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    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS
    2.
    发明申请
    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS 有权
    ZINC催化剂/用于环氧化物单体聚合的添加剂体系

    公开(公告)号：US20160289381A1

    公开(公告)日：2016-10-06

    申请号：US15035422

    申请日：2014-11-18

    申请人： DOW GLOBAL TECHNOLOGIES LLC

    发明人： Anna V. Davis ,  Peter N. Nickias

    IPC分类号： C08G65/12

    CPC分类号： C08G65/12 ,  B01J2531/11 ,  C08G65/10 ,  C08G65/266 ,  C08G65/269

    摘要： The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) first row transition metals excluding Zn, preferably Sc, Ti, V, Cr, Mn, Ni, and Co, more preferably Ti, (II) second row transition metals, preferably Y and Zr, more preferably Zr, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

    摘要翻译： 本发明涉及一种催化剂制剂，其包含：（a）包含衍生自一种或多种多元醇的具有醇化物配体的Zn化合物的Zn催化剂，和（b）包含具有醇化物配体的金属化合物（i） s），其中金属选自：（I）不包括Zn的第一排过渡金属，优选Sc，Ti，V，Cr，Mn，Ni和Co，更优选Ti，（II）第二排 过渡金属，优选Y和Zr，更优选Zr，和（III）选自（I）和（II）中的至少两种金属的组合。 本发明还涉及聚合环氧化物单体，优选环氧乙烷的方法，包括在催化剂制剂存在下进行该方法。

    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS
    3.
    发明申请
    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS 有权
    ZINC催化剂/用于环氧化物单体聚合的添加剂体系

    公开(公告)号：US20160289380A1

    公开(公告)日：2016-10-06

    申请号：US15035407

    申请日：2014-11-18

    申请人： DOW GLOBAL TECHNOLOGIES LLC

    发明人： Anna V. Davis ,  Peter N. Nickias

    IPC分类号： C08G65/12 ,  C08G65/26

    CPC分类号： C08G65/12 ,  B01J31/0212 ,  B01J2231/14 ,  C08G65/10 ,  C08G65/2648 ,  C08G65/2651 ,  C08G65/266 ,  C08G65/269

    摘要： The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 2 metals, preferably Mg, Ca, Sr, and Ba, more preferably Mg, (II) Li, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

    摘要翻译： 本发明涉及一种催化剂制剂，其包含：（a）包含衍生自一种或多种多元醇的具有醇化物配体的Zn化合物的Zn催化剂，和（b）包含具有醇化物配体的金属化合物（i） s）衍生自一种或一元醇的金属，其中金属选自：（I）第2族金属，优选Mg，Ca，Sr和Ba，更优选Mg，（II）Li和（III）至少两种 选自（I）和（II）的金属。 本发明还涉及聚合环氧化物单体，优选环氧乙烷的方法，包括在催化剂制剂存在下进行该方法。

    Method for preparing polyalkylenecarbonate
    4.
    发明授权
    Method for preparing polyalkylenecarbonate 有权
    聚亚烷基碳酸酯的制备方法

    公开(公告)号：US09458285B2

    公开(公告)日：2016-10-04

    申请号：US14436010

    申请日：2014-05-27

    申请人： LG CHEM, LTD.

    发明人： Yoon-Jung Kim ,  Seung Young Park ,  Taek-Jun Jung ,  Yun-ki Cho

    IPC分类号： C08G64/34 ,  C08G59/68 ,  C08G65/26 ,  B01J31/12 ,  C08G64/02 ,  C08L69/00 ,  C08G65/04 ,  C08G65/10

    CPC分类号： C08G59/685 ,  B01J31/12 ,  C08G64/02 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/266 ,  C08G65/269 ,  C08L69/00

    摘要： This disclosure relates to a method for preparing polyalkylenecarbonate. More specifically, in the method for preparing polyalkylenecarbonate, by using a solution polymerization with a specific heterogeneous catalyst and a solvent in the polymerization process of an epoxide compound and carbon dioxide, the products of side-reaction are reduced, removal of metal residues and by-products from the products is facilitated, danger due to overheating of the reactants is minimized, and heat removal and process stability are improved, and thus, high molecular weight copolymer may be easily provided, and mass production and scale-up are easy.

