公开(公告)号：US11879374B2

公开(公告)日：2024-01-23

申请号：US17657954

申请日：2022-04-05

Applicant: Johnson Matthey Public Limited Company

Inventor： Ruxandra Georgiana Chitac ,  Nicholas McNamara ,  Alessandro Turrina ,  Paul Anthony Wright

IPC: B01J29/86 ,  F01N3/20 ,  B01J29/70 ,  C07C1/22 ,  B01J37/10 ,  B01J29/76 ,  B01J29/88 ,  B01J29/04 ,  B01J29/74 ,  B01J29/78 ,  B01J29/87 ,  B01J37/30 ,  B01J37/02 ,  B01J29/89 ,  B01J29/72

CPC classification number: F01N3/2066 ,  B01J29/046 ,  B01J29/047 ,  B01J29/048 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J37/0201 ,  B01J37/10 ,  B01J37/30 ,  C07C1/22 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  C07C2529/70 ,  F01N2570/14

Abstract: The present invention is directed to a method of preparing a molecular sieve of SWY framework type, denominated STA-30. STA-30 is synthesized using 1,4-diazabicyclo[2.2.2]octane, 1-azabicyclo[2.2.2]octane derivates and combinations thereof as structure directing agents. The resulting molecular sieve is useful as catalysts, particularly when used in combination with exchanged transition metal(s) for the Selective Catalytic Reduction (SCR) of NO.

公开(公告)号：US20030229257A1

公开(公告)日：2003-12-11

申请号：US10412641

申请日：2003-04-11

Inventor： Avelino Corma Canos ,  Maria Teresa Navarro Villalba ,  Fernando Rey Garcia ,  Susana Valencia Valencia

IPC: B01J029/06 ,  C10G011/02 ,  C10G011/04 ,  C07C027/00

CPC classification number: C10G45/64 ,  B01J29/04 ,  B01J29/046 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  C10G11/05 ,  C10G29/205 ,  C10G47/16

Abstract: A microporous crystalline material of a zeolitic nature, that corresponds to the empirical formulax(M1/nXO2):yYO2:zGeO2:(1nullz)TO2wherein x has a value between 0 and 0.2; y has a value between 0 and 0.1; z has a value between 0 and 0.67; being at least one of the z, x and y above zero; M is selected between Hnull and inorganic cations with a nulln charge; X is at least one chemical element with a null3 oxidation status; Y is at least one chemical element with a null4 oxidation status; and T is at least one chemical element with a null4 oxidation status; and is also characterised by its X-ray diffraction pattern and its microporous properties, and can be employed as a catalyst or oxidating agent in the separation and transformation of organic compounds.

Abstract translation: 沸石性质的微孔结晶材料对应于经验公式（M1 / nXO2）：yYO2：zGeO2：（1-z）TO2，其中x具有0和0.2之间的值; y的值在0到0.1之间; z的值介于0和0.67之间; 是z，x和y中的至少一个高于零; 在+ +电荷之间选择H +和无机阳离子之间的M; X是至少一种具有+3氧化状态的化学元素; Y是至少一种具有+4氧化状态的化学元素; 和T是具有+4氧化状态的至少一种化学元素; 并且其特征在于其X射线衍射图及其微孔性质，并且可用作有机化合物的分离和转化中的催化剂或氧化剂。

公开(公告)号：US20030188991A1

公开(公告)日：2003-10-09

申请号：US10313720

申请日：2002-12-06

Inventor： Zhiping Shan ,  Jacobus Cornelius Jansen ,  Chuen Y. Yeh ,  Philip J. Angevine ,  Thomas Maschmeyer

IPC: C10G011/02 ,  C07C007/12 ,  C07C005/333 ,  C07C005/22 ,  C10G047/02 ,  C10G045/04 ,  C07C002/08 ,  C07C002/58

CPC classification number: C10G2/332 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 null to about 30 null and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3null to about 3.5null at 2null. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

Abstract translation: 一种用于处理有机化合物的方法包括提供一种组合物，其包括基本上介孔结构的二氧化硅，其含有至少97体积％的孔径范围为约至约的孔，并且具有至少约0.01的微孔体积 cc / g，其中介孔结构具有至少约0.02重量％的至少一种选自Al，Ti，V，Cr，Zn，Fe，Sn，Mo的催化和/或化学活性的杂原子 ，Ga，Ni，Co，In，Zr，Mn，Cu，Mg，Pd，Pt和W，催化剂在2θ处具有0.3°至约3.5°的一个峰的X射线衍射图。 催化剂在反应条件下与有机原料接触，其中处理过程选自烷基化，酰化，低聚，选择性氧化，加氢处理，异构化，脱金属催化脱蜡，羟基化，氢化，氨肟化，异构化，脱氢，裂化和吸附。

