公开(公告)号：US11780798B2

公开(公告)日：2023-10-10

申请号：US16461989

申请日：2017-11-22

Applicant: HALDOR TOPSØE A/S

Inventor： Christian Mårup Osmundsen ,  Esben Taarning

IPC: C07C51/235 ,  B01J23/44 ,  B01J23/52 ,  C07C45/60 ,  C07C51/285 ,  C07C59/06 ,  C07C27/00

CPC classification number: C07C51/235 ,  B01J23/44 ,  B01J23/52 ,  C07C27/00 ,  C07C45/60 ,  C07C51/285 ,  C07C59/06 ,  C07C45/60 ,  C07C47/19 ,  C07C51/235 ,  C07C59/06

Abstract: A method and a system for producing glycolic acid and/or glycolate from sustainable resources. A method for catalytic production of glycolic acid and/or glycolate including the step of: oxidation of a starting material including between 0.1-100 wt/wt % glycolaldehyde at a temperature of between −10° C. and 100° C. with an oxidant in the presence of a metal-based catalyst including a catalytically active metal, which is selected from the group of palladium and platinum; or mixtures thereof.

公开(公告)号：US10137442B2

公开(公告)日：2018-11-27

申请号：US15604942

申请日：2017-05-25

Applicant: BASF CORPORATION

Inventor： Robert McGuire

IPC: B01J29/80 ,  B01J23/24 ,  B01J37/04 ,  B01J23/656 ,  B01J35/00 ,  C07C1/20 ,  C07C37/52 ,  C07C41/01 ,  C07C27/00 ,  B01J29/06 ,  C10G3/00 ,  C01B3/16 ,  B01J29/08 ,  B01J23/755 ,  B01J35/08 ,  B01J29/40 ,  B01J21/08 ,  B01J21/06 ,  B01J23/42 ,  B01J23/16 ,  B01J37/02 ,  B01J29/16 ,  B01J29/48 ,  B01J29/87

Abstract: A novel catalyst blend for processing of feedstocks into monoaromatics in a single stage, comprising at least one cracking catalyst, one heterogeneous transition metal catalyst, and optionally at least one hydrogenation catalyst. The process occurs in one-step or single stage with substantially no solvents or external additives, or when the feedstock contains less than 15% oxygen, the process includes additional water or steam to enable sufficient amounts of H2 being produced in-situ.

公开(公告)号：US20180236427A1

公开(公告)日：2018-08-23

申请号：US15955418

申请日：2018-04-17

Applicant: XYLECO, INC.

Inventor： Marshall Medoff

IPC: B01J19/08 ,  C08B1/00 ,  B01J19/12 ,  B02C23/18 ,  C07C27/04 ,  C07C27/24 ,  C12M1/00 ,  C12P7/10 ,  H01J37/30 ,  G21K5/00 ,  D21B1/06 ,  D21B1/02 ,  C13K1/02 ,  C12P19/14 ,  C12P19/02 ,  C12P19/00 ,  C07C27/00

CPC classification number: C12P7/10 ,  B01J19/081 ,  B01J19/085 ,  B01J19/121 ,  B01J19/123 ,  B01J19/126 ,  B01J2219/00006 ,  B01J2219/08 ,  B01J2219/0869 ,  B01J2219/0871 ,  B01J2219/0879 ,  B01J2219/089 ,  B02C23/18 ,  C07C27/00 ,  C07C27/04 ,  C07C27/24 ,  C08B1/00 ,  C10L1/02 ,  C10L2200/0469 ,  C10L2290/26 ,  C12M45/00 ,  C12P19/00 ,  C12P19/02 ,  C12P19/14 ,  C12P2201/00 ,  C13K1/02 ,  D21B1/02 ,  D21B1/063 ,  D21B1/10 ,  G21K5/00 ,  H01J37/3002 ,  Y02E50/16 ,  Y02E50/17

Abstract: Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy or sugary materials, to produce ethanol and/or butanol, e.g., by fermentation.

