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公开(公告)号:US09947938B2
公开(公告)日:2018-04-17
申请号:US14765679
申请日:2014-01-29
IPC分类号: H01M4/92 , H01M8/1004 , H01M4/86 , B01J21/18 , B01J23/648 , B01J37/02 , B01J23/46 , H01M4/88 , H01M8/1018
CPC分类号: H01M4/921 , B01J21/18 , B01J23/466 , B01J23/6484 , B01J23/6486 , B01J37/0201 , H01M4/86 , H01M4/881 , H01M4/8828 , H01M4/8842 , H01M4/925 , H01M4/926 , H01M8/1004 , H01M8/1018 , H01M2004/8684 , H01M2008/1095 , H01M2250/20 , H01M2300/0082 , Y02E60/521 , Y02T90/32
摘要: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of Nb and Ta, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum in the anode catalyst layer is from 0.01 to 0.2 mgPt/cm2.
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公开(公告)号:US20210143443A1
公开(公告)日:2021-05-13
申请号:US17153927
申请日:2021-01-21
IPC分类号: H01M4/92 , H01M8/1004 , H01M4/86 , B01J21/18 , B01J23/648 , B01J37/02 , H01M8/1018
摘要: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of rhodium and osmium, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum group metals (PGM) in the anode catalyst layer is from 0.01 to 0.2 mgPGM/cm2.
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公开(公告)号:US09947939B2
公开(公告)日:2018-04-17
申请号:US14765699
申请日:2014-01-29
IPC分类号: H01M4/92 , H01M8/1004 , H01M4/86 , B01J21/18 , B01J23/648 , B01J37/02 , H01M8/1018 , B01J23/46 , H01M4/88
CPC分类号: H01M4/921 , B01J21/18 , B01J23/466 , B01J23/6484 , B01J23/6486 , B01J37/0201 , H01M4/86 , H01M4/881 , H01M4/8828 , H01M4/8842 , H01M4/925 , H01M4/926 , H01M8/1004 , H01M8/1018 , H01M2004/8684 , H01M2008/1095 , H01M2250/20 , H01M2300/0082 , Y02E60/521 , Y02T90/32
摘要: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of rhodium and osmium, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum group metals (PGM) in the anode catalyst layer is from 0.01 to 0.2 mgPGM/cm2.
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公开(公告)号:US10938038B2
公开(公告)日:2021-03-02
申请号:US15874000
申请日:2018-01-18
IPC分类号: H01M4/92 , H01M8/1004 , H01M4/86 , B01J21/18 , B01J23/648 , B01J37/02 , H01M8/1018 , B01J23/46 , H01M4/88 , B01J23/56 , B01J23/42 , H01M8/04298
摘要: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of rhodium and osmium, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum group metals (PGM) in the anode catalyst layer is from 0.01 to 0.2 mgPGM/cm2.
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公开(公告)号:US20190221857A1
公开(公告)日:2019-07-18
申请号:US16361974
申请日:2019-03-22
CPC分类号: H01M4/8657 , H01M4/8647 , H01M4/8652 , H01M4/9016 , H01M4/9025 , H01M2008/1095
摘要: A catalyst layer comprising an electrocatalyst and an oxygen evolution catalyst, wherein the oxygen evolution catalyst comprises a crystalline metal oxide comprising: (i) one of more first metals selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, magnesium, calcium, strontium, barium, sodium, potassium, indium, thallium, tin, lead, antimony and bismuth; (ii) one or more second metals selected from the group consisting of Ru, Ir, Os and Rh; and (iii) oxygen characterised in that: (a) the atomic ratio of first metal(s):second metal(s) is from 1:1.5 to 1.5:1 (b) the atomic ratio of (first metal(s)+second metal(s)):oxygen is from 1:1 to 1:2 is disclosed.
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公开(公告)号:US20180145338A1
公开(公告)日:2018-05-24
申请号:US15874000
申请日:2018-01-18
IPC分类号: H01M4/92 , B01J23/648 , B01J37/02 , H01M4/86 , B01J21/18 , H01M8/1004 , H01M8/1018 , H01M4/88 , B01J23/46
CPC分类号: H01M4/921 , B01J21/18 , B01J23/466 , B01J23/6484 , B01J23/6486 , B01J37/0201 , H01M4/86 , H01M4/881 , H01M4/8828 , H01M4/8842 , H01M4/925 , H01M4/926 , H01M8/1004 , H01M8/1018 , H01M2004/8684 , H01M2008/1095 , H01M2250/20 , H01M2300/0082 , Y02E60/521 , Y02T90/32
摘要: A method of operating a fuel cell having an anode, a cathode and a polymer electrolyte membrane disposed between the anode and the cathode, includes feeding the anode with an impure hydrogen stream having low levels of carbon monoxide up to 5 ppm, and wherein the anode includes an anode catalyst layer including a carbon monoxide tolerant catalyst material, wherein the catalyst material includes: (i) a binary alloy of PtX, wherein X is a metal selected from the group consisting of rhodium and osmium, and wherein the atomic percentage of platinum in the alloy is from 45 to 80 atomic % and the atomic percentage of X in the alloy is from 20 to 55 atomic %; and (ii) a support material on which the PtX alloy is dispersed; wherein the total loading of platinum group metals (PGM) in the anode catalyst layer is from 0.01 to 0.2 mgPGM/cm2.
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