公开(公告)号：US4454365A

公开(公告)日：1984-06-12

申请号：US479700

申请日：1983-03-28

Applicant: Marvin R. Klotz

Inventor： Marvin R. Klotz

IPC: B01J29/89 ,  C01B33/20 ,  C07C5/27 ,  C07C5/22

CPC classification number: B01J29/046 ,  C01B33/20 ,  C07C5/2705 ,  B01J2229/40 ,  Y02P20/52

Abstract: There is provided a catalytic composition which comprises a crystalline chromosilicate and a porous refractory inorganic oxide, said chromosilicate and said inorganic oxide having been intimately admixed with one another, said chromosilicate comprising a molecular sieve material providing a specific X-ray diffraction pattern and having the following composition in terms of mole ratios of oxides:0.9.+-.0.2 M.sub.2/n O:Cr.sub.2 O.sub.3 :YSiO.sub.2 :ZH.sub.2 O,wherein M is at least one cation having a valence of n, Y is within the range of about 4 to about 200, and Z is a value within the range of 0 to about 160. There is also provided a method for preparing such a catalytic composition.There is provided a process for the conversion of a hydrocarbon stream, which process comprises contacting said stream at conversion conditions with the above catalytic composition. In addition, there is provided a process for the isomerization of a xylene feed, which process comprises contacting said feed at isomerization conditions with the above catalytic composition.

Abstract translation: 提供了一种催化组合物，其包含结晶铬酸盐和多孔耐火无机氧化物，所述铬硅酸盐和所述无机氧化物彼此紧密混合，所述含氯硅酸盐包括提供特定X射线衍射图的分子筛材料， 按照氧化物的摩尔比计算以下组成：0.9 +/- 0.2M 2 / nO：Cr 2 O 3 :YSiO 2 :ZH 2 O，其中M是至少一种价数为n的阳离子，Y在约4至约200的范围内， Z为0至约160的范围内的值。还提供了制备这种催化剂组合物的方法。 提供了一种转化烃流的方法，该方法包括在转化条件下将所述物流与上述催化剂组合物接触。 此外，提供了二甲苯进料异构化的方法，该方法包括使异构化条件下的进料与上述催化剂组合物接触。

公开(公告)号：US4405504A

公开(公告)日：1983-09-20

申请号：US281839

申请日：1981-07-09

Applicant: Marvin R. Klotz

Inventor： Marvin R. Klotz

IPC: B01J29/89 ,  C07C5/27 ,  B01J29/00 ,  B01J29/04

CPC classification number: B01J29/046 ,  C07C5/2705

Abstract: There is provided a catalytic composition which comprises a mixture of a crystalline chromosilicate and an oxide of chromium, said catalytic composition providing a specific X-ray diffraction pattern and having the following composition in terms of mole ratios of oxides:0.9.+-.0.2 M.sub.2/n O:Cr.sub.2 O.sub.3 :YSiO.sub.2 :ZH.sub.2 O,wherein M is at least one cation having a valence of n, Y is a value within the range of about 4 to about 500, and Z is a value within the range of about 0 to about 160. There is also provided a method for preparing such a catalytic composition.There is provided a process for the conversion of a hydrocarbon stream which comprises contacting said stream at conversion conditions with the above catalytic composition. In addition, there is provided a process for the isomerization of a xylene feed which comprises contacting said feed at isomerization conditions with the above catalytic composition.

Abstract translation: 提供了一种催化组合物，其包含结晶铬酸铬和铬的氧化物的混合物，所述催化组合物提供特定的X射线衍射图，并且以氧化物的摩尔比计具有以下组成：0.9 +/- 0.2M2 / nO：Cr 2 O 3 :YSiO 2 :HH 2 O，其中M为至少一个价数为n的阳离子，Y为约4至约500的范围内的值，Z为约0至约160的范围内的值 还提供了制备这种催化剂组合物的方法。 提供了一种转化烃流的方法，其包括在转化条件下将所述物流与上述催化组合物接触。 此外，提供了二甲苯进料异构化的方法，其包括使异构化条件下的进料与上述催化组合物接触。

公开(公告)号：US4396783A

公开(公告)日：1983-08-02

申请号：US299546

申请日：1981-09-04

Applicant: Antonio Esposito ,  Marco Taramasso ,  Carlo Neri

Inventor： Antonio Esposito ,  Marco Taramasso ,  Carlo Neri

IPC: C07C37/60 ,  C07C43/205 ,  C07C205/22 ,  C07C79/26

CPC classification number: B01J37/033 ,  B01J29/046 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/89 ,  C01B37/005 ,  C07C201/12 ,  C07C37/60 ,  C07C41/26 ,  B01J2229/18

Abstract: A process for the hydroxylation of aromatic hydrocarbons by hydrogen peroxide, consisting in reacting said compounds in the presence of synthetic zeolites which contain heteroatoms, both replaced and exchanged.The reaction is carried out at a temperature comprised between 80.degree. C. and 120.degree. C. and in the presence of the hydrocarbon only or in the presence of a solvent which permits, at least partially, to admix the aromatic hydrocarbon with the hydrogen peroxide.