公开(公告)号：US20180179131A1

公开(公告)日：2018-06-28

申请号：US15739921

申请日：2016-04-21

Applicant: IFP Energies Nouvelles

Inventor： Emilie BRULE ,  Etienne GIRARD ,  Amandine CABIAC ,  Damien DELCROIX ,  Marc JACQUIN

IPC: C07C31/18 ,  C07C27/00 ,  C07H3/06 ,  C07H3/02 ,  C01G25/02 ,  C01G45/12 ,  C01G23/00 ,  B01J21/06 ,  B01J23/34

CPC classification number: C07C27/00 ,  B01J21/063 ,  B01J21/066 ,  B01J23/34 ,  C01G23/006 ,  C01G25/02 ,  C01G45/125 ,  C01P2002/34 ,  C07B41/06 ,  C07B41/08 ,  C07B41/12 ,  C07C29/00 ,  C07C29/132 ,  C07C29/60 ,  C07C31/18 ,  C07H3/02 ,  C07H3/06 ,  Y02P20/52 ,  C07C31/02 ,  C07C31/202 ,  C07C31/205

Abstract: The invention concerns a method for converting a feedstock selected from sugars or sugar alcohols, alone or in a mixture, into mono- or polyoxygenated compounds, wherein the feedstock is contacted with at least one heterogeneous catalyst comprising a support selected from perovskites of formula ABO3, in which A is selected from the elements Mg, Ca, Sr and Ba and B is selected from the elements Fe, Mn, Ti and Zr, and the oxides of elements selected from lanthanum, neodymium, yttrium and cerium, alone or in a mixture, which oxides can be doped with at least one element selected from alkali metals, alkaline earths and rare earths, in a reducing atmosphere, at a temperature of 100° C. to 300° C. and at a pressure of 0.1 MPa to 50 MPa.

公开(公告)号：US09828573B2

公开(公告)日：2017-11-28

申请号：US15384344

申请日：2016-12-20

Applicant: SHELL OIL COMPANY

Inventor： Paul Theodore Sharko

IPC: C10M173/02 ,  C07C29/16 ,  C07C27/00 ,  C11D3/34 ,  C11D11/00 ,  C10M135/08 ,  C10M105/12 ,  C10M133/04 ,  C11D3/20 ,  C11D3/30 ,  B01F17/00

CPC classification number: C11D3/34 ,  B01F17/0021 ,  B01F17/0092 ,  C10M105/12 ,  C10M129/06 ,  C10M129/72 ,  C10M133/04 ,  C10M133/08 ,  C10M135/08 ,  C10M145/36 ,  C10M2207/021 ,  C10M2207/282 ,  C10M2209/108 ,  C10M2215/02 ,  C10M2215/042 ,  C10M2219/042 ,  C10N2220/027 ,  C10N2220/028 ,  C11D1/04 ,  C11D1/146 ,  C11D1/29 ,  C11D3/2006 ,  C11D3/2017 ,  C11D3/2093 ,  C11D3/30 ,  C11D11/0017

Abstract: The invention provides a composition comprising a mixture of pentadecanols wherein at least about 60 wt % of the mixture is linear pentadecanol and at least about 10 wt % of the mixture is branched pentadecanols wherein the branched pentadecanols have branching on the second carbon atom. The mixture of pentadecanols may be converted to one or more derivatives, and these derivatives may be used in laundry detergents, cleaning products or as an agricultural adjuvant, an emulsifying agent, a lubricant additive, a pour point depressant, or a personal care ingredient.

公开(公告)号：US09687829B2

公开(公告)日：2017-06-27

申请号：US14616028

申请日：2015-02-06

Applicant: BASF Corporation

Inventor： Robert McGuire

IPC: B01J23/00 ,  B01J20/18 ,  B01J21/00 ,  B01J29/80 ,  B01J23/656 ,  B01J35/00 ,  C07C1/20 ,  C07C37/52 ,  C07C41/01 ,  C07C27/00 ,  B01J37/04 ,  B01J29/06 ,  C10G3/00 ,  C01B3/16 ,  B01J29/08 ,  B01J23/755 ,  B01J35/08 ,  B01J29/40 ,  B01J21/08 ,  B01J21/06 ,  B01J23/24 ,  B01J23/42 ,  B01J23/16 ,  B01J37/02 ,  B01J29/16 ,  B01J29/48 ,  B01J29/87

