ,  B01J35/647 ,  B01J37/08 ,  B01J37/30 ,  C07C2/12

Abstract: In the present disclosure, a heterogeneous nickel-based oligomerization catalyst in which nickel in the form of single atom is loaded on an Al-mesoporous silicate support by ion exchange and a method for producing the same, and a method for oligomerizing light olefins, specifically C4 olefins using the catalyst are described.

公开(公告)号：US12070740B2

公开(公告)日：2024-08-27

申请号：US17299748

申请日：2019-12-03

Applicant: FURUKAWA ELECTRIC CO., LTD.

Inventor： Kaori Sekine ,  Yuichiro Banba ,  Yukako Nakai ,  Mai Nishii ,  Masayuki Fukushima ,  Sadahiro Kato ,  Takao Masuda ,  Yuta Nakasaka ,  Takuya Yoshikawa

IPC: B01J29/04 ,  B01J35/40 ,  B01J35/64 ,  B01J37/02 ,  B01J37/10 ,  B01J37/16

CPC classification number: B01J29/044 ,  B01J35/40 ,  B01J35/643 ,  B01J37/02 ,  B01J37/10 ,  B01J37/16

Abstract: A catalyst structure that allows prevention of aggregation of fine particles of a functional substance, suppresses decrease of catalyst activity, and thus enables extension of the lifetime of the catalyst structure. A catalyst structure has a carrier that is formed from a zeolite-type compound and has a porous structure. The functional substance includes a first element that is at least one metallic element selected from the group consisting of cobalt (Co), nickel (Ni), iron (Fe), and ruthenium (Ru), and at least one second element selected from the group consisting of metallic elements in group 1, group 2, group 4, group 7, and group 12 on the periodic table. The carrier has paths connected to each other. The functional substance is present in at least the paths of the carrier.

公开(公告)号：US11857955B1

公开(公告)日：2024-01-02

申请号：US17964156

申请日：2022-10-12

Applicant: Saudi Arabian Oil Company

Inventor： Aaron Chi Akah ,  Veera Venkata Ramakrishna Tammana

IPC: B01J29/70 ,  B01J37/02 ,  B01J35/10 ,  B01J23/745 ,  B01J27/14 ,  B01J21/04 ,  B01J37/00 ,  C10G11/05 ,  B01J35/00 ,  B01J35/02 ,  B01J23/10 ,  B01J29/04 ,  B01J29/76 ,  B01J37/10 ,  B01J37/28

CPC classification number: B01J37/0205 ,  B01J21/04 ,  B01J23/10 ,  B01J23/745 ,  B01J27/14 ,  B01J29/041 ,  B01J29/042 ,  B01J29/044 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0072 ,  B01J37/10 ,  B01J37/28 ,  C10G11/05 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/22 ,  B01J2229/38 ,  B01J2229/40 ,  B01J2229/42

Abstract: A process of producing a catalyst comprises forming mesoporous beta zeolite particles, impregnating mesoporous beta zeolite particles with a metal and phosphorus to produce a metal and phosphorus impregnated zeolite, and incorporating the metal and phosphorus impregnated zeolite with clay and alumina to produce the catalyst. The forming step comprises converting a crystalline beta zeolite to a non-crystalline material with reduced silica content relative to the crystalline beta zeolite, and crystalizing the non-crystalline material to produce mesoporous beta zeolite particles.