Abstract translation: 一种通过过氧化氢使芳烃羟基化的方法，包括使所述化合物在含有杂原子的合成沸石存在下进行反应，两者都被替换和交换。 反应在80℃至120℃之间的温度下进行，仅在烃存在下或在溶剂存在下进行，该溶剂允许至少部分地将芳族烃与过氧化氢 。

公开(公告)号：US11834340B2

公开(公告)日：2023-12-05

申请号：US17230560

申请日：2021-04-14

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Robert Peter Hodgkins ,  Omer Refa Koseoglu ,  Kuo-Wei Huang ,  Jean-Marie Maurice Basset ,  Yu Han ,  Rajesh Parsapur ,  Anissa Bendjeriou Sedjerari ,  Sathiyamoorthy Murugesan

IPC: B01J29/40 ,  C01B39/40 ,  B01J29/04 ,  B01J29/48 ,  B01J29/46 ,  B01J29/42 ,  C01B39/06 ,  B01J29/44 ,  B01J35/10 ,  B01J35/02

CPC classification number: C01B39/40 ,  B01J29/04 ,  B01J29/041 ,  B01J29/042 ,  B01J29/043 ,  B01J29/045 ,  B01J29/046 ,  B01J29/047 ,  B01J29/048 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J35/023 ,  B01J35/109 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  C01B39/06 ,  C01B39/065 ,  B01J2229/183 ,  C01P2002/01 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16

Abstract: Embodiments of the present disclosure relate to zeolites and method for making such zeolites. According to embodiments disclosed herein, a zeolite may have a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm and a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The microporous framework may include an MFI framework type. The microporous framework may include silicon atoms, aluminum atoms, oxygen atoms, and transition metal atoms. The transition metal atoms may be dispersed throughout the entire microporous framework.

公开(公告)号：US20180057364A1

公开(公告)日：2018-03-01

申请号：US15686235

申请日：2017-08-25

Applicant: PURDUE RESEARCH FOUNDATION

Inventor： Rajamani P. Gounder ,  Juan Carlos Vega-Vila ,  James William Harris

IPC: C01B39/06 ,  C07H1/00 ,  C07H3/02 ,  B01J29/89 ,  B01J29/04

CPC classification number: C01B39/06 ,  B01J29/04 ,  B01J29/046 ,  B01J29/047 ,  B01J29/061 ,  B01J29/072 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/065 ,  C07H1/00 ,  C07H3/02

Abstract: A process of producing a zeotype material having a zeolite-type framework. The process includes providing a zeolite having a framework, dealuminating the zeolite to remove aluminum atoms therefrom to produce a dealuminated framework comprising a plurality of vacancy sites, contacting the dealuminated framework with dichloromethane and a precursor comprising heteroatoms, and then heating the dealuminated framework, the dichloromethane, and the precursor under reflux conditions to incorporate the heteroatoms into at least some of the plurality of vacancy sites in the dealuminated framework to produce a zeotype material having a zeolite-type framework comprising the heteroatoms. In addition, a process is provided for producing a stannosilicate comprising a zeolite-type framework comprising Sn heteroatoms incorporated therein which form Sn sites in the zeolite-type framework each having an open configuration or a closed configuration. This process includes controlling relative amounts of Sn sites having open and closed configurations in the stannosilicate.

公开(公告)号：US20060052234A1

公开(公告)日：2006-03-09

申请号：US11198564

申请日：2005-08-05

Applicant: Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

Inventor： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

IPC: C10G47/02 ,  C10G45/04 ,  C10G11/02 ,  B01J29/06

CPC classification number: B01J29/046 ,  B01J21/12 ,  B01J23/44 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  B01J2229/42 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C10G2/332 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G50/00 ,  C07C15/073

Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of refractory oxide containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2 theta (θ). The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

Abstract translation: 一种用于处理有机化合物的方法包括提供一种组合物，其包括耐火氧化物的基本介孔结构，其含有至少97体积％的孔径为约至约的孔，并且具有至少约 0.01cc / g，其中介孔结构与其中至少约0.02重量％的至少一种催化和/或化学活性的选自Al，Ti，V，Cr，Zn，Fe，Sn， Mo，Ga，Ni，Co，In，Zr，Mn，Cu，Mg，Pd，Pt和W，并且催化剂具有在2θ（θ）处在0.3°至约3.5°具有一个峰的X射线衍射图， 。 催化剂在反应条件下与有机原料接触，其中处理过程选自烷基化，酰化，低聚，选择性氧化，加氢处理，异构化，脱金属催化脱蜡，羟基化，氢化，氨肟化，异构化，脱氢，裂化和吸附。

公开(公告)号：US20050201920A1

公开(公告)日：2005-09-15

申请号：US11101858

申请日：2005-04-08

Applicant: Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

Inventor： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

IPC: B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/10 ,  C01B13/36 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C27/00 ,  C07C27/06 ,  C10G11/02 ,  C10G15/00

CPC classification number: C10G2/332 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2θ. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.