CPC classification number: B01J29/80 ,  B01J21/06 ,  B01J21/08 ,  B01J23/16 ,  B01J23/24 ,  B01J23/42 ,  B01J23/6567 ,  B01J23/755 ,  B01J29/061 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/87 ,  B01J35/0006 ,  B01J35/08 ,  B01J37/0205 ,  B01J37/04 ,  B01J2229/42 ,  C01B3/16 ,  C07C1/20 ,  C07C27/00 ,  C07C37/52 ,  C07C41/01 ,  C07C2521/04 ,  C07C2523/28 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/656 ,  C07C2523/755 ,  C07C2529/40 ,  C07C2529/80 ,  C10G3/49 ,  C10G2300/1014 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P20/588 ,  Y02P30/20 ,  C07C43/23 ,  C07C39/08 ,  C07C15/08 ,  C07C15/02

Abstract: A novel catalyst blend for processing of feedstocks into monoaromatics in a single stage, comprising at least one cracking catalyst, one heterogeneous transition metal catalyst, and optionally at least one hydrogenation catalyst. The process occurs in one-step or single stage with substantially no solvents or external additives, or when the feedstock contains less than 15% oxygen, the process includes additional water or steam to enable sufficient amounts of H2 being produced in-situ.

公开(公告)号：US09458387B2

公开(公告)日：2016-10-04

申请号：US14007396

申请日：2012-03-14

Applicant: Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

Inventor： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC: B01J21/00 ,  C07C27/00 ,  C10G2/00 ,  B01J21/06 ,  B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J37/18 ,  B01J21/08

CPC classification number: C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

Abstract: A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

Abstract translation: 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。

公开(公告)号：US09452408B2

公开(公告)日：2016-09-27

申请号：US13914493

申请日：2013-06-10

Applicant: Velocys, Inc.

Inventor： William Allen Rogers, Jr. ,  Christopher Paul Weil ,  Robert Dwayne Litt ,  Ronald Chester Pasadyn ,  George Bradley Smith ,  Charles Robert Miele ,  Thomas Peter Forte ,  Jimmy Glen Pelham

IPC: C07C27/00 ,  B01J19/00 ,  C01B3/38 ,  B01J3/04 ,  C07C1/04 ,  C10G2/00

CPC classification number: B01J19/0093 ,  B01J3/046 ,  B01J2219/0081 ,  B01J2219/00817 ,  B01J2219/00835 ,  B01J2219/00867 ,  B01J2219/00869 ,  B01J2219/00873 ,  B01J2219/00891 ,  B01J2219/00957 ,  B01J2219/00961 ,  B01J2219/00963 ,  B01J2219/00986 ,  C01B3/382 ,  C01B3/384 ,  C01B2203/0227 ,  C01B2203/0283 ,  C01B2203/0811 ,  C01B2203/1604 ,  C07C1/0475 ,  C07C1/0485 ,  C10G2/00 ,  C10G2300/4031 ,  Y02P20/52 ,  Y10T29/49345 ,  Y10T29/49815 ,  Y10T29/49826 ,  Y10T29/49948 ,  Y10T137/0335

Abstract: A method of starting up one or more units, the method comprising the steps of: (a) starting up a first unit including a microchannel reactor housing a Fischer-Tropsch catalyst by initially feeding a carbon monoxide source and a hydrogen source to the first unit and through the microchannel reactor; (b) processing, within the microchannel reactor, at least a portion of the carbon monoxide source and the hydrogen source; (c) monitoring at least one of internal pressure, temperature, and concentration at least one of within the microchannel reactor and downstream from the microchannel reactor; (d) at least partially containing the microchannel reactor using a wall of a containment device, the wall cooperating with the microchannel reactor to delineate at least one of a first inlet cavity and a first outlet cavity of the microchannel reactor, where at least one of the first inlet cavity and the first outlet cavity is not in fluid communication with at least one of a second inlet cavity and a second outlet cavity; and, (e) using the containment device to reinforce the integrity of the microchannel reactor.

Abstract translation: 一种启动一个或多个单元的方法，所述方法包括以下步骤：（a）启动第一单元，其包括容纳费 - 托催化剂的微通道反应器，所述微通道反应器首先将一氧化碳源和氢源进料至第一单元 并通过微通道反应器; （b）在微通道反应器内处理至少一部分一氧化碳源和氢源; （c）监测微通道反应器内和微通道反应器下游中的至少一个的内部压力，温度和浓度中的至少一个; （d）至少部分地包含微通道反应器，使用容纳装置的壁，所述壁与微通道反应器配合以描绘微通道反应器的第一入口腔和第一出口空腔中的至少一个，其中至少一个 第一入口腔和第一出口腔不与第二入口腔和第二出口腔中的至少一个流体连通; 和（e）使用容纳装置来增强微通道反应器的完整性。

公开(公告)号：US09410452B2

公开(公告)日：2016-08-09

申请号：US14426083

申请日：2013-09-05

Applicant: POWERDYNE, INC.