    摘要翻译： 本公开涉及一种制备聚亚烷基碳酸酯的方法。 更具体地说，在制备聚亚烷基碳酸酯的方法中，通过在环氧化合物和二氧化碳的聚合过程中通过使用特异性非均相催化剂和溶剂的溶液聚合，副反应产物减少，金属残余物的除去和 - 来自产品的产品被促进，由于反应物的过热的危险被最小化，并且提高了除热和加工稳定性，因此可以容易地提供高分子量共聚物，并且容易进行批量生产和放大。

    Copolyether glycol manufacturing process
    6.
    发明授权
    Copolyether glycol manufacturing process 有权
    共聚乙二醇制造工艺

    公开(公告)号：US08609805B2

    公开(公告)日：2013-12-17

    申请号：US13247794

    申请日：2011-09-28

    申请人： Qun Sun ,  Gary L. Kiser ,  Robert D. Orlandi

    发明人： Qun Sun ,  Gary L. Kiser ,  Robert D. Orlandi

    IPC分类号： C08G65/20 ,  C08G65/30

    CPC分类号： C08G65/10 ,  C08G65/20 ,  C08G65/2609 ,  C08G65/2681 ,  C08G65/2684 ,  C08G65/2687 ,  C08G65/269 ,  C08G65/30

    摘要： The present invention provides a highly efficient process for manufacturing copolyether glycol having a mean molecular weight of from about 650 to about 5000 dalton by polymerization of tetrahydrofuran and at least one alkylene oxide in the presence of an acid catalyst and at least one compound containing reactive hydrogen atoms. More particularly, the invention relates to a process for manufacturing copolyether glycol which comprises recycle to the polymerization reaction step of at least a portion of the oligomeric cyclic ether which is co-produced with the copolyether glycol, said process exhibiting an Space Time Yield value of greater than about 0.9.

    摘要翻译： 本发明通过在酸催化剂和至少一种含有反应性氢的化合物存在下，通过四氢呋喃和至少一种烯化氧的聚合来提供平均分子量为约650至约5000道尔顿的共聚醚二醇的高效方法 原子 更具体地说，本发明涉及一种制备共聚醚二醇的方法，该方法包括将与共聚醚二醇共同生产的至少一部分低聚环醚再循环到聚合反应步骤中，所述方法表现出空时收率值 大于0.9。

    Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates
    7.
    发明授权
    Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates 有权
    基于DMC合成的中间体的单体反应器合成KOH-封端的多元醇

    公开(公告)号：US07005552B2

    公开(公告)日：2006-02-28

    申请号：US10699951

    申请日：2003-11-03

    申请人： Bryan D. Kaushiva

    发明人： Bryan D. Kaushiva

    IPC分类号： C07C41/02

    CPC分类号： C08G65/2663 ,  C08G18/4841 ,  C08G18/4866 ,  C08G65/2648 ,  C08G65/269 ,  C08G65/2696

    摘要： The present invention relates to processes for preparing ethylene oxide (EO)-capped polyols in which removal of catalyst residues or salts formed by the neutralization of the basic catalyst is not required prior to discharging the polyol from the reactor because neutralization occurs during or after the starter charge of a subsequent batch. The inventive processes allow for the preparation of DMC-catalyzed intermediates and their base-catalyzed EO caps within the same reactor. Polyols produced by the processes of the invention have a high content of primary hydroxyl groups and may be useful for producing polyurethane foams, elastomers, sealants, coatings, adhesives and the like.

    摘要翻译： 本发明涉及制备环氧乙烷（EO）包被的多元醇的方法，其中在将多元醇从反应器中排出之前，不需要除去由碱性催化剂中和形成的催化剂残余物或盐，因为中和发生在反应器中或之后 后续批次的起动器充电。 本发明的方法允许在同一反应器内制备DMC催化的中间体及其碱催化的EO盖。 通过本发明方法生产的多元醇具有高含量的伯羟基，并且可用于生产聚氨酯泡沫，弹性体，密封剂，涂料，粘合剂等。