Inventor： Geoffrey Hirson ,  Gus F. Shouse

IPC: C07C27/00 ,  F01K25/06 ,  B01J12/00 ,  C01B3/04 ,  B01D21/00 ,  B01D21/01 ,  B09B3/00 ,  H05H1/42 ,  H05H1/44 ,  C01B3/12 ,  C07C1/04 ,  C10G2/00 ,  B01J19/08 ,  C01B3/02 ,  C10L1/06 ,  C10L1/08 ,  H05H1/34 ,  F02C1/05

CPC classification number: F01K25/06 ,  B01D21/0009 ,  B01D21/01 ,  B01J12/002 ,  B01J19/088 ,  B01J2219/0809 ,  B01J2219/0815 ,  B01J2219/0875 ,  B01J2219/0877 ,  B01J2219/0898 ,  B09B3/005 ,  C01B3/02 ,  C01B3/042 ,  C01B3/12 ,  C01B2203/062 ,  C01B2203/0861 ,  C07C1/04 ,  C10G2/32 ,  C10J3/00 ,  C10J2300/1238 ,  C10J2300/1671 ,  C10J2300/1675 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0415 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2290/38 ,  C10L2290/42 ,  F02C1/05 ,  H05H1/34 ,  H05H1/42 ,  H05H1/44 ,  Y02E50/32 ,  Y02E60/364 ,  Y02P20/13

Abstract: Methods of making fuel are described herein. A method may include providing a first working fluid, a second working fluid, and a third working fluid. The method may further include exposing the first working fluid to a first high-voltage electric field to produce a first plasma, exposing the second working fluid to a second high-voltage electric field to produce a second plasma, and exposing the third working fluid to a third high-voltage electric field to produce a third plasma. The method may also include contacting the third plasma, the second plasma, and the first plasma to form a plasma mixture, cooling the plasma mixture using a heat exchange device to form a cooled plasma mixture, and contacting the cooled plasma mixture with a catalyst to form a fuel fluid.

Abstract translation: 本文描述了制备燃料的方法。 一种方法可以包括提供第一工作流体，第二工作流体和第三工作流体。 该方法还可以包括将第一工作流体暴露于第一高压电场以产生第一等离子体，将第二工作流体暴露于第二高压电场以产生第二等离子体，并将第三工作流体暴露于 第三高压电场产生第三等离子体。 该方法还可以包括使第三等离子体，第二等离子体和第一等离子体接触以形成等离子体混合物，使用热交换装置冷却等离子体混合物以形成冷却的等离子体混合物，并将冷却的等离子体混合物与催化剂接触 形成燃料流体。

公开(公告)号：US09399837B2

公开(公告)日：2016-07-26

申请号：US14574689

申请日：2014-12-18

Applicant: SHELL OIL COMPANY

Inventor： Joseph Broun Powell ,  Juben Nemchand Chheda

IPC: C07C27/00 ,  D21C11/00 ,  C07C29/132 ,  C13K1/02 ,  D21C9/08 ,  C07C1/24 ,  C07G1/00 ,  C10G1/06 ,  C10G3/00 ,  C08H8/00

CPC classification number: D21C9/083 ,  C07C1/24 ,  C07C29/132 ,  C07G1/00 ,  C08H8/00 ,  C10G1/065 ,  C10G3/42 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/4081 ,  C13K1/02 ,  D21C11/0028 ,  Y02P30/20

Abstract: A selective removal of metal and its anion species that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed prior to carrying out catalytic hydrogenation/hydrogenolyzis/hydrodeoxygenation of the biomass in a manner that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.

Abstract translation: 选择性除去金属及其阴离子物质，这些物质在生物质进行催化氢化/氢解/加氢脱氧之前不利于随后的水热催化转化从生物质原料中转移，而不会降低水热催化剂处理的有效性同时最小化 提供了在该过程中使用